Light modulating device

• US 4,889,414 A
• Filed: 09/25/1985
• Issued: 12/26/1989
• Est. Priority Date: 08/21/1984
• Status: Expired due to Term

• Current Assignee: EIC Laboratories Incorporated Norwood Massachusetts
• Original Assignee: EIC Laboratories, Inc.
• Inventors: Goldner, Ronald B., Rauh, R. David
• Primary Examiner(s): LaRoche, Eugene R.
• Assistant Examiner(s): Shingleton, Michael
• Application Number:
  US06/779,872
• Time in Patent Office: 1,553 Days
• Field of Search: 350/357, 350/355, 252/600
• US Class Current: 359/273
• CPC Class Codes: G02F 1/1524 Transition metal compounds
• CPC Class Codes: G02F 2203/02 reflective
• CPC Class Codes: G02F 2203/11 involving infrared radiation

Abstract

In a device for transmitting light, means for controlling the transmissivity of the device, including a ceramic, reversibly electrochromic, crystalline element having a highly reflective state when injected with electrons and charge compensating ions and a highly transmissive state when the electrons and ions are removed, the crystalline element being characterized as having a reflectivity of at least 50% in the reflective state and not greater than 10% in the transmissive state, and means for modulating the crystalline element between the reflective and transmissive states by injecting ions into the crystalline element in response to an applied electrical current of a first polarity and removing the ions in response to an applied electrical current of a second polarity.

Claims

1. A device for transmitting light comprising means for controlling the transmissivity of said device,

said transmissivity controlling means comprising

(a) a ceramic, reversibly electrochromic, crystalline element having a highly reflective state when injected with electrons and charge compensating ions and a highly transmissive state when said electrons and said ions are removed,

said crystalline element being characterized as having a reflectivity of at least 50% in said reflective state and not greater than 10% in said transmissive state, and

(b) means for modulating said crystalline element between said reflective and said transmissive states by injecting ions into said crystalline element in response to an applied electrical current of a first polarity and removing said ions in response to an applied electrical current of a second polarity.

2. The device of claim 1 wherein said crystalline element is so characterized by exhibiting a degree of crystalline order, sufficient to ensure said reflectivity of at least 50% when said crystalline element is injected with said electrons and said charge compensating ions.

3. The device of claim 1 wherein said crystalline element is so characterized by being sufficiently free of crystalline defects to ensure said reflectivity of at least 50% when said crystalline element is injected with said electrons and said charge compensating ions.

4. The device of claim 1 wherein the orientation of the highest mobility crystallite faces of said crystalline element is characterized as being sufficiently uniform and transverse to the incident light beam to ensure said reflectivity of at least 50% when said crystalline element is injected with said electrons and said charge compensating ions.

5. The device of claim 1 wherein the chemical composition of said crystalline element is so characterized by being sufficiently close to stoichiometric to ensure said reflectivity of at least 50% when said crystalline element is injected with said electrons and said charge compensating ions.

6. The device of claim 5 wherein said chemical composition of said crystalline element is WO_x.

7. The device of claim 5 wherein X is between 2.8 and 3, inclusive.

8. The device of claim 1 wherein said modulating means is a ceramic element.

9. The device of claim 8 wherein said ceramic element is an amorphous, reversibly electrochromic compound capable of anodically injecting ions.

10. The device of claim 9 wherein said ceramic element is IrO₂.

11. The device of claim 8 wherein said ceramic element is an amorphous, weakly electrochromic compound capable of cathodically injecting ions.

12. The device of claim 11 wherein said ceramic element is Nb₂ O₅.

13. The device of claim 1 wherein said modulating means is chosen from the group consisting of SnO_2-x ;

SnO_2-x doped with Sb, F, or In;

In₂ O_3-x ;

In₂ O_3-x doped with Sn, F, or Cd;

In₂ O_3-x /SnO_2-x alloys doped with Sn, Sb, F, In, or Cd; and

glass substrates coated with said SnO_2-x, said doped SnO_2-x, said In₂ O_3-x, said doped In₂ O_3-x, or said doped In₂ O_3-x /SnO_2-x alloys.

14. The device of claim 1 further comprising an electrically insulating element capable of conducting ions between said crystalline element and said modulating means.

15. The device of claims 1 or 13 wherein said modulating means forms an outermost portion of said device.

16. The device of claim 1 wherein said crystalline element forms an outermost portion of said device.

17. The device of claims 1 or 13 wherein said modulating means and said crystalline element each form a separate outermost portion of said device.

18. The device of claim 14 wherein said electrically insulating element is LiAlF₄.

19. The device of claim 1 further comprising means for applying said electrical currents of first and second polarities.

20. The device of claim 1 further comprising a first transparent electrode in contact with said crystalline element and a second transparent electrode in contact with said modulating means.

21. The device of claim 20 wherein said first transparent electrode and said second transparent electrode, independently, are chosen from the group consisting of SnO_2-x ;

SnO_2-x doped with Sb, F, or In;

In₂ O_3-x ;

In₂ O_3-x doped with Sn, F, or Cd;

In₂ O_3-x SnO_2-x alloys doped with Sn, Sb, F, In, or Cd; and

glass substrates coated with said SnO_2-x, said doped SnO_2-x, said In₂ O_3-x, said doped In₂ O_3-x, or said doped In₂ O_3-x /SnO_2-x alloys.

22. The device of claim 1 wherein said device is deposited on a transparent substrate.

23. The device of claim 1 wherein said device is sandwiched between two transparent substrates.

24. The device of claim 1 wherein said crystalline element and said modulating means are substantially continuous films.

25. A method for producing a ceramic, reversibly electrochromic, crystalline element having a highly reflective state when injected with electrons and charge compensating ions and a highly transmissive state when said electrons and said ions are removed, said crystalline element being characterized as having a reflectivity of at least 50% in said reflective state and not greater than 10% in said transmissive state,

said method comprising the steps of

sputtering a compound onto a heated substrate, the temperature of said substrate being sufficient to cause crystallization of said compound as deposited in substantially oriented and ordered form, from a sputtering target comprising said compound to be deposited,

said sputtering being conducted by means of a radio frequency plasma in an atmosphere comprising an inert gas and a reactive gas capable of being incorporated into said compound as deposited, said reactive gas being present in an amount sufficient to produce said crystalline element in substantially stoichiometric, oriented, and ordered form,

wherein said stoichiometry, said order, and said orientation are so characterized by being sufficient to ensure a reflectivity of at least 50% when said crystalline element is injected with electrons and charge compensating ions.

26. The method of claim 25 wherein the chemical composition of said crystalline element is WO_x where X is between 2.8 and 3, inclusive.

27. The method of claim 25 wherein the power of said radio frequency plasma is between 1.7 and 2.2 watts/cm².