Inhibiting wax deposition from a wax-containing oil

• US 4,905,762 A
• Filed: 12/30/1988
• Issued: 03/06/1990
• Est. Priority Date: 12/30/1988
• Status: Expired due to Fees

• Current Assignee: Union Oil Company of California (Chevron Corp.)
• Original Assignee: Union Oil Company of California (Chevron Corp.)
• Inventors: Zilch, Horst E.
• Primary Examiner(s): Suchfield, George A.
• Application Number:
  US07/292,386
• Time in Patent Office: 431 Days
• Field of Search: 166/279, 166/304, 166/310, 166/371, 166/902, 252/8.552, 252/8.553
• US Class Current: 166/310
• CPC Class Codes: C09K 8/524 organic depositions, e.g. paraffins or asphaltenes
• CPC Class Codes: C10L 1/1973 mono-carboxylic
• CPC Class Codes: Y10S 507/931 Organic contaminant is paraffinic

Abstract

A method for inhibiting the deposition of wax in an oil well producing a wax-containing petroleum from a subterranean formation comprises injecting into the oil pool at the base of said well a copolymer comprised of ethylene and vinyl acetate and having an average molecular weight between about 15,000 and about 35,000.

Claims

1. A method for inhibiting wax deposition in an oil well producing a wax-containing oil comprising injecting down-hole into the oil-pool at the base of the well a wax-inhibiting amount of a copolymer of between about 62 and about 66 weight percent ethylene and about 34 and about 38 weight percent vinyl acetate, aid copolymer having an average molecular weight below about 35,000.

2. The method of claim 1 wherein said inhibiting amount is between about 40 and about 1000 ppm, based on the weight of the oil.

3. The method of claim 2 wherein the concentration of said wax-inhibitor is between about:

40 and about 200 ppm, based on the weight of the oil, and the average molecular weight of said copolymer is between about 15,000 and about 35,000.

4. The method of claim 1 wherein the concentration of said wax-inhibitor is between about 40 and about 200 ppm based on the weight of the oil.

5. The method of claim 1 wherein said wax inhibitor is dissolved or dispersed in an organic solvent prior to being injected into said well.

6. The method of claim 5 wherein the concentration of said wax inhibitor in said solvent is between about 1 and about 50 percent.

7. The method of claim 1 wherein said wax-containing oil is at a temperature above the melting point of said wax before said wax inhibitor is admixed therein.

8. The method of claim 1 wherein said copolymer, when dissolved to form a 10 weight percent solution in hexane, has a pour point below about -30°

F and a viscosity, at 100°

F., below about 5 centistokes.

9. The method of claim 1 wherein said oil pool is at a temperature above about 160°

F.

10. The method of claim 2 wherein said oil pool is at a temperature above about 160°

F.

11. The method of claim 3 wherein said oil pool is at a temperature above about 160°

F.

12. The method of claim 4 wherein said oil pool is at a temperature above about 160°

F.

13. The method of claim 5 wherein said oil pool is at a temperature above about 160°

F.

14. The method of claim 6 wherein said oil pool is at a temperature above about 160°

F.

15. The method of claim 8 wherein said oil pool is at a temperature above about 160°

F.

16. A method for inhibiting wax deposition in an oil well producing a wax-containing oil comprising injecting down-hole into said well and admixing said oil at the base thereof with between about 40 and about 200 ppm of a wax deposition inhibitor comprised of a copolymer of between about 62 and about 66 weight percent ethylene and about 34 and about 38 weight percent vinyl acetate, said copolymer having an average molecular weight between about 15,000 and about 35,000 and said oil at a temperature above the melting point of said wax.

17. The method of claim 16 wherein said copolymer, when dissolved to form a 10 weight percent solution in hexane, has a pour point below about -30°

F. and a viscosity, at 100°

F., below about 5 centistokes.

18. The method of claim 16 wherein said wax inhibitor is dissolved or dispersed in an organic solvent prior to being injected into said well.

19. The method of claim 16 wherein said wax-containing oil is at a temperature above about 180°

F. when said wax inhibitor is admixed therein.

20. The method of claim 18 wherein the concentration of said wax inhibitor in said solvent is between about 1 and about 50 percent.