Multi-layer low emissivity thin film coating

• US 4,883,721 A
• Filed: 07/24/1987
• Issued: 11/28/1989
• Est. Priority Date: 07/24/1987
• Status: Expired due to Term

• Current Assignee: Guardian Glass LLC (KOCH Industries Incorporated)
• Original Assignee: Guardian Industries Corporation (KOCH Industries Incorporated)
• Inventors: Nalepka, Raymond, Huffer, Russell
• Primary Examiner(s): Rutledge, L. Dewayne
• Assistant Examiner(s): Wyszomierski, George
• Application Number:
  US07/077,226
• Time in Patent Office: 858 Days
• Field of Search: 428/622, 428/623, 428/630, 428/632, 428/633, 428/673, 428/34, 428/434
• US Class Current: 428/623
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3618 Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
• CPC Class Codes: C03C 17/3644 the metal being silver
• CPC Class Codes: C03C 17/3652 the coating stack containing at least one sacrificial layer to protect the metal from oxidation
• CPC Class Codes: C03C 17/366 Low-emissivity or solar control coatings
• CPC Class Codes: C03C 17/3681 the multilayer coating being used in glazing, e.g. windows or windscreens
• CPC Class Codes: E06B 3/6715 specially adapted for increased thermal insulation or for controlled passage of light E06B3/66323 takes precedence; coating of glass pains C03C17/00; devices or arrangements for controlling the intensity, colour, phase, polarisation or direction of light G02F1/00
• CPC Class Codes: Y10T 428/12549 Adjacent to each other
• CPC Class Codes: Y10T 428/12597 Noncrystalline silica or noncrystalline plural-oxide component [e.g., glass, etc.]
• CPC Class Codes: Y10T 428/12611 Oxide-containing component
• CPC Class Codes: Y10T 428/12618 Plural oxides
• CPC Class Codes: Y10T 428/12896 Ag-base component

Abstract

A multi-layer of thin film for application to a transparent substrate such as glass provides excellent visible light transmission while controlling both near infra-red solar energy and far infra-red reflected energy. The film comprises a layer of sputtered zinc, tin, or bismuth oxide, a layer of sputtered silver or silver alloy, a layer of sputtered titanium or stainless steel and a final layer of zinc, tin, or bismuth oxide. The product exhibits a nominal visible light transmittance of 55% and a reflectance less than about 15% for incident light on the substrate (glass) side at visible light wavelengths and reflectance less than about 6% for incident light on the film side in the visible wavelengths. Emissivity is less than 0.15. A method of fabricating the product is also disclosed.

Claims

1. In a multi-layer thin film for glass and other transparent substrates, the improvement comprising a first metallic oxide layer selected from the group consisting of zinc, tin, titanium, indium/tin and bismuth, a second layer selected from the group consisting of silver and silver alloy, a third layer selected from the group consisting of titanium and stainless steel and a fourth metallic oxide layer having a thickness of at least 100 Angstroms selected from the group consisting of zinc, tin, titanium, indium/tin and bismuth, wherein said thin film exhibits visible light transmittance of at least 50% and emissivity of less than 0.15.

2. The improvement of claim 1 wherein said first layer is between about 400 and 500 Angstroms in thickness.

3. The improvement of claim 1 wherein said second layer is between about 100 and 200 Angstroms in thickness.

4. The improvement of claim 1 wherein said third layer is about 100 Angstroms in thickness.

5. The improvement of claim 1 wherein said fourth layer is between about 400 and 500 Angstroms in thickness.

6. The improvement of claim 1 wherein said first layer is about 450 Angstroms in thickness.

7. The improvement of claim 1 wherein said fourth layer is about 450 Angstroms in thickness.

8. The improvement of claim 1 wherein said multi-layer thin film reflects about 15% of the incident visible radiation to the outside and absorbs about 35% of such incident visible radiation.

9. The improvement of claim 1 wherein said multi-layer thin film reflects about 6% of the incident visible radiation to the inside.

10. The improved multi-layer thin film of claim 1 wherein the substrate side reflectance is less than about 15%.

14. The radiation controlling thin film of claim 10 wherein said film reflects about 6% of the incident visible radiation to the inside and at least 70% of the incident radiation in the far infra-red toward said inside.

15. The radiation controlling thin film of claim 10 wherein said film reflects about 15% of the incident visible radiation to the outside and absorbs about 35% of such incident visible radiation.

17. The radiation controlling thin film of claim 10 wherein said substrate side reflectance is less than about 15%.

11. A radiation controlling thin film disposed on one surface of a transparent substrate, said thin film comprising, in combination,

a first metallic oxide layer selected from the group consisting of zinc, tin, titanium, indium/tin and bismuth,

a second metallic layer selected from the group consisting of silver and silver alloy,

a third metallic layer selected from the group consisting of stainless steel and titanium, and

a fourth metallic oxide layer having a thickness of at least 100 Angstroms selected from the group consisting of zinc, tin, titanium, indium/tin and bismuth,

wherein said thin film exhibits visible light transmittance of at least 50% and emissivity of less than 0.15.

12. The radiation controlling thin film of claim 11 wherein said first and said fourth metallic layer are between about 400 and 500 Angstroms in thickness.

13. The radiation controlling thin film of claim 11 wherein said second layer is between about 100 and 200 Angstroms in thickness and said third layer is about 100 Angstroms in thickness.

16. The radiation controlling thin film of claim 11 wherein said one surface on said transparent substrate is disposed more proximate the occupied space of a building and further including a transparent sheet article disposed between said thin film and said occupied space.

18. An improved radiation controlling product comprising, in combination,

a transparent substrate,

a plurality of thin layers disposed on one face of said substrate, said plurality of layers including

a first metallic oxide layer selected from the group consisting of zinc, tin, titanium, indium/tin and bismuth,

a second metallic layer selected from the group consisting of silver and silver alloys,

a third metallic layer selected from the group consisting of stainless steel and titanium and

a fourth metallic oxide layer having a thickness of at least 100 Angstroms selected from the group consisting of zinc, tin, titanium, indium/tin and bismuth.

19. The radiation controlling product of claim 18 wherein said first layer is between about 400 and 500 Angstroms in thickness.

20. The radiation controlling product of claim 18 wherein said second layer is between about 100 and 200 Angstroms in thickness.

21. The radiation controlling product of claim 18 wherein said third layer is about 100 Angstroms in thickness.

22. The radiation controlling product of claim 18 wherein said fourth layer is between about 400 and 500 Angstroms in thickness.

23. The radiation controlling product of claim 18 wherein said stainless steel is type 316.

24. The radiation controlling product of claim 18 wherein said silver alloy comprises 5 to 10% copper with the remainder being silver.

25. The radiation controlling product of claim 18 wherein said product provides a visible light transmittance of at least 50% and an emissivity of less than 0.15.

26. the improved radiation controlling thin film of claim 18 wherein the substrate side reflectance is less than about 15%.