Process and device for selective extraction of H.sub.2 S from an H.sub.2 S-containing gas

• US 4,889,700 A
• Filed: 06/03/1987
• Issued: 12/26/1989
• Est. Priority Date: 10/04/1985
• Status: Expired due to Term

• Current Assignee: ELF Exploration Production (Cook Composites and Polymers)
• Original Assignee: Societe Nationale Elf Aquitaine (Cook Composites and Polymers)
• Inventors: Elgue, Jean, Peytavy, Jean-Louis, Oliveau, Olivier
• Primary Examiner(s): Stoll, Robert L.
• Application Number:
  US07/067,259
• Time in Patent Office: 937 Days
• Field of Search: 423/228, 423/229, 423/220, 423/223, 423/229, 423/243, 423/242, 423/563, 423/645, 55/48, 55/68, 55/73, 55/93
• US Class Current: 423/220
• CPC Class Codes: B01D 53/1468 Removing hydrogen sulfide
• CPC Class Codes: C01B 17/167 Separation

Abstract

Method and devices for the selective removal of H₂ S from an H₂ S-containing gas by contacting the gas in an absorption column with an H₂ S-selective absorbent liquid and transferring the H₂ S-charged absorbent liquid to the upper part of a second column. The charged absorbent liquid then travels to a regeneration zone at the bottom of the column, where it is heated to a temperature at which the absorbent liquid is vaporized and the H₂ S is released.

The regeneration zone temperature causes the absorbent liquid vapor to strip the H₂ S back to the upper part of the column where it forms an equilibrium with the H₂ S-charged absorbent liquid at a temperature not more than 30° C. higher than the injection temperature of the absorbent liquid in the absorption column, which equilibrium temperature is maintained by the temperature in the regeneration zone. The H₂ S-enriched vapor formed at the equilibrium point is then tapped.

Claims

1. A process for the selective extraction of H₂ S from a gas containing a plurality of gaseous acid compounds, one of which is H₂ S, by operating in a first column comprising an absorption zone and a second column comprising a mixed treatment zone provided with an upper enrichment zone and a lower regeneration zone, said process comprising the steps of

introducing into the absorption column an absorbent liquid for acid compounds, which is selective for H₂ S and regeneratable by heating, and circulating said absorbent liquid and the gas to be treated in countercurrent in said absorption zone to yield a treated gas with a reduced level of H₂ S and a stream of absorbent liquid charged with said gaseous acid compounds,

transporting said stream of absorbent liquid charged with said gaseous acid compounds to the second column and introducing said stream of charged absorbent liquid into the upper enrichment zone, said stream of charged absorbent liquid travelling through the enrichment zone to the regeneration zone at the bottom of the second column,

heating the absorbent liquid charged with the gaseous acid compounds in the lower regeneration zone, thereby releasing said gaseous acid compounds and obtaining a regenerated absorbent liquid and also a gaseous acid effluent, the latter containing the released gaseous acid compounds and being richer in H₂ S than the gaseous acid compound fraction of the gas to be treated,

transporting the H₂ S-rich gaseous acid effluent into the upper enrichment zone by stripping said effluent with the absorbent liquid vapor generated by said heating,

contacting in said upper enrichment zone the H₂ S-rich gaseous acid effluent with the charged absorbent liquid flowing from the absorption column and forming an equilibrium between the H₂ S-rich gaseous acid effluent and said charged absorbent liquid,

tapping at the equilibrium location a fraction of the H₂ S-rich gaseous effluent available at said location,

controlling the heat supplied to the lower regeneration zone to maintain a temperature difference of no more than about 30°

C. between the temperature in the enrichment zone at the tapping level and the temperature of the absorbent liquid entering the absorption column, and

collecting at the top of the second column upper enrichment zone the remainder of the gaseous acid effluent resulting from the regeneration of the charged absorbent liquid in the lower regeneration zone.

2. The process according to claim 1, wherein the temperature in the enrichment zone at the tapping level is no more than about 20°

C. higher than the temperature of the absorbent liquid entering the absorption column.

3. The process according to claim 1, wherein the lower the ratio of the flow of deabsorbed H₂ S-rich gaseous acid effluent tapped from the second column upper enrichment zone equilibrium location to the total flow of acid gases under treatment, the higher the concentration of H₂ S in the deabsorbed gaseous acid effluent.

4. The process according to claim 3, wherein the flow rate of the deabsorbed gaseous acid effluent tapped from the second column upper enrichment zone equilibrium location is about 3,200 Nm³ /h, the total flow rate of the gas under treatment is about 210,000 Nm³ /h, the H₂ S content of the gas under treatment is about 1% by volume and the H₂ S content of the gaseous acid effluent tapped is about 66% by volume.

5. The process according to claim 1, wherein the stream of absorbent liquid charged with gaseous acid compounds transported to the second column from the absorption column is depressurized before being introduced into the second column upper enrichment zone, to bring its pressure to a value approximately equal to the pressure prevailing in the second column upper enrichment zone.

6. The process according to claim 1, wherein the gas stream collected at the top of the second column upper enrichment zone is reintroduced into the absorption column after having been brought by compression to a pressure essentially equal to that of the gas under treatment injected to the absorption column.

7. The process of claim 1, wherein the regenerated absorbent liquid is tapped from the bottom of the second column, cooled, and reintroduced into the absorption column.

8. The process according to claim 1, wherein the gas under treatment is injected into the absorption zone under an absolute pressure between about 3 bars and about 100 bars.

9. The process according to claim 1, wherein the absorbent liquid comprises at least one solvent selected from the group consisting of methanol, polyethylene gylcol dimethyl ether, N-methyl pyrrolidone, sulfolane, phosphoric esters and alkanolamines.

10. The process according to claim 9, wherein the absorbent liquid comprises an aqueous solution of at least one solvent.

11. The process according to claim 10, wherein the absorbent liquid is an aqueous solution of at least one alkanolamine that selectively fixes H₂ S.

12. The process according to claim 1, wherein the alkanolamine which selectively fixes H₂ S is selected from the group consisting of methyldiethanolamine, diisopropanolamine and triethanolamine.

13. The process according to claim 12, wherein the alkanolamine is methyldiethanolamine.

14. The process according to claim 9, wherein said absorbent liquid is a mixture of methanol and at least one alkanolamine selected from the group consisting of methyldiethanolamine, monoethanolamine, diisopropanolamine and diethanolamine.

15. The process according to claim 10, wherein the absorbent liquid is an aqueous solution of sulfolane and an alkanolamine selected from the group consisting of diisopropanolamine and methyldiethanolamine.

16. The process according to claim 11, wherein the concentration of the alkanolamine in the aqueous absorbent liquid is between about 1N and about 8N.

17. The process according to claim 16, wherein said concentration is between about 3N and about 6N.

18. The process according to claim 1, wherein the gas under treatment comprises H₂ S and CO₂.

19. The process according to claim 1, wherein the gas under treatment is discharged at the top of the absorption column and is essentially free of H₂ S.

20. The process of claim 1 wherein the temperature difference of no more than about 30°

C. is controlled by recycling a portion of the regenerated absorbent liquid from the bottom of the regeneration zone through a heating means and reintroducing the regenerated absorbent liquid into the regeneration zone.

21. The process of claim 1 further comprising the steps of tapping a portion of the regenerated absorbent liquid from the bottom of the regeneration zone in the second column through a indirect heat exchange means and then through the absorption column and introducing the absorbent liquid charged with said gaseous acid compounds into the regeneration zone in the second column.