Pressure sensitive carbonless imaging system incorporating uncolored ferric organophosphates and colored chelates

• US 4,902,668 A
• Filed: 08/25/1988
• Issued: 02/20/1990
• Est. Priority Date: 08/25/1988
• Status: Expired due to Fees

• Current Assignee: 3M Company
• Original Assignee: 3M Company
• Inventors: Whitcomb, David R., Albin, Loren D.
• Primary Examiner(s): Hess, Bruce H.
• Application Number:
  US07/236,658
• Time in Patent Office: 544 Days
• Field of Search: 427/150-152, 428/704, 428/913, 428/914, 428/201, 428/215, 428/216, 500/200, 500/211, 500/217, 500/226
• US Class Current: 503/201
• CPC Class Codes: B41M 5/132 Chemical colour-forming components; Additives or binders therefor
• CPC Class Codes: Y10S 428/914 Transfer or decalcomania

Abstract

Pressure sensitive imaging materials are stable until pressure addressed, but thereafter provide an intense dark image. The materials comprise colorless ferric organophosphate, ferric organophosphinate, or ferric organophosphonate and a colored chelate.

Claims

1. A pressure sensitive imaging system comprising a substrate having coated on one surface thereof or disposed therein a first component comprising a colored chelate selected from aromatic or alkyl ligands having either neutral donors or at least one ionizable hydrogen, or both, and which react with iron (III) to form colored complexes;

, and a second component in such physical relationship with said substrate that said second component will contact said first component upon the application of pressure to said substrate, said second component comprising a colorless ferric iron compound selected from ferric organophosphates, ferric organophosphinates, and ferric organophosphonates which react with said colored chelate upon contact to form a visible color.

2. A pressure sensitive imaging system as recited in claim 1 wherein said colorless ferric iron compound is selected from

where each R is independently selected from alkyl or alkoxy groups and substituted alkyl or alkoxy groups bearing substituents selected from alkyl, cycloalkyl, and aryl groups, provided that said substituents do not act as ligands or chelates for ferric ions;

and X is a counterion.

3. A pressure sensitive imaging system as recited in claim 2 wherein each R is selected independently from the group represented by the formula ##STR3## where:

3<

=a+b<

=18, b>

a, b>

c, 1<

=c<

=10, d=0 or 1, and X is selected from fluoride, hexafluorophosphate, tetraphenylborate, tetrafluoroborate and nitrate.

4. A pressure sensitive imaging system as recited in claim 3 wherein a=1, b=4, c=2, d=1, and X=nitrate.

5. A pressure sensitive imaging system as recited in claim 4 wherein said first component further comprises a colorless chelate selected from aromatic or alkyl ligands having either neutral donors or at least one ionizable hydrogen, or both, and which react with iron (III) to form colored complexes.

6. A pressure sensitive imaging system as recited in claim 5 wherein said colorless chelate is a substituted catechol bearing electron donating groups.

7. A pressure sensitive imaging system as recited in claim 4 wherein said colored chelate is selected from the group consisting of catechols, quinones, azo dyes and macrocyclic chelates.

8. A pressure sensitive imaging system as recited in claim 4 wherein at least one of said colored chelate or said colorless ferric iron compound is encapsulated, as a liquid solution or dispersion, in pressure-rupturable microcapsules, and said second component is dispersed within said substrate.

9. A pressure sensitive imaging system as recited in claim 4 wherein at least one of said colored chelate or said colorless ferric iron compound is encapsulated, as a liquid solution or dispersion, in pressure-rupturable microcapsules, and said second component is coated on one surface of said substrate.

10. A pressure sensitive imaging system as recited in claim 4 further comprising a second substrate having said second component coated on one surface thereof or dispersed therein.

11. A pressure sensitive imaging system as recited in claim 10 wherein said first component and said second component are coated on the surfaces of said respective substrates facing one another.

12. A pressure sensitive imaging system as recited in claim 10 wherein at least one of said colored chelate or said colorless ferric iron compound is encapsulated, as a ligand solution or dispersion, in pressure-rupturable microcapsules, and at least one of said first component or said second component is dispersed within its respective substrate.

13. A pressure sensitive imaging system as recited in claim 1 wherein said colored chelate is selected from the group consisting of catechols, quinones, azo dyes and macrocyclic chelates.

14. A pressure sensitive imaging system as recited in claim 1 wherein said first component further comprises a colorless chelate selected from aromatic or alkyl ligands having either neutral donors or at least one ionizable hydrogen, or both, and which reacts with iron (III) to form colored complexes.

15. A pressure sensitive imaging system as recited in claim 14 wherein said colorless chelate is a substituted catechol bearing electron donating groups.

16. A pressure sensitive imaging system as recited in claim 1 wherein at least one of said colored chelate or said colorless ferric iron compound is encapsulated, as a liquid solution or dispersion, in pressure-rupturable microcapsules, and said second component is dispersed within said substrate.

17. A pressure sensitive imaging system as recited i claim 1 wherein at least one of said colored chelate or said colorless ferric iron compound is encapsulated, as a liquid solution or dispersion, in pressure-rupturable microcapsules, and said second component is coated on one surface of said substrate.

18. A pressure sensitive imaging system as recited in claim 1 further comprising a second substrate having said second component coated on one surface thereof or dispersed therein.

19. A pressure sensitive imaging system as recited in claim 18 wherein said first component and said second component are coated on the surfaces of said respective substrates facing one another.

20. A pressure sensitive imaging system as recited in claim 18 wherein at least one of said colored chelate or said colorless ferric iron compound is encapsulated, as a liquid solution or dispersion, in pressure-rupturable microcapsules, and at least one of said first component or said second component is dispersed within its respective substrate.

21. A method of generating a visible image on the surface of a substrate, said image comprising a representation of the characteristic pattern of raised and recessed portions of the external surface of the skin covering the hands, fingers, feet and toes of the human body, comprising:

(a) providing a first substrate, selected from the group consisting of the hands, fingers, feet and toes of the human body, having coated thereon a component comprising a colored chelate selected from aromatic or alkyl ligands having either neutral donors or at least one ionizable hydrogen, or both and which react with iron (III) to form colored complexes;

(b) providing a second substrate having coated thereon a component comprising a colorless ferric iron compound selected from ferric organophosphates, ferric organophosphinates and ferric organophosphonates which react with said colored chelate upon contact to form a visible color; and

(c) pressing said first and second substrates together such that said colored chelate contacts said colorless ferric iron compound and reacts therewith to form a visible colored image on the surface of said second substrate comprising a representation of said characteristic pattern on the surface of said first substrate.

22. A method of generating a visible image on the surface of a substrate, said image comprising a representation of the characteristic pattern of raised and recessed portions of the external surface of the skin covering the hands, fingers, feet and toes of the human body, comprising:

(a) providing a first substrate having coated thereon a component comprising a colored chelate selected from aromatic or alkyl ligands having either neutral donors or at least one ionizable hydrogen, or both, and which react with iron (III) to form colored complexes;

(b) providing a second substrate, selected from the group consisting of the hands, feet, fingers and toes of the human body, having coated thereon a component comprising a colorless ferric iron compound selected from ferric organophosphates, ferric organophosphinates and ferric organophosphonates which react with said colored chelate upon contact to form a visible color; and

(c) pressing said first and second substrates together such that said colored chelate contacts said colorless ferric iron compound and reacts therewith to form a visible colored image on the surface of said first substrate comprising a representation of said characteristic pattern on the surface of said second substrate.