Process for preparing an aqueous dispersion

• US 4,886,852 A
• Filed: 10/07/1988
• Issued: 12/12/1989
• Est. Priority Date: 10/12/1987
• Status: Expired due to Fees

• Current Assignee: Kansai Paint Company Limited
• Original Assignee: Kansai Paint Company Limited
• Inventors: Numa, Nobushige
• Primary Examiner(s): Schofer, Joseph L.
• Assistant Examiner(s): SMITH, JEFFREY
• Application Number:
  US07/254,625
• Time in Patent Office: 431 Days
• Field of Search: 524/521, 524/458, 525/288
• US Class Current: 524/458
• CPC Class Codes: C08F 2/08 with the aid of dispersing agents for the polymer
• CPC Class Codes: C08J 3/03 in aqueous media

Abstract

A process for preparing an aqueous dispersion, the process being characterized by comprising the steps of (i) preparing a nonaqueous dispersion of polymer particles by polymerizing a radically polymerizable unsaturated monomer (A) in an organic solvent, in which the polymer particles are insoluble, in the presence of, as a dispersion stabilizer resin, a copolymer which is prepared by copolymerizing an alkoxysilane group-containing vinyl monomer represented by the formula ##STR1## (wherein A is a group ##STR2## R₁ is a hydrogen atom or methyl group, R₂ is a saturated bivalent aliphatic hydrocarbon group having 1 to 6 carbon atoms, R₃ and R₄ are the same or different and each represent a phenyl group, alkyl group having 1 to 6 carbon atoms or alkoxy group having 1 to 10 carbon atoms, R₅ is an alkyl group having 1 to 10 carbon atoms, and n is an integer of 1 to 100), a carboxyl group-containing unsaturated monomer and other polymerizable monomer (B) copolymerizable with these monomers; and (ii) converting the nonaqueous dispersion to an aqueous dispersion.

Claims

1. A process for preparing an aqueous dispersion, comprising the steps of (i) preparing a nonaqueous dispersion of polymer particles by polymerizing a radically polymerizable unsaturated monomer, (A) in an organic solvent, in which the polymer particles prepared from unsaturated monomer (A) are insoluble, in the presence of a dispersion stabilizer resin comprising a copolymer prepared by copolymerizing an alkoxysilane group-containing vinyl monomer represented by the formula ##STR11## wherein Z is a group ##STR12## R₁ is a hydrogen atom or methyl group, R₂ is a straight- or branched-chain alkylene group having 1 to 6 carbon atoms, R₃ and R₄ are the same or different and each represent a phenyl group, straight- or branched-chain alkyl group having 1 to 6 carbon atoms or straight- or branched-chain alkoxy group having 1 to 10 carbon atoms, R₅ is a straight- or branched-chain alkyl group having 1 to 10 carbon atoms, and n is an integer of 1 to 10, with a carboxyl group-containing unsaturated monomer and a polymerizable monomer (B);

the unsaturated monomer (A) being at least one monomer selected from the group consisting of C₁ -C₁₈ alkyl esters or C₁ -C₁₈ cycloalkyl esters of acrylic or methacrylic acids, alkoxyalkyl esters of acrylic or methacrylic acids, hydroxyalkyl esters of acrylic or methacrylic acids, esters of aromatic alcohol with acrylic or methacrylic acid, addition products of glycidyl acrylate, glycidyl methacrylate or hydroxyalkyl ester of acrylic or methacrylic acid with C₂ -C₁₈ monocarboxylic acid compound, addition products of acrylic or methacrylic acid with monoepoxy compound, vinyl aromatic compounds, mono- or di-esters of α

, β

-unsaturated carboxylic acids with mono-alcohol having 1 to 18 carbon atoms, acrylates or methacrylates having fluorine atom at the side chain, fluorine-containing unsaturated compounds, vinyl esters, vinyl ethers, α

-olefin type compounds and cyano group-containing unsaturated compounds,

the carboxyl group-containing unsaturated monomer being at least one monomer selected from the group consisting of acrylic acid, methacrylic acid, crotonic acid, maleic acid, maleic anhydride, itaconic acid, itaconic anhydride, fumaric acid and citraconic acid, and

the polymerizable monomer (B) being at least one monomer selected from the group consisting of C₁ -C₁₈ alkl esters or C₁ -C₁₈ cycloalkyl esters of acrylic or methacrylic acids, alkoxyalkyl esters of acrylic or methacrylic acids, hydroxyalkyl esters of acrylic or methacrylic acids, esters of aromatic alcohol with acrylic or methacrylic acid, addition products of glycidyl acrylate, glycidyl methacrylate or hydroxyalkyl ester of acrylic or methacrylic acid with C₂ -C₁₈ monocarboxylic acid compound, addition products of acrylic or methacrylic acid with monoepoxy compound, vinyl aromatic compounds, mono- or di-esters of α

, β

-unsaturated carboxylic acids with mono-alcohol having 1 to 18 carbon atoms, acrylates or methacrylates having fluorine atom at the side chain, fluorine-containing unsaturated compounds, vinyl esters, vinyl ethers, α

-olefin type compounds; and

(ii) converting the nonaqueous dispersion to an aqueous dispersion.

2. A process according to claim 1 wherein the copolymer used as the dispersion stabilizer resin is one prepared from about 1 to about 90% by weight of the monomer of the formula (I), about 1 to about 25% by weight of the carboxyl group-containing unsaturated monomer and about 9 to about 98% by weight of the polymerizable monomer (B) based on the total amount of the monomers.

3. A process according to claim 2 wherein the copolymer used as the dispersion stabilizer resin is one prepared from about 5 to about 50% by weight of the monomer of the formula (I), about 2 to about 20% by weight of the carboxyl group-containing unsaturated monomer and about 30 to about 93% by weight of the polymerizable monomer (B) based on the total amount of the monomers.

4. A process according to claim 1 wherein the copolymer used as the dispersion stabilizer resin has a number-average molecular weight of about 1,000 to about 60,000.

5. A process according to claim 4 wherein the copolymer used as the dispersion stabilizer resin has a number-average molecular weight of about 1,000 to about 30,000.

6. A process according to claim 1 wherein the nonaqueous dispersion is converted to an aqueous one by neutralizing the nonaqueous dispersion with a basic substance in an amount of about 0.1 to about 1.5 equivalents per equivalent of the free carboxyl group contained in the nonaqueous dispersion, and adding water to the neutralized nonaqueous dispersion or adding the neutralized nonaqueous dispersion to water.

7. A process according to claim 1 wherein the nonaqueous dispersion is converted to an aqueous one by adding water to the nonaqueous dispersion to change the nonaqueous dispersion to an aqueous one, and adding a basic substance in an amount of about 0.1 to about 1.5 equivalents per equivalent of the free carboxyl group contained in the dispersion.

8. A process according to claim 1 wherein the aqueous dispersion has a solids concentration of about 1 to about 70% by weight.

9. A process according to claim 1 wherein the compound of formula (I) is at least one of γ

-acryloxyethyl trimethoxysilane, γ

-methacryloxyethyl trimethoxysilane, γ

-acryloxypropyl trimethoxysilane, γ

-methacryloxypropyl trimethoxysilane, γ

-acryloxypropyl triethoxysilane, γ

-methacryloxypropyl triethoxysilane, γ

-acryloxypropyl tripropoxysilane, γ

-methacryloxypropyl tripropoxysilane, γ

-acryloxypropyl methyldimethoxysilane, γ

-methacryloxyproply methyldimethoxysilane, γ

-acryloxyproply methyldiethoxysilane, γ

-methacryloxypropyl methyldiethoxysilane, γ

-acryloxypropyl methyldipropoxysilane, γ

-methacryloxypropyl methyldipropoxysilane, γ

-acryloxybutyl phenyldimethoxysilane, γ

-methacryloxybutyl phenyldimethoxysilane, γ

-acryloxybutyl phenyldiethoxysilane, γ

-methacryloxybutyl phenyldiethoxysilane, γ

-acryloxybutyl phenyldipropoxysilane, γ

-methacryloxybutyl phenyldipropoxysilane, γ

-acryloxypropyl dimethylmethoxysilane, γ

-methacryloxypropyl dimethylmethoxysilane, γ

-acryloxypropyl dimethylethoxysilane, γ

-methacryloxypropyl dimethylethoxysilane, γ

-acryloxypropyl diphenylmethylmethoxysilane, γ

-methacryloxypropyl diphenylmethylmethoxysilane γ

-acryloxypropyl diphenylmethylethoxysilane, γ

-methacryloxypropyl diphenylmethylethoxysilane, ##STR13##