Pressure-sensitive microcapsule sheet

• US 4,888,334 A
• Filed: 04/19/1988
• Issued: 12/19/1989
• Est. Priority Date: 04/20/1987
• Status: Expired due to Term

• Current Assignee: Fujifilm Corporation (Fujifilm Holdings Corporation)
• Original Assignee: Fuji Photo Film Co Limited (Fujifilm Holdings Corporation)
• Inventors: Ohga, Kunihiko, Saeki, Keiso
• Primary Examiner(s): Hess, Bruce H.
• Application Number:
  US07/183,104
• Time in Patent Office: 609 Days
• Field of Search: 427/150-152, 428/913, 428/914, 503/214, 503/215
• US Class Current: 503/214
• CPC Class Codes: B41M 5/132 Chemical colour-forming components; Additives or binders therefor
• CPC Class Codes: Y10S 428/914 Transfer or decalcomania

Abstract

A pressure-sensitive microcapsule sheet comprising a support having thereon a pressure-sensitive layer comprising microcapsules and a binder comprising a copolymer latex composed of at least two monomers selected from the group consisting of an aliphatic conjugated diolefin monomer, an aromatic vinyl monomer and an ethylenically unsaturated nitrile monomer and an ethylenically unsaturated acid amide monomer. The sheet is free from color stain and fog during printing.

Claims

1. A pressure-sensitive microcapsule sheet comprising a support having thereon a pressure-sensitive layer comprising microcapsule containing an electron donating color former dissolved in a solvent and a binder comprising a copolymer latex comprising an ethylenically unsaturated acid amide monomer and at least one monomer selected from the group consisting of an aliphatic conjugated diolefin monomer, an aromatic vinyl monomer, and an ethylenically unsaturated nitrile monomer.

2. The pressure-sensitive microcapsule sheet as claimed in claim 1, wherein said copolymer latex comprises from about 15 to 70 wt % of said aliphatic conjugated diolefin monomer, from about 10 to 70 wt % of said aromatic vinyl monomer, from about 0.5 to 20 wt % of said ethylenically unsaturated acid amide monomer and from about 3 to 30 wt % of said ethylenically unsaturated nitrile monomer.

3. The pressure-sensitive microcapsule sheet as claimed in claim 2, wherein said copolymer latex comprises from about 30 to 60 wt % of said aliphatic conjugated diolefin monomer, from about 20 to 60 wt % of said aromatic vinyl monomer, from about 3 to 15 wt % of said ethylenically unsaturated acid amide monomer and from about 5 to 20 wt % of said ethylenically unsaturated nitrile monomer.

4. The pressure-sensitive microcapsule sheet as claimed in claim 3, wherein said aliphatic conjugated diolefin monomer is selected from the group consisting of 1,3-butadiene, 2-methyl-1,3-butadiene, 2,3-dimethyl1,3-butadiene, and a butadiene substituted with a halogen;

said aromatic vinyl monomer is selected from the group consisting of styrene, α

-methylstyrene, vinyltoluene and monochlorostyrene;

said ethylenically unsaturated acid amide monomer is selected from the group consisting of acrylic acid amide, N-methylolacrylamide, methacrylic acid amide, crotonic acid amide, cinnamic acid amide, itaconic acid amide, fumaric acid amide, maleic acid amide, itaconic acid amide monoethylester, fumaric acid amide monoethylester and maleic acid amide monoethylester; and

said ethylenically unsaturated nitrile monomer is selected from the group consisting of acrylonitrile, methacrylonitrile and α

-chloroacrylonitrile.

5. The pressure-sensitive microcapsule sheet as claimed in claim 2, wherein said copolymer latex further comprises a copolymerizable olefinic monomer.

6. The pressure-sensitive microcapsule sheet as claimed in claim 5, wherein said copolymerizable monomer is selected from the group consisting of methyl acrylate, methyl methacrylate, ethyl acrylate, butyl acrylate, glycidyl acrylate, glycidyl methacrylate, acrolein, allyl alcohol, divinylbenzene, diallyl phthalate, diallyl maleate, triallyl cyanurate, ethylene glycol dimethacrylate, allyl acrylate and vinylpyridine.

7. The pressure-sensitive microcapsule sheet as claimed in claim 1, comprising from about 10 to 90 parts by weight of said copolymer latex per 100 parts by weight of said microcapsules.

8. The pressure,-sensitive microcapsule sheet as claimed in claim 7, comprising from about 15 to 70 parts by weight of said copolymer latex per 100 parts by weight of said microcapsules.

9. The pressure-sensitive microcapsule sheet as claimed in claim 1, wherein said microcapsules are pressure-rupturable microcapsules.

10. The pressure-sensitive microcapsule sheet as claimed in claim 9, wherein said color former is selected from the group consisting of a triarylmethane compound, a diphenylmethane compound, a xanthene compound, a thiazine compound, a spiro compound, and a mixture of these compounds.

11. A pressure-sensitive recording material comprising (a) a pressure-sensitive microcapsule sheet comprising a support having thereon a pressure-sensitive layer comprising microcapsules containing a color former dissolved in a solvent and a binder comprising a copolymer latex comprising an ethylenically un saturated acid amide misnomer and at least two monomer selected from the group consisting of an aliphatic conjugated diolefin monomer, an aromatic vinyl monomer, and an ethylenically unsaturated nitrile monomer, and (b) a recording layer comprising a binder and a developer capable of reacting with said color former to form a colored image, said recording layer being adjacent to said pressure-sensitive layer.