Method for producing metal carbide grade powders

• US 4,886,638 A
• Filed: 07/24/1989
• Issued: 12/12/1989
• Est. Priority Date: 07/24/1989
• Status: Expired due to Term

• Current Assignee: Global Tungsten & Powders Corporation (Flatlake Privatstiftung)
• Original Assignee: GTE Products Corporation
• Inventors: Smith, Theodore E., Burwick, Jack L., Penkunas, Joseph J.
• Primary Examiner(s): Lechert, Jr., Stephen J.
• Application Number:
  US07/384,199
• Time in Patent Office: 141 Days
• Field of Search: 75/0.5 BC, 419/15, 419/14, 419/33, 419/36, 419/37, 419/40
• US Class Current: 419/15
• CPC Class Codes: C22C 1/1084 by mechanical alloying (blending, milling)

Abstract

A method is disclosed for producing metal carbide grade powders, which comprises dry milling metal carbide powder which can be tungsten carbide, titanium carbide, tantalum carbide, niobium carbide, vanadium carbide, chromium carbide, and combinations thereof to increase the surface area of the powder particles to result in essetially all of the powders being converted to single crystals, forming a mixture of the resulting dry milled carbide powder, a binder metal which can be cobalt, nickel, and combinations thereof, and a wax, while heating the carbide powder, the binder metal and the wax to a temperature above the melting point of the wax and maintaining the temperature to result in a uniform distribution of the wax on the carbide and binder metal particles, forming a slurry of the mixture and water, attritor milling the slurry at a temperature below the melting point of the wax, and removing the water from the resulting attritor milled mixture and aggiomerating the mixture to produce the metal carbide grade powder wherein a densified article made therefrom exhibits essentially no pores that are greater than about 10 micrometers in diameter after sintering at from about 1350° C. to about 1540° C.

Claims

1. A method for producing metal carbide grade powders, said method comprising:

(a) dry milling metal carbide powder selected from the group consisting of tungsten carbide, titanium carbide, tantalum carbide, niobium carbide, vanadium carbide, chromium carbide, and combinations thereof to increase the surface area of the powder particles to result in essentially all of said powders being converted to single crystals;

(b) forming a mixture of the resulting dry milled carbide powder, a binder metal selected from the group consisting of cobalt, nickel, and combinations thereof, and a wax while heating said carbide powder, said binder metal and said wax to a temperature above the melting point of said wax and maintaining said temperature to result in a uniform distribution of said wax on said carbide and binder metal particles;

(c) forming a slurry of said mixture and water;

(d) attritor milling said slurry at a temperature below the melting point of said wax; and

(e) removing the water from the resulting attritor milled mixture and agglomerating said mixture to produce said metal carbide grade powder wherein a densified article made therefrom exhibits essentially no pores that are greater than about 10 micrometers in diameter after sintering at from about 1350°

C. to about 1540°

C.