Coated glass

• US 4,894,290 A
• Filed: 01/13/1988
• Issued: 01/16/1990
• Est. Priority Date: 01/29/1986
• Status: Expired due to Term

• Current Assignee: Pilkington Brothers Unlimited (Pilkington PLC)
• Original Assignee: Pilkington Brothers Unlimited (Pilkington PLC)
• Inventors: Lowe, Martin, Chesworth, Peter
• Primary Examiner(s): Swisher, Nancy A. B.
• Application Number:
  US07/143,195
• Time in Patent Office: 734 Days
• Field of Search: 428/434, 428/433, 428/426, 428/432
• US Class Current: 428/426
• CPC Class Codes: B32B 17/10174 Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3615 Coatings of the type glass/metal/other inorganic layers, at least one layer being non-metallic
• CPC Class Codes: C03C 17/3618 Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
• CPC Class Codes: C03C 17/3644 the metal being silver
• CPC Class Codes: C03C 17/3647 in combination with other metals, silver being more than 50%
• CPC Class Codes: C03C 17/3652 the coating stack containing at least one sacrificial layer to protect the metal from oxidation
• CPC Class Codes: C03C 17/3681 the multilayer coating being used in glazing, e.g. windows or windscreens
• CPC Class Codes: C03C 17/3689 one oxide layer being obtained by oxidation of a metallic layer

Abstract

Bent and/or toughened silver coated glass having light transmission is produced by depositing layers of additional metal over, or both under and over, the silver layer. When the additional metal is used over the silver layer, it is selected from aluminium, titanium, zinc and tantalum. When the additional metal is used both under and over the silver, it is selected from aluminium, titanium, zinc, tantalum and zirconium. The additional metal is used in an amount such that the light transmission of the coated glass increases on bending and/or toughening. The bent and/or toughened coated glass is useful for architectural glazing and as vehicle windows.

Claims

1. A coated glass substrate with a coating comprising a layer of additional metal selected from aluminum, titanium, zinc, tantalum and zirconium, a silver layer from 5 nm to 30 nm thick over the layer of additional metal, a further layer of additional metal selected from aluminum, titanium, zinc, tantalum and zirconium over the silver layer, and an anti-reflection metal oxide layer over said further layer of additional metal which coated glass substrate, when subjected to a bending and/or toughening cycle in which the glass is heated in air to a temperature above the softening temperature of the glass, develops an increased light transmission, with the thickness of any anti-reflection metal oxide layer overlying the silver layer plus the thickness of the oxidised additional metal over the silver being in the range of from 10 nm to 80 nm.

2. A coated glass substrate according to claim 1 which develops an increased light transmission of at least 70% during the bending and/or toughening cycle.

3. A coated glass substrate according to claim 1 which develops an increased light transmission of at least 80% of the light transmission of the base glass during the bending and/or toughening cycle.

4. A coated glass substrate according to claim 1 wherein the total amount of additional metal is such that the light transmission of the coated glass increases by at least 10% of its original value on bending and/or toughening in air.

5. A coated glass substrate according to claim 1 wherein the total amount of additional metal is sufficient to provide a metal layer having a thickness in the range of from 4 nm to 15 nm.

6. A coated glass substrate according to claim 1 wherein the additional metal in each layer of additional metal is aluminium, zinc or titanium.

7. A coated glass substrate according to claim 6 wherein the additional metal is aluminium in a total amount equivalent to a layer from 5 nm to 10 nm thick.

8. A coated glass substrate according to claim 1 wherein the coating additionally comprises an anti-reflection layer or layers of metal oxide between the glass and the silver layer.

9. A coated glass substrate according to claim 8 wherein the total thickness of any metal oxide layers between the glass and the silver layer is from 20 nm to 60 nm.

10. A bent and/or toughened silver-coated glass substrate having a light transmission of at least 80% of that of the uncoated glass the coating being deposited directly on the glass substrate and comprising an anti-reflection metal oxide layer, an oxidised layer of metal selected from aluminum, titanium, tantalum and zirconium over the anti-reflection layer, a silver layer from 5 nm to 30 nm thick over said oxidised metal layer, a further oxidised layer of metal selected from aluminum, titanium, tantalum and zirconium over said silver layer, and an overlying anti-reflection metal oxide layer, the said two layers of oxidised metal having a combined total thickness in the range of from 8 nm to 30 nm, and the thickness of any anti-reflection metal oxide layer overlying the silver layer plus the thickness of the oxidised additional metal over the silver being in the range of from 10 nm to 80 nm.

11. A bent and/or toughened silver-coated glass substrate according to claim 10 wherein each of the said two oxidised layers of metal has a thickness in the range of from 4 nm to 15 nm.

12. A bent and/or toughened silver-coated glass substrate having a light transmission of at least 80% of the uncoated glass, the coating being deposited directly on the glass substrate and comprising an anti-reflection metal oxide layer, a silver layer from 5 nm to 30 nm thick over said anti-reflection layer, and an oxidised layer of titanium or tantalum over said silver layer, and an overlying anti-reflection metal oxide layer, the said layer of oxidised metal having a thickness in the range of from 8 nm to 30 nm, and the thickness of any anti-reflection metal oxide layer overlying the silver layer plus the thickness of the oxidised additional metal over the silver being in the range of from 10 nm to 80 nm.

13. A bent and/or toughened silver-coated glass substrate according to claim 12 having a light transmission of at least 70%.

14. A bent and/or toughened silver-coated glass substrate having a light transmission of at least 80% of the uncoated glass, the coating being deposited directly on the glass substrate and comprising an anti-reflection metal oxide layer, a silver layer from 5 nm to 30 nm thick over said anti-reflection metal oxide layer and an overlying anti-reflection metal oxide layer, with oxidised zinc distributed through all the layers of the coating, with the thickness of any anti-reflection metal oxide layer overlying the silver layer being in the range of from 10 nm to 80 nm.

15. A bent and/or toughened silver-coated glass according to claim 14 wherein the zinc is present in an amount equivalent to a layer of zinc 4 nm to 15 nm thick.

16. A bent and/or toughened silver-coated glass according to claim 14 having a light transmission of at least 70%.