Controlled electrochemical power generation

• US 4,897,321 A
• Filed: 09/29/1986
• Issued: 01/30/1990
• Est. Priority Date: 09/29/1986
• Status: Expired due to Fees

• Current Assignee: Westinghouse Electric Corporation (Paramount Global (f/k/a ViacomCBS Inc.))
• Original Assignee: Gould, Inc. (Transdigm Group Incorporated)
• Inventors: Neff, Joseph A., Shuster, Nicholas
• Primary Examiner(s): Skapars, Anthony
• Application Number:
  US06/912,274
• Time in Patent Office: 1,219 Days
• Field of Search: 429/51, 429/50, 429/52, 429/63, 429/64, 429/70, 429/72, 429/14, 429/34, 429/61, 429/62
• US Class Current: 429/51
• CPC Class Codes: H01M 50/77 with external circulating path
• CPC Class Codes: H01M 6/50 Methods or arrangements for servicing or maintenance, e.g. for maintaining operating temperature constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals, H01M50/569

Abstract

A system and a method of controlled electrochemical power generation are disclosed. The system includes an electrochemical cell comprising an alkali metal anode, a cathode initially spaced about 10-25 mils from the anode to define a flow channel, an electrolyte comprising an aqueous solution of the hydroxide of the alkali metal and, for example, a separator system adapted for providing a substantially uniform pattern of flow of the electrolyte through the flow channel is utilized in a system and method of controlled power generation. Flow control valves may, for example, be used to control the volumetric flow rate of the electrolyte through the flow channel thereby attaining substantially uniform voltage from the cell.

Claims

1. A method of power generation, said method comprising the steps of:

supplying an electrolyte to a flow channel defined between an alkali metal anode and a cathode initially spaced about 10-25 mils from said anode in an electrochemical cell having means adapted for providing a substantially uniform pattern of flow of said electrolyte through said flow channel, said electrolyte comprising an aqueous solution of the hydroxide of said alkali metal; and

,

controlling the volumetric flow rate of said electrolyte through said flow channel in order to attain substantially uniform voltage from said cell.

2. The method of claim 1 wherein said alkali metal comprises lithium.

3. The method of claim 2 wherein said cathode comprises silver oxide.

4. The method of claim 1 wherein said means adapted for providing a substantially uniform pattern of flow comprises a rigid, non-conductive porous member disposed adjacent said cathode and a resilient, nonconductive porous member disposed adjacent said rigid porous member between said rigid porous member and said anode.

5. The method of claim 4 wherein said resilient porous member comprises a compressible reticulated foam material.

6. The method of claim 5 wherein said compressible reticulated foam material comprises polyether urethane.

7. The method of claim 4 wherein said rigid porous member comprises a rigid plastic screen.

8. The method of claim 7 wherein said rigid plastic comprises polypropylene.

9. The method of claim 1 wherein said cathode is initially spaced about 10-20 mils from said anode.

10. The method of claim 1 additionally comprising the step of controlling the molarity of said electrolyte to assist in maintaining said uniform voltage from said cell.

11. The method of claim 10 wherein said step of controlling said molarity of said electrolyte comprises adding diluent to said electrolyte.

12. The method of claim 1 additionally comprising the step of maintaining the spacing of said cathode of said cell from said anode substantially constant during operation.

13. The method of claim 12 wherein said spacing is about 10-20 mils.

14. The method of claim 12 wherein said step of maintaining the spacing of said cathode of said cell from said anode comprises maintaining said cathode and said anode under compression.

15. A method of power generation, said method comprising the steps of:

supplying an electrolyte to a flow channel defined between an alkali metal anode and a cathode initially spaced about 10-25 mils from said anode in an electrochemical cell having a rigid non-conductive plastic screen member disposed adjacent said cathode and a resilient, non-conductive porous compressible reticulated foam material member disposed adjacent said screen member between said screen member and said anode, said electrolyte comprising an aqueous solution of the hydroxide of said alkali metal; and

,

controlling the volumetric flow rate of said electrolyte through said flow channel in order to attain substantially uniform voltage from said cell.

16. The method of claim 15 wherein said alkali metal comprises lithium.

17. The method of claim 16 wherein said cathode comprises silver oxide.

18. The method of claim 15 wherein said compressible reticulated foam material comprises polyether urethane.

19. The method of claim 15 wherein said rigid plastic comprises polypropylene.

20. The method of claim 15 wherein said cathode is initially spaced about 10-20 mils from said anode.

21. The method of claim 15 additionally comprising the step of controlling the molarity of said electrolyte to assist in maintaining said uniform voltage from said cell.

22. The method of claim 21 wherein said step of controlling said molarity of said electrolyte comprises adding diluent to said electrolyte.

23. The method of claim 15 additionally comprising the step of maintaining the spacing of said cathode of said cell from said anode substantially constant during operation.

24. The method of claim 23 wherein said spacing is about 10-20 mils.

25. The method of claim 23 wherein said step of maintaining the spacing of said cathode of said cell from said anode comprises maintaining said cathode and said anode under compression.