Machine washing process: detergent paste and automatic dispenser

• US 4,889,644 A
• Filed: 06/15/1988
• Issued: 12/26/1989
• Est. Priority Date: 06/15/1987
• Status: Expired due to Term

• Current Assignee: Henkel KGaA (Henkel AG & Co KGaA)
• Original Assignee: Henkel KGaA (Henkel AG & Co KGaA)
• Inventors: Bechstedt, Wolfgang, Amberg, Guenther, Schulz, Paul, Trabitzsch, Uwe
• Primary Examiner(s): CLINGMAN, A
• Application Number:
  US07/207,610
• Time in Patent Office: 559 Days
• Field of Search: 8/137, 252/8.9, 252/174.21
• US Class Current: 8/137
• CPC Class Codes: C11D 1/04 Carboxylic acids or salts thereof soap C11D9/00
• CPC Class Codes: C11D 1/143 Sulfonic acid esters
• CPC Class Codes: C11D 1/22 derived from aromatic compounds
• CPC Class Codes: C11D 1/28 Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
• CPC Class Codes: C11D 1/72 Ethers of polyoxyalkylene glycols
• CPC Class Codes: C11D 1/722 Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups C11D1/721 takes precedence
• CPC Class Codes: C11D 1/83 Mixtures of non-ionic with anionic compounds
• CPC Class Codes: C11D 17/003 Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
• CPC Class Codes: C11D 2111/12 Soft surfaces, e.g. textile
• CPC Class Codes: D06F 39/022 in a liquid state D06F39/024 takes precedence
• CPC Class Codes: D06L 1/01 using only solid or pasty agents

Abstract

A machine washing process with process-controlled dosing of water and detergent using a paste-form, phosphate-reduced or phosphate-free detergent which is substantially free from water, organic solvents and hydrotropic compounds. The paste comprises a phase liquid at a temperature below 10° C. and contains a nonionic surfactant selected from the group of polyglycolether compounds and of a solid phase dispersed therein in which the particles have a mean particle size of from 5 to 40 μm and less than 5% of the particles have a particle size larger than 80 μm, the solid phase comprising washing alkalis, sequestering compounds and other detergent constituents and, optionally, anionic surfactants. Under the control of a process-control computer, the paste is taken from a storage container, delivered to a mixer and diluted therein with water to at least such an extent that the formation of a gel phase is avoided. The aqueous mixture is fed to a washing machine and, unless this has already happened in the mixer, is diluted with more water to a concentration of 0.5 to 10 g/l, after which the washing process is started.

Claims

1. A machine washing process with process-controlled dosing of water and detergent, comprising:

a. a paste-form, phosphate-reduced or phosphate-free detergent composition which is substantially free from water, organic solvent selected from the group consisting of low molecular weight, low-boiling alcohols and ether alcohols and hydrotropic compound, comprising a phase which is liquid at a temperature below 10°

C. and containing a nonionic surfactant selected from the group consisting of alkoxylated alcohols and ethoxylated alkylphenols, and a solid phase dispersed therein wherein the particles have a mean particle size of about 5 to about 40 μ

m and less than about 5% of the particles have a particle size of greater than about 80 μ

m, the solid phase comprising a washing alkali, sequestering compound and other detergent constituents; and

,

b. a process controlled system for dosing said detergent composition into the liquor container of a washing machine, said system removing said detergent composition from a storage container and delivering it to a mixer wherein it is diluted with water to at least such an extent that the formation of a gel phase is avoided, feeding the aqueous detergent mixture to said washing machine, and diluting the aqueous detergent mixture with more water to a concentration of 0.5 to 10 g/l.

2. A process as in claim 1 wherein the content of nonionic surfactant in the paste-form detergent is from about 15 to about 30% by weight, based on the weight of said detergent.

3. A process as in claim 1 wherein said paste-form detergent contains a low-melting mixture of nonionic surfactants differing in their degrees of ethoxylation.

4. A process as in claim 1 wherein the liquid phase of said paste-form detergent contains less than about 15% by weight of a compound selected from the group consisting of a low molecular weight polyethylene glycol, paraffin oil and liquid ether containing 8 to 16 carbon atoms in the hydrocarbon chain, based on the weight of said detergent.

5. A process as in claim 1 wherein said paste-form detergent contains less than about 4% by weight of a sulfonate surfactant selected from the group consisting of C₁₀ -C₁₃ alkyl benzenesulfonate, C₁₁ -C₁₅ alkanesulfonate, C₁₂ -C₁₈ α

-olefin sulfonate, α

-sulfofatty acid and esters thereof and less than about 1% by weight of a C₁₂ -C₁₈ soap, based on the weight of said detergent.

6. A process as in claim 1 wherein said detergent contains sodium metasilicate in a quantity of from about 35 to about 70% by weight, based on the weight of said detergent.

7. A process as in claim 1 wherein the average particle size of the constituents present in the dispersed solid phase is between about 5 and about 40 μ

m, and the maximum size of the particles is less than about 80 μ

m.

8. A process as in claim 1 wherein the Brookfield viscosity measured at 20°

C. using a No. 6 spindle at about 10 revolutions per minute of the paste-form detergent is from about 20 to about 1,000 Pa.s.

9. A process as i claim 1 wherein said nonionic surfactant has a melting temperature of less than about 10°

C.

10. A process as in claim 1 wherein said controlled system for dosing comprises:

a storage container for the detergent paste, means connected to said storage container for removing and transporting the paste, a mixer connected to said means for removing and transporting the paste for mixing the paste with water taken from a water supply, a feed line connected to said mixer and to the point of use of the detergent, and a control unit which records the demand for detergent or wash liquor at the point of use and controls the functions of said means for removing and transporting the paste, said mixer, and said water supply, including dosage of the water supply from said feed line, in dependence upon demand.

11. A process as in claim 10 wherein said paste is diluted with softened water in ratio of 2:

1 to 1;

10 in said mixer.

12. A process as in claim 10 wherein the dosing system additionally comprises an equalizing container connected to said mixer and said feed line.

13. A process as in claim 10 wherein the function of said means for removing and transporting the paste, said mixer, said water supply and said feed line is synchronously controlled in dependence upon the conductivity of the dilute wash liquor as measured in the point of use.

14. A process as in claim 13 wherein said point of use comprises a washing machine.

15. A process as in claim 10 wherein said means for removing and transporting said paste extends to the bottom of said storage container.

16. A process as in claim 10 wherein said mixer comprises an injector which generates a reduced pressure.

17. A process as in claim 10 wherein said mixer comprises a motor-driven pump.

18. A process as in claim 10 wherein said storage container is equipped with a movable, tightly closing follower plate.

19. A process as in claim 10 wherein said mixer is positioned into said storage container.

20. A process as in claim 10 wherein said paste is transported from said storage container under the effect of pressure.

21. A process as in claim 10 wherein said mixer is equipped with a shut-off member.