Flow cell

• US 4,889,611 A
• Filed: 11/23/1988
• Issued: 12/26/1989
• Est. Priority Date: 05/15/1987
• Status: Expired due to Term

• Current Assignee: Beckman Instruments, Inc. (Danaher Corporation)
• Original Assignee: Beckman Instruments, Inc. (Danaher Corporation)
• Inventors: Blough, William M. Jr.
• Primary Examiner(s): Niebling, John F.
• Assistant Examiner(s): Gorgos, Kathryn
• Application Number:
  US07/277,477
• Time in Patent Office: 398 Days
• Field of Search: 204/409, 204/412, 204/416, 204/418, 204/419, 204/420
• US Class Current: 204/411
• CPC Class Codes: G01N 27/403 Cells and electrode assemblies

Abstract

An ion selective electrode flow cell includes a first fluid conduit and at least two ion sensing electrodes each having ion sensing surfaces disposed within the first fluid conduit. A second fluid conduit and an ion sensing electrode having an ion sensing tip is disposed within the second conduit. There is an electrically conducting bridge connecting the first and second fluid conduits. A conductive member is disposed within the first fluid conduit proximate the ion sensing surfaces of two ion sensing electrodes and the bridge. A third fluid conduit may intersect the first fluid conduit and can include grounding for grounding fluid flowing through the third fluid conduit. Capacitors between exit and entry ports of the first and second fluid conduits and ground reduce electrical noise within the flow cell.

Claims

1. An improved ion selective electrode flow cell comprising:

a first fluid conduit;

at least two ion sensing electrodes each having an ion sensing surface disposed within the first fluid conduit;

a second fluid conduit;

an ion sensing electrode having an ion sensing surface disposed within the second conduit;

an electrically conducting bridge connecting the first and second fluid conduits; and

a conductive member other than electrodes, having at least portions thereof disposed in the first fluid conduit proximate the ion sensing surfaces of the at least two ion sensing electrodes and the bridge.

2. A flow cell as in claim 1 wherein the flow cell further includes a third fluid conduit intersecting the first fluid conduit;

and

grounding means for grounding fluid flowing through the third fluid conduit.

3. A flow cell as in claim 2 wherein the cell includes capacitor means connected between ground and entry and exit ports of each of the first and second fluid conduits.

4. A flow cell as in claim 1 wherein the conductive member comprises a conducting metallic wire disposed in the first fluid conduit.

5. A flow cell as in claim 4 wherein the material comprising the conductive metallic wire is selected from a group including gold, platinum and rhodium.

6. A flow cell as in claim 1 wherein the conductive member includes conductive metallic plating deposited on the first fluid conduit.

7. A flow cell as in claim 1 further including means for grounding the first conduit at a point along the first fluid conduit proximate the conductive member.

8. A flow cell as in claim 1 further including means for providing a low impedance path from the conductive member to ground.

9. An improved ion selective electrode flow cell comprising:

a flow cell body;

a first fluid conduit formed in the flow cell body;

at least two ion sensing electrodes each having an ion sensing surface disposed within the first fluid conduit;

a second fluid conduit formed in the flow cell body;

a compensating ion sensing electrode having an ion sensing surface disposed within the second conduit;

an electrically conducting bridge connecting the first and second fluid conduits; and

a conductive member, other than the electrodes, disposed within the first fluid conduit and extending within the first fluid conduit along a path proximate the ion sensing surface of the at least two ion sensing electrodes and the bridge.

10. A flow cell as in claim 9 further including means for providing a low impedance path from the conductive member for grounding the conductive member.

11. An improved ion selective electrode flow cell comprising:

a flow cell body;

a first fluid conduit formed in the flow cell body;

at least two ion sensing electrodes each having an ion sensing surface disposed within the first fluid conduit;

a second fluid conduit formed in the flow cell body;

a compensating ion sensing electrode having an ion sensing surface disposed within the second conduit;

an electrically conducting bridge connecting the first and second fluid conduits;

a conductive member, other than electrodes, disposed within the first fluid conduit and extending within the first fluid conduit along a path proximate the ion sensing surface of the at least two ion sensing electrodes and the bridge;

a third fluid conduit formed in the flow cell body and intersecting the first fluid conduit proximate the conductive member; and

grounding means for grounding the third fluid conduit.

12. An improved ion selective electrode flow cell comprising:

a first fluid conduit;

at least two ion sensing electrodes each having an ion sensing surface disposed within the first fluid conduit;

a second fluid conduit without grounding means for fluid flowing through the second fluid conduit;

an ion sensing electrode having an ion sensing surface disposed within the second conduit;

a conductive member, other than the electrodes, having at least portions thereof disposed in the first fluid conduit proximate to the ion sensing surfaces of the at least two ion sensing electrodes and the bridge;

a third fluid conduit intersecting the first fluid conduit; and

grounding means for grounding fluid flowing through the third fluid conduit.

13. A flow cell as in claim 12 wherein the cell includes capacitor means connected between ground and entry and exit ports of each of the first and second fluid conduits.

14. A flow cell as in claim 12 wherein the conductive member comprises a conducting metallic wire disposed in the first fluid conduit.

15. A flow cell as in claim 14 wherein the material comprising the conductive metallic wire is selected from a group including gold, platinum and rhodium.

16. A flow cell as in claim 14 wherein the conductive member includes conductive metallic plating deposited on the first fluid conduit.

17. A flow cell as in claim 12 further including means for grounding the first conduit at a point along the first fluid conduit proximate the conductive member.