Liquid crystal polyester resin composition having excellent surface characteristics

• US 4,888,127 A
• Filed: 12/02/1987
• Issued: 12/19/1989
• Est. Priority Date: 12/10/1986
• Status: Expired due to Term

• Current Assignee: Polyplastics Co., Ltd. (Daicel Corporation)
• Original Assignee: Polyplastics Co., Ltd. (Daicel Corporation)
• Inventors: Ishikawa, Takayuki, Wada, Mitsuo, Kanoe, Toshio
• Primary Examiner(s): Kalafut, Stephen J.
• Application Number:
  US07/127,413
• Time in Patent Office: 748 Days
• Field of Search: 252/299.01, 252/299.62, 523/220, 523/513, 524/847
• US Class Current: 252/299.5
• CPC Class Codes: C08K 2201/016 Additives defined by their aspect ratio
• CPC Class Codes: C08K 3/013 Fillers, pigments or reinforcing additives
• CPC Class Codes: C08L 67/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds C08L67/06 takes precedence
• CPC Class Codes: C09K 19/3838 Polyesters; Polyester derivatives
• CPC Class Codes: C09K 2019/521 Inorganic solid particles

Abstract

A liquid crystal polyester composition having an improved resistance to deformation comprising 99.5 to 30 percent by weight of a polyester which is melt-processable and capable of forming an anisotropic phase in the melt state and 0.5 to 7 percent by weight of filler particles.

Claims

1. A liquid crystal polyester composition, having excellent surface characteristics, which comprises 99.5 to 30 percent by weight of a polyester and 0.5 to 70 percent by weight of a particulate filler material having an aspect ratio of up to 3 and an average particulate diameter of 1 to 50 μ

m, the polyester being of a type which is melt processable and which, in the molten state, displays anisotropy.

2. The composition as claimed in claim 1, wherein said particulate filler material is at least one member selected from the group consisting of alumina, silica, barium sulfate, glass bead, glass powder, an organic high molecular fluorocarbon resin, and organic low-molecular crystals of brominated diphenyl ether.

3. The composition as claimed in claim 2 wherein the aspect ratio of the particulate filler material is in the range of 1 to 2.

4. The composition as claimed in claim 1 wherein fibrous material is incorporated together with the particulate filler material.

5. The composition as claimed in claim 4, wherein the fibrous material is incorporated in an amount equal to or less than that of said particulate filler material.

6. The composition as claimed in claim 4 wherein the fibrous material has an aspect ratio of 5 to 70.

7. The liquid crystal polyester resin composition according to claim 4, wherein the fibrous material is at least one fiber selected from the group consisting of glass fiber, carbon fiber, graphitized fiber, whisker, metallic fiber, inorganic fiber, synthetic fiber, and mineral fiber.

8. The composition according to claim 4 wherein the total weight of the particulate filler material and the fibrous material is not more than 70% by weight based on the total weight of the composition.

9. The composition of claim 1 wherein the polyester is composed of at least one member selected from the group consisting of aromatic dicarboxylic acids and alicyclic dicarboxylic acids and at least one member selected from the group consisting of aromatic diols, alicyclic diols, and aliphatic diols.

10. The composition of claim 1 wherein the polyester is composed of aromatic hydroxy carboxylic acids.

11. The composition of claim 1 wherein the polyester is composed of at least one member selected from the group consisting of aromatic dicarboxylic acids and alicyclic dicarboxylic acids, at least one member selected from the group consisting of aromatic diols, and aromatic hydroxy carboxylic acids.

12. The composition of claim 1 wherein the polyester is composed of at least one member selected from the group consisting of aromatic dicarboxylic acids and alicyclic dicarboxylic acids, at least one member selected from the group consisting of aromatic diols, aromatic hydroxy carboxylic acids, and at least one member selected from the group consisting of aromatic hydroxy amines and aromatic diamines.

13. The composition of claim 1 wherein the liquid crystal polyester has a weight--average molecular weight of about 2,000 to 200,000.

14. The composition of claim 1 wherein the liquid crystal polyester possesses an inherent viscosity of at least about 2.0 dl/g to 10.0 dl/g.

15. A liquid crystal polyester composition having excellent surface characteristics which comprises 99.5 to 30 percent by weight of a polyester and 0.5 to 70 percent by weight of a particulate filler material having an aspect ratio of up to 3 and an average particle size of 0.1 to 100 μ

m, said particulate filler material having a fibrous material incorporated therewith, said polyester being of a type which is melt processable and which, in the molten, state displays anisotropy.

16. The composition as claimed in claim 15, wherein said particulate filler material is at least one member selected from the group consisting of alumina, silica, barium sulfate, glass bead, glass powder, an organic high molecular fluorocarbon resin, and organic low-molecular crystals of brominated diphenyl ether.

17. The composition as claimed in claim 15 wherein the aspect ratio of the particulate filler material is in the range of 1 to 2.

18. The composition as claimed in claim 15, wherein the average particulate diameter of the particulate filler material is 1 to 50 μ

m.

19. The composition as claimed in claim 15, wherein the fibrous material is incorporated in an amount equal to or less than that of said particulate filler material.

20. The composition as claimed in claim 15, wherein the fibrous material has an aspect ratio of 5 to 70.

21. The liquid crystal polyester resin composition according to claim 16, wherein the fibrous material is at least one fiber selected from the group consisting of glass fiber, carbon fiber, graphitized fiber, whisker, metallic fiber, inorganic fiber, synthetic fiber, and mineral fiber.

22. The composition according to claim 15, wherein the total weight of the particulate filler material and the fibrous material is not more than 70% by weight based on the total weight of the composition.

23. The composition of claim 15, wherein the polyester is composed of at least one member selected from the group consisting of aromatic dicarboxylic acids and alicyclic dicarboxylic acids and at least one member selected from the group consisting of aromatic diols, alicyclic diols, and aliphatic diols.

24. The composition of claim 15, wherein the polyester is composed of aromatic hydroxy carboxylic acids.

25. The composition of claim 15, wherein the polyester is composed of at least one member selected from the group consisting of aromatic dicarboxylic acids and alicyclic dicarboxylic acids, at least one member selected from the group consisting of aromatic diols, and aromatic hydroxy carboxylic acids.

26. The composition of claim 15, wherein the polyester is composed of at least one member selected from the group consisting of aromatic dicarboxylic acids and alicyclic dicarboxylic acids, at least one member selected from the group consisting of aromatic diols, aromatic hydroxy carboxylic acids, and at least one member selected from the group consisting of aromatic hydroxy amines and aromatic diamines.

27. The composition of claim 15, wherein the liquid crystal polyester has a weight--average molecular weight of about 2,000 to 200,000.

28. The composition of claim 15, wherein the liquid crystal polyester possesses an inherent viscosity of at least about 2.0 dl/g to 10.0 dl/g.