Wear-resistant titanium or titanium-alloy member and a method for manufacturing the same

• US 4,902,359 A
• Filed: 09/06/1988
• Issued: 02/20/1990
• Est. Priority Date: 05/18/1986
• Status: Expired due to Term

• Current Assignee: Daido Tokushuko Kabushiki Kaisha, Fuji Valve Co., Ltd.
• Original Assignee: Daido Tokushuko Kabushiki Kaisha, Fuji Valve Co., Ltd.
• Inventors: Hayakawa, Hitoshi, Nakayama, Shinji, Takeuchi, Yukoh, Kato, Yoshihisa, Nagata, Masaru
• Primary Examiner(s): KASTLER, SCOTT R
• Application Number:
  US07/241,786
• Time in Patent Office: 532 Days
• Field of Search: 148/4, 148/421, 148/902, 148/903, 148/133, 219/121 P, 219/121 PA, 219/121 PB, 219/121 Pl
• US Class Current: 148/222
• CPC Class Codes: B23K 35/325 Ti as the principal constituent
• CPC Class Codes: C22F 1/183 of titanium or alloys based thereon
• CPC Class Codes: C23C 26/02 applying molten material to the substrate
• CPC Class Codes: C23C 4/06 Metallic material
• CPC Class Codes: C23C 4/08 containing only metal elements C23C4/073 takes precedence
• CPC Class Codes: C23C 4/10 Oxides, borides, carbides, nitrides or silicides; Mixtures thereof
• CPC Class Codes: C23C 4/134 Plasma spraying
• CPC Class Codes: Y10S 148/903 Directly treated with high energy electromagnetic waves or particles, e.g. laser, electron beam

Abstract

A wear-resistant titanium or titanium-alloy member adapted for use as a poppet valve, rocker arm, etc., of an internal combustion engine, which requires lightness in weight and good wear resistance, and a method for manufacturing the member. The surface of the titanium or titanium-alloy member is given a Vickers hardness number of 390 to 1,200, preferably 400 to 800, and a hardened layer depth of 0.1 to 2.0 mm, preferably 0.3 to 1.5 mm, by being melt-hardened while being supplied with hardening elements.

Claims

1. A method for manufacturing a wear-resistant member, comprising a step of melt-hardening the surface of a member made of a material selected from the group consisting of titanium and titanium alloy, while spraying the member surface with a plasma jet containing, as a working gas, a gas mixture of an inert gas and a hardening gas, thereby providing a Vickers hardness number of 390 to 1,200 and a hardened layer depth of 0.1 to 2.0 mm.

2. A method for manufacturing a wear-resistant member according to claim 3, wherein said Vickers hardness number ranges from 400 to 800, and said hardened layer depth ranges from 0.3 mm to 1.5 mm.

3. A method for manufacturing a wear-resistant member according to claim 1, wherein said plasma jet is sprayed by means of a torch including a center electrode, a first passage surrounding said center electrode, and a second passage surrounding said first passage, said first passage being supplied with said working gas, and said second passage being supplied with a shielding gas containing an inert gas and a hardening gas.

4. A method for manufacturing a wear-resistant member according to claim 3, wherein said torch further includes a third passage defined between said first passage and said second passage so as to surround said first passage, said first passage being supplied with a first gas mixture, as a working gas, containing at least said inert gas, and said third passage being supplied with a second gas mixture containing at least said hardening gas, so that said second gas mixture is caused to join a plasma jet produced in said first passage.

5. A method for manufacturing a wear-resistant member according to claim 3, wherein said hardening gas is formed of one or more gases selected from the group consisting of nitrogen, carbon dioxide, carbon monoxide, oxygen, methane, and ammonia.

6. A method for manufacturing a wear-resistant member according to claim 5, wherein said hardening gas is nitrogen, and said gas mixture contains nitrogen gas at a rate of 0.1 to 20% by volume.

7. A method for manufacturing a wear-resistant member according to claim 5, wherein said hardening gas is carbon monoxide, and said gas mixture contains carbon monoxide at a rate of 30% or less by volume.

8. A method for manufacturing a wear-resistant member according to claim 5, wherein said hardening gas is carbon dioxide, and said gas mixture contains carbon dioxide at a rate of 20% or less by volume.

9. A method for manufacturing a wear-resistant member according to claim 4, wherein said hardening gas of said second gas mixture is oxygen.

10. A method for manufacturing a wear-resistant member, comprising a step of mixing (i) at least one hardening alloy element selected from the group consisting of tin, boron, iron, chromium, nickel, manganese, copper, silicon, silver, tungsten, molybdenum, vanadium, columbium, tantalum, and zirconium, with (ii) at least one compound selected from the group consisting of carbides, nitrides and oxides to form a hardening mixture, and a step of applying said mixture to the surface of a member made of a material selected from the group consisting of titanium and titanium alloy, and a step of melt-hardening said member surface together with said hardening mixture, thereby forming a hardened surface layer on said member having a member surface Vickers hardness number of 390 to 1,200 and a hardened layer depth of 0.1 to 2.0 mm.

11. A method for manufacturing a wear-resistant member according to claim 10, wherein titanium is mixed with said hardening alloy elements.

12. A method for manufacturing a wear-resistant member, comprising a step of applying hardening alloy elements, formed of one or more elements selected from the group consisting of tin, boron, iron, chromium, nickel, manganese, copper, silicon, silver, tungsten, molybdenum, vanadium, columbium, tantalum, and zirconium, to the surface of a member made of a material selected from the group consisting of titanium and titanium alloy, and a step of melt-hardening said member surface together with said hardening alloy elements, while spraying the member surface with a hardening gas, thereby providing a Vickers hardness number of 390 to 1,200 and a hardened layer depth of 0.1 to 2.0 mm.

13. A method for manufacturing a wear-resistant member according to claim 12, wherein titanium is mixed with said hardening alloy elements, and the resulting mixture is applied to said member surface.

14. A method for manufacturing a wear-resistant member according to claim 12, wherein at least one compound from the group consisting of a carbide, a nitride, and an oxide is mixed with said hardening alloy elements, and the resulting mixture is applied to said member surface.

15. A method for manufacturing a wear-resistant member according to claim 12, wherein said hardening gas is formed of one or more gases selected from the group consisting of nitrogen, carbon dioxide, carbon monoxide, oxygen, methane, and ammonia.