Method of manufacturing a thin glass membrane

• US 4,883,563 A
• Filed: 10/28/1988
• Issued: 11/28/1989
• Est. Priority Date: 11/27/1986
• Status: Expired due to Fees

• Current Assignee: Horiba Limited
• Original Assignee: Horiba Limited
• Inventors: Yada, Takaaki, Nakanishi, Tsuyoshi, Tomita, Katsuhiko, Kotani, Haruo
• Primary Examiner(s): Powell, William A.
• Application Number:
  US07/264,143
• Time in Patent Office: 396 Days
• Field of Search: 156/645, 156/654, 156/663, 65/30, 65/31, 204/408, 252/79.3
• US Class Current: 216/52
• CPC Class Codes: G01N 27/36 Glass electrodes

Abstract

A flat shaped composite electrode includes a flat substrate having a high electrical insulating property. A flat inside pair of electrodes and a flat outside pair of electrodes are fixed on the substrate. A flat support layer having a high electrical insulating property overlays the electrodes and substrate. The support layer describes two holes into which a gelatinized internal solution is placed. An ion response glass membrane is mounted on the support layer and over one hole, while a liquid junction membrane is similarly mounted over the other hole.

Claims

1. A method of manufacturing a thin pH-responsive glass membrane, comprising the steps of:

providing a glass ingot;

cutting the glass ingot to form a glass sheet of approximately a predetermined thickness;

adjusting the thickness of the glass sheet, if necessary, to the predetermined thickness;

heating the glass sheet to a temperature below its melting point;

applying additional heat energy to the heated glass sheet of an amount to uniformly melt only its surface, and

solidifying the melted surface to form the pH-responsive glass membrane.

2. The method of claim 1 wherein the additional heat energy is applied through application of a laser beam to the glass sheet.

3. The method of claim 1 wherein any adjustment of the glass sheet is accomplished by an etching treatment to remove any excess thickness of the glass sheet.

4. The method of claim 1 wherein the additional heat energy is applied through lamp heat radiation to the glass sheet.

5. The method of claim 1 wherein the additional heat energy is applied through gas combustion gases directed to the glass sheet.

6. The method of claim 1 wherein the glass sheet is heated to approximately 600°

C. below the softening point of the glass sheet.

7. The method of claim 6 wherein the additional heat energy is applied at 1200°

C. for several seconds to uniformly melt the surface.

8. The method of claim 6 wherein the glass ingot is cut to approximately 0.2 mm in thickness.

9. The method of claim 2 wherein the additional heat energy is applied to both surfaces of the glass sheet by scanning with the laser beam.

10. The method of claim 1 wherein the predetermined thickness is 0.1 mm.

11. The method of claim 3 wherein a 5% aqueous solution of NH₄ F is used to etch the glass sheet.

12. The method of claim 1 wherein the glass ingot is cut to a shape of about 45 mm long, 45 mm wide and 0.2 mm thick, subsequently adjusted into a thickness of about 0.1 mm and recut to smaller sheets of about 10 mm long and 8 mm wide.

13. A method of manufacturing a thin pH-responsive glass membrane, comprising the steps of:

providing a solid glass member of the desired glass composition;

mechanically cutting the glass member to form a glass sheet;

etching the glass sheet to an approximate thickness of 0.1 mm;

heating the entire glass sheet to a temperature below its melting point to stabilize the glass sheet and prevent creaking in subsequent processing;

heating at least one glass sheet surface to a temperature to melt only that surface for a short period of time, and

solidifying the melted surface to form the pH-responsive glass membrane.

14. The method of claim 13 wherein the glass member is cut to form a glass sheet of approximately 0.2 mm in thickness.

15. The method of claim 13 wherein the additional heat energy is applied through application of a laser beam to the glass sheet.

16. The method of claim 13 wherein the glass sheet is heated to approximately 600°

C. below the softening point of the glass sheet.

17. The method of claim 13 wherein the heating of the glass sheet surface is applied at 1200°

C. for several seconds to uniformly melt the surface.

18. The method of claim 13 wherein the glass member is cut to approximately 0.2 mm in thickness.

19. The method of claim 13 wherein a 5% aqueous solution of NH₄ F is used to etch the glass sheet.

20. The method of claim 13 wherein the additional heat energy is applied through lamp heat radiation to the glass sheet.

21. The method of claim 17 wherein the heat energy is applied to both surfaces of the glass sheet by scanning with the laser beam.

22. The method of claim 17 wherein the heat energy is applied through gas combustion gases directed to the glass sheet.

23. The method of claim 22 further including placing a plurality of working blocks having high heat a conductivity in a furnace to apply gas combustion gases, each working block supporting at least one glass sheet and moving the working blocks through the furnace.