Vis-breaking heavy crude oils for pumpability

• US 4,883,582 A
• Filed: 03/07/1988
• Issued: 11/28/1989
• Est. Priority Date: 03/07/1988
• Status: Expired due to Fees

• Current Assignee: Malcolm T. Mccants
• Original Assignee: Malcolm T. Mccants
• Inventors: McCants, Malcolm T.
• Primary Examiner(s): Caldarola, Glenn
• Application Number:
  US07/164,861
• Time in Patent Office: 631 Days
• Field of Search: 208/106, 208/107, 208/100, 208/102, 208/103, 208/109, 208/78, 208/414, 208/427, 208/130, 208/48 R, 208/48 Q
• US Class Current: 208/106
• CPC Class Codes: C10G 69/06 including at least one step of thermal cracking in the absence of hydrogen
• CPC Class Codes: C10G 9/007 Visbreaking

Abstract

Crude oils are normally so viscous that they cannot be pumped through pipelines without periodic heating. The usual practice is to pump the oil from one heat station to another, with part of the crude oil being used to generate heat. This problem is solved by reducing the viscosity of the crude oil. The viscosity reduction is effected using reactors for partially cracking crude oil, mixing the partially cracked oil with incoming crude oil, separating gases from the liquid in the mixture in a flash vessel, condensing the gases to yield liquid hydrocarbons, and mixing the latter with untreated crude oil and liquid residue from the flash vessel to yield a flowable, relatively low viscosity mixture. Coke produced in the reactors is periodically reacted with superheated steam to yield hydrogen, which is used to improve the quality of some of the residue from the flash residue. The thus treated flash vessel residue is used to feed the reactors.

Claims

1. A method of reducing the viscosity of untreated crude oil, comprising the steps of:

(a) vis-breaking in a reactor a first portion of the untreated crude oil with a recycled stream to produce a partially cracked residuum of the untreated oil;

(b) mixing the partially cracked residuum of the untreated oil with a second portion of the untreated oil to quench cracking and producing a first mixture;

(c) separating gas, vapor, and liquid by flashing from said mixture;

(d) condensing the gas and vapor obtained in step (c) to produce liquid hydrocarbons and gas;

(e) splitting the liquid obtained in step (c) into first and second streams thereof;

(f) passing said first stream obtained in step (e) for use as said recycled stream in step (a);

(g) reacting coke produced in step (a) with superheated steam to produce a hydrogen-containing gas during regeneration cycle to the reactor; and

(h) mixing said hydrogen-containing gas with said first stream obtained in step (e) prior to vis-breaking in step (a).

2. A method according to claim 1, and including the step of:

(i) mixing said second stream obtained in step (e) with a third portion of the untreated oil and the liquid hydrocarbons obtained in step (d).

3. A method according to claim 1, including the step of:

(j) burning the gas obtained in step (d) to generate heat for the reactor.

4. A method according to claim 3, including the steps of:

(k) mixing a fuel with the gas obtained in step (d); and

(l) burning the mixture obtained in step (k) to generate heat for the reactor.

5. A method according to claim 1, including the step of:

(m) producing superheatod steam for use in step (g) by heating water from burning flue gases generated in the reactor.

6. A method according to claim 1, including the steps of:

(n) separating gases and liquid from the mixture obtained in step (h);

(o) passing the liquid obtained in step (n) for vis-breaking in step (a); and

(p) mixing the gases obtained in step (n) with the gas and vapor obtained in step (c) for condensing in step (d).