Absorbent composition containing a tertiary amino azabicyclic alcohol and an amine salt

• US 4,894,179 A
• Filed: 10/13/1987
• Issued: 01/16/1990
• Est. Priority Date: 10/13/1987
• Status: Expired due to Fees

• Current Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Original Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Inventors: Santori, Guido, Stogryn, Eugene L., Ho, W. S. Winston
• Primary Examiner(s): Rotman, Alan L.
• Assistant Examiner(s): SCALZO, CATHERINE KILBY
• Application Number:
  US07/106,797
• Time in Patent Office: 826 Days
• Field of Search: 252/189, 252/190, 252/191
• US Class Current: 252/189
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents
• CPC Class Codes: C07D 451/06 Oxygen atoms

Abstract

A new alkaline absorbent solution containing a tertiary amino azabicyclic alcohol in combination with its salt with a strong acid and/or in combination with a severely-hindered aminoacid is provided. A process for the removal of H₂ S from fluid mixtures using this absorbent solution to produce a very low level of H₂ S in the treated fluid is also provided. The process is also suitable for the selective removal of H₂ S from fluid mixtures comprising H₂ S and CO₂. Use of the above absorbent solution leads to higher selectivity for H₂ S without damaging capacity than observed when the tertiary amino azabicyclic alcohol is used alone without additive.

Claims

1. A composition comprising:

(1) at least one tertiary amino azabicyclic alcohol and (2) an amine salt, said amine salt being the reaction product of said azabicyclic alcohol and a component selected from the group consisting of an acid having at least one pKa of not more than about 7, a decomposable salt of an acid having at least one pKa of not more than about 7, a compound capable of forming an acid having a pKa of not more than about 7 and a mixtures thereof, said amine salt and said tertiary azabicyclic alcohol being present in said composition in a mole ratio of said amine salt to said tertiary amino azabicyclic alcohol of at least about 0.2;

1 to 4;

1.

2. The composition of claim 1 wherein said composition additionally comprises a liquid selected from the group consisting of water, an organic solvent and mixtures thereof.

3. The composition of claim 1 wherein said azabicyclic alcohol is selected from the group consisting of tropine, pseudotropine, 9-methylgranatanin-3-ol, isoquinuclidine ethanol, trachelanthamidine, 4-hydroxymethyl-quinuclidine, N-hydroxyethyllnortropine, N-hydroxyethyl (9-azabicyclo [3.3.1]nonane), N-hydroxyethoxyethyl(9-azabicyclo[4.2.1]nonane), and 3-hydroxymethyl-8-methyl-8-azabicyclo[3.2.1]octane.

4. The composition of claim 1 wherein said component reacted with said alcohol is selected from the group consisting of sulfuric acid, phosphoric acid, phosphorous acid, pyrophosphoric acid, sulfurous acid, and mixtures thereof.

5. The composition of claim 1 wherein said component reacted with said alcohol is selected from the group consisting of ammonium sulfate, ammonium sulfite, sulfur dioxide, ammonium phosphate and mixtures thereof.

6. The composition of claim 1 wherein said mole ratio of said amine salt to said alcohol ranges from about 0.2:

1 to 1;

1.

7. The composition of claim 1 wherein said mole ratio of said amine salt to said alcohol ranges from about 0.3:

1 to 1;

1.

8. The composition of claim 1 wherein said composition comprises water and wherein said amine salt is a non-volatile water soluble amine salt.

9. The composition of claim 1 wherein said composition comprises from about 5 to 70 wt. % of said alcohol, from about 5 to 40 weight percent of said amine salt calculated as said alcohol, and the balance being water.

10. The composition of claim 1 wherein said amine salt is the reaction product of tropine and H₂ SO₄.