Stabilization of extremely lightweight aggregate concrete

• US 4,895,598 A
• Filed: 05/18/1988
• Issued: 01/23/1990
• Est. Priority Date: 10/05/1983
• Status: Expired due to Fees

• Current Assignee: Bengt Hedberg, Leif Berntsson
• Original Assignee: Bengt Hedberg, Leif Berntsson
• Inventors: Hedberg, Bengt, Berntsson, Leif
• Primary Examiner(s): Bell, Mark L.
• Assistant Examiner(s): Brunsman, David M.
• Application Number:
  US07/198,722
• Time in Patent Office: 615 Days
• Field of Search: 106/86, 106/88-90, 106/314, 106/315
• US Class Current: 106/694
• CPC Class Codes: C04B 14/06 Quartz; Sand
• CPC Class Codes: C04B 16/04 Macromolecular compounds C04B16/02 takes precedence
• CPC Class Codes: C04B 16/08 porous, e.g. expanded polystyrene beads or microballoons
• CPC Class Codes: C04B 20/0076 characterised by the grain distribution
• CPC Class Codes: C04B 20/1018 with organic materials pigments or dyes C04B20/1096
• CPC Class Codes: C04B 24/24 Macromolecular compounds C04B24/14 takes precedence; macromolecular compounds comprising sulfonate or sulfate groups C04B24/16
• CPC Class Codes: C04B 24/36 Bituminous materials, e.g. tar, pitch C04B24/243 takes precedence
• CPC Class Codes: C04B 28/02 containing hydraulic cements other than calcium sulfates
• CPC Class Codes: C04B 38/08 by adding porous substances
• CPC Class Codes: C04B 38/10 by using foaming agents C04B38/02 takes precedenceor by using mechanical means, e.g. adding preformed foam

Abstract

Method of producing monolithic mainly cementbound concrete in the density range of 650-1300 kg/m³, preferably of 800-1200 kg m³ with substantially good placing properties both for building in situ and prefabrication. The concrete consists of cement mortar with an air-void volume of 7-18% of the total concrete volume and aggregate consisting of lightweight organic or inorganic material. The smaller particles of the aggregate should be spherical, exceptionally lightweight, hydrophobic and durable against deformation in order to reduce the water content without changing the consistency of the concrete. The production of concrete is based on the aggregate having a continuous distribution of particle size within which the particle density decreases with decreased particle size, that during mixing small as well as big air-voids are created with strengthened and thickened bubble walls, that the thixotropy of the cement paste is strengthened and that air bubbles are replaced with an equivalent volume of sand particles in excess of those which are needed for the creation of air bubbles. The effects are achieved with multifunctional polymer microparticles on which different surfactant systems have been adsorbed. Air bubbles with their thickened walls as well as the most lightweight aggregate particles reduce the difference in density between the continuous medium and the air bubbles - aggregate particles.

Claims

1. Method of producing a monolithic lightweight aggregate concrete of a density of 700-1200 Kg/m³ in fully dried condition composed of lightweight cement mortar including hydraulic cement, sand, fine and extremely lightweight particles, air bubbles and water mixed together with coarse lightweight aggregate,

characterized by the fact that

the low density of the cement mortar of the lightweight aggregate concrete is constituted by replacing sand at least partly by an equivalent volume of small air bubbles with a diameter in the range of approximately from 20 to 500 micrometers so that the volume of air bubbles is in the range of 5 to 30% of the volume of cement mortar and expanded organic and inorganic aggregate of particle density less than 200 Kg/m³ and of a size approximately from 0.2 to 2 mm and a volume from 5-20% of the volume of cement mortar in such a way that the total particle volume of the cement mortar constitutes nearly a continuous size distribution, the stability is increased and the homogenity is maintained of the fresh cement mortar and concrete by adding polymer microparticles and equivalent organic microparticles in the amount of 0.1-5.0% of the cement weight,

said polymer microparticles consisting of a mixture of at least two different types,

a first type consisting of synthetic polymer particles having a diameter of 0.1-1.0 micrometers on the surface of which an anionic or a combination of anionic-nonionic calcium stable surfactants have been adsorbed to an amount of 0.1-5.0% by weight of the synthetic polymer, and

a second type consisting of natural or synthetic polymer microparticles having a diameter of 0.5-10 micrometers on the surface of which an anionic or anionic-nonionic calcium destabilizable combination of surfactants have been adsorbed to an amount of 0.1-5.0% by weight of the natural or synthetic polymer, wherein the weight ratio between the second type microparticles and the first type microparticles is in the range from 1:

3 to 1;

6.

2. Method in accordance with claim 1, characterized by the fact that the fine aggregate particles of the cement mortar except sand particles are chosen from the group consisting of expanded polystyrene, polyethylene and polyurethene polymers of a particle density of 10-50 Kg/m³ or substantially expanded inorganic particles of a density of 50-200 Kg/m³ consisting of pumice, expanded clay, flyash, and perlite.

3. Method in accordance with claim 1, characterized by the fact that the coarse aggregate is chosen from the group consisting of organic, inorganic, synthetic and natural lightweight particles having a particle density less than 1,200 Kg/m³ in dried condition with a size approximately from 2 to 25 mm, and particle volume between 30 to 50% of the total concrete volume.

4. Method in accordance with claim 1, characterized by the fact that the cement mortar of the concrete is stabilized in the fresh state with an admixture of polymer microparticles of equal hydrophobic-hydrophilic organic particles by deformable, stable air bubbles with thickened walls during mixing that the bubbles act as spherical extremely lightweight particles and the character of the microparticles also increases the thixotropy of cement paste.

5. Method in accordance with claim 1, characterized by the fact that the particle-shaped product of the microparticles to be incorporated in the mortar and concrete includes a homopolymer or a copolymer of styrene and one or more esters of acrylic or methacrylic acid with the general formula:

##STR2## where R₁ =H or CH₃ and R₂ =an alcohol radical with 1-18 carbon atoms chosen from the group consisting of methacrylate, ethylacrylate, propylacrylate, butylacrylate, hexylacrylate or 2-ethylmethacrylate, methylmethacrylate, ethylmethacrylate, butylmethacrylate, hexylmethacrylate, and 2-ethylhexylmethacrylate with particle size of 0.1-10 micrometers on the surface of which surfactants have been adsorbed.

6. Method in accordance with claim 1, characterized by the fact that the particle-shaped product incorporated in the cement mortar and concrete comprises a copolymer of acrylic-vinylidenchloride or styrene-butadiene on which surface surfactants have been adsorbed or a natural surface with an active hydrophobic-hydrophilic organic combination of matter which chemically reacts with alkaline earth metals or polyvalent metals into fatty soaps.

7. Method in accordance with claim 1, characterized by the fact that the microparticles are located on the inner surface of the air bubbles and on the walls of the capillary pores and other cavities creating water-repellant properties after some drying and at the same time low resistance to water vapor transfer.

8. Method in accordance with claim 1, characterized by the fact that the consistency of the lightweight aggregate concrete is in the range of 35-45 cm according to a flow table test, DIN 1045.