Lactone modified mono-or dicarboxylic acid based adduct dispersant compositions
First Claim
1. A C5 -C9 lactone adduct material useful as an oil additive formed by reacting an aliphatic hydrocarbyl saturated or unsaturated, natural or synthetic, straight chain or branched chain monocarboxylic or dicarboxylic acylating agent heaving from about 1 to about 165 total carbon atoms with the reaction product of a C5 -C9 lactone with a member selected from the group consisting of (a) a polyamine having from about 2 to 60 total carbon atoms and from about 2 to about 12 nitrogen atoms, (b) an amino alcohol containing up to about 50 total carbon atoms, from 1 to about 5 nitrogen atoms and from 1 to about 15 hydroxyl groups, and (c) mixtures of (a) and (b), said aliphatic acylating agent having at least about twelve carbon atoms in said straight or branched chain to produce lactone adduct material that is hydrocarbon soluble.
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Abstract
C5 -C9 lactone based adduct materials are made by reacting a C5 -C9 lactone with a polyamine, a polyol or an amino alcohol to form a lactone adduct intermediate, and thereafter reacting the intermediate with an aliphatic hydrocarbyl saturated or unsaturated, straight chain or branched chain monocarboxylic or dicarboxylic acylating agent having from about one to about 165 total carbon atoms in said straight or branched chain to insure that the resulting lactone adduct is hydrocarbon soluble. The resulting adduct material are useful per se, as oil soluble dispersant additives, and are useful in fuel and lubricating oil compositions including concentrates containing the additives.
117 Citations
78 Claims
- 1. A C5 -C9 lactone adduct material useful as an oil additive formed by reacting an aliphatic hydrocarbyl saturated or unsaturated, natural or synthetic, straight chain or branched chain monocarboxylic or dicarboxylic acylating agent heaving from about 1 to about 165 total carbon atoms with the reaction product of a C5 -C9 lactone with a member selected from the group consisting of (a) a polyamine having from about 2 to 60 total carbon atoms and from about 2 to about 12 nitrogen atoms, (b) an amino alcohol containing up to about 50 total carbon atoms, from 1 to about 5 nitrogen atoms and from 1 to about 15 hydroxyl groups, and (c) mixtures of (a) and (b), said aliphatic acylating agent having at least about twelve carbon atoms in said straight or branched chain to produce lactone adduct material that is hydrocarbon soluble.
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21. A process for preparing a C5 -C9 lactone adduct material useful as an oil additive, which comprises the steps of:
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(i) reacting a C5 -C9 lactone with a member selected from the group consisting of (a) polyamines having from about 2 to about 60 total carbon atoms and from about 2 to about 12 nitrogen atoms, (b) amino alcohols containing up to about 50 total carbon atoms, from 1 to about 5 nitrogen atoms, and from 1 to about 15 hydroxyl groups, and (c) mixtures of (a) and (b) to form a lactone adduct intermediate product; and (ii) reacting said intermediate product with an aliphatic hydrocarbyl saturated or unsaturated, natural or synthetic, straight chain or branched chain monocarboxylic or dicarboxylic acylating agent having from about twelve to about eighteen total carbon atoms and at least twelve carbon atoms in the hydrocarbyl group. - View Dependent Claims (22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33)
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- 34. An oleaginous composition comprising (I) a lubricating oil and (II) a C5 -C9 lactone adduct material, said adduct material being prepared by reacting (i) a C5 -C9 lactone with (ii) a member selected from the group consisting of (a) a polyamine having from about 2 to about 60 total carbon atoms and from about 2 to about 12 nitrogen atoms, (b) an amino alcohol containing up to about 50 total carbon atoms, from 1 to about five nitrogen atoms and from 1 to about 15 hydroxyl groups, and (c) mixtures of (a) and (b) to form an intermediate lactone adduct, and then reacting said intermediate lactone adduct with (iii) an aliphatic hydrocarbyl saturated or unsaturated, natural or synthetic, straight chain or branched chain monocarboxylic or dicarboxylic acylating agent having from about 12 to about 165 total carbon atoms and at least about twelve carbon atoms in said straight or branched chain to insure that the resulting lactone adduct material is hydrocarbon soluble.
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53. An oil soluble dispersant useful as an oil additive, comprising the product of a reaction mixture comprising:
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(I) an aliphatic hydrocarbyl saturated or unsaturated, natural or synthetic, straight chain or branched chain monocarboxylic or dicarboxylic acylating agent having from about 1 to about 165 total carbon atoms; and (II) a C5 -C9 lactone adduct formed by reacting (a) a C5 -C9 lactone with (b) a member selected from the group consisting of (i) a polyamine having from about 2 to 60 total carbon atoms and from about 2 to about 12 nitrogen atoms, (ii) an amino alcohol containing up to about 50 total carbon atoms, from 1 to about five nitrogen atoms and from 1 to about 15 hydroxyl groups, or mixtures of (i) and (ii), wherein there are from 1 to about 10 C5 -C9 lactone derived moieties per unit of said adduct (II) used in the reaction. - View Dependent Claims (54, 55, 56, 57, 58, 59, 60, 61, 62, 63)
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64. An oil soluble reaction product useful as an oil additive of:
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(a) an aliphatic hydrocarbyl saturated or unsaturated, natural or synthetic, straight chain or branched chain monocarboxylic or dicarboxylic acylating agent having from about to about 18 total carbon atoms (b) amine containing 2 to 60 carbon atoms and 2 to 12 nitrogen groups, and, (c) C5 -C9 lactone, wherein (b) is first reacted with (c) and the resulting product is then reacted with (a), and wherein there are about 0.2 to 100 molar proportions of (c) per molar proportion of said reaction product. - View Dependent Claims (65)
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66. An oil soluble reaction product useful as an oil additive of:
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(a) an aliphatic hydrocarbyl saturated or unsaturated, natural or synthetic, straight chain or branched chain monocarboxylic or dicarboxylic acylating agent having from about 12 to about 18 total carbon atoms (b) amino alcohol containing up to about 50 total carbon atoms, from 1 to about 5 nitrogen atoms and from 1 to about 15 hydroxyl groups, and (c) C5 -C9 lactone, wherein (b) is first reacted with (c) and the resulting product is then reacted with (a), and wherein there are about 0.2 to 100 molar proportions of (c) per molar proportion of said reaction product. - View Dependent Claims (67)
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- 68. A lubricating oil composition comprising lubricating oil and an oil soluble reaction product useful as an oil additive, said reaction product being the product of reaction of the intermediate product formed by reacting (a) a C5 -C9 lactone with (b) at least one member selected from the group consisting of (i) a polyamine having from about 2 to 60 total carbon atoms and from about 2 to about 12 nitrogen atoms an amino alcohol containing up to about 50 total carbon atoms, from 1 to about five nitrogen atoms and from 1 to about 15 hydroxyl groups, wherein there are 0.2 to 100 molar proportions of (b) in said intermediate product, further reacted with (c) an aliphatic hydrocarbyl saturated or unsaturated, natural or synthetic, straight chain or branched chain monocarboxylic or dicarboxylic acylating agent having from about 12 to about 18 total carbon atoms.
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70. A lubricating crankcase motor oil composition for automotive vehicles and trucks comprising a major amount of lubricating oil;
- from about 0.01 to 15 wt. % of a dispersant formed by reacting an aliphatic hydrocarbyl saturated or unsaturated, natural or synthetic, straight chain or branched chain monocarboxylic or dicarboxylic acylating agent having from about 12 to about 18 total carbon atoms with the reaction product of a C5 -C9 lactone and at least one member selected from the group consisting of (a) polyamines having from about 2 to 60 total carbon atoms and from about 2 to about 12 nitrogen atoms, and (b) amino alcohols containing up to about 50 total carbon atoms, from 1 to about five nitrogen atoms and from 1 to about 15 hydroxyl groups, wherein said dispersant has about one to five molar proportion of acylating agent moieties; and
about 3 to 25 wt. % of a metal containing detergent additive. - View Dependent Claims (71, 72)
- from about 0.01 to 15 wt. % of a dispersant formed by reacting an aliphatic hydrocarbyl saturated or unsaturated, natural or synthetic, straight chain or branched chain monocarboxylic or dicarboxylic acylating agent having from about 12 to about 18 total carbon atoms with the reaction product of a C5 -C9 lactone and at least one member selected from the group consisting of (a) polyamines having from about 2 to 60 total carbon atoms and from about 2 to about 12 nitrogen atoms, and (b) amino alcohols containing up to about 50 total carbon atoms, from 1 to about five nitrogen atoms and from 1 to about 15 hydroxyl groups, wherein said dispersant has about one to five molar proportion of acylating agent moieties; and
- 73. An additive concentrate comprising about 20 to 90 wt. % lubricating oil and 20 to 80 wt. % of a dispersant which is a C5 -C9 lactone adduct material formed by first reacting about 0.2 to 100 molar proportions of a C5 -C9 lactone per molar proportion of at least one member selected from the group consisting of (a) polyamines having from about 2 to 60 total carbon atoms and from about 2 to about 12 nitrogen atoms and (b) amino alcohols containing up to about 50 total carbon atoms, from 1 to about five nitrogen atoms and from 1 to about 15 hydroxyl groups, to from a lactone adduct intermediate, and then reacting said intermediate with an aliphatic hydrocarbyl saturated or unsaturated, natural or synthetic, straight chain or branched chain monocarboxylic or dicarboxylic acylating agent having from about 12 to about 18 total carbon atoms.
- 76. An additive concentrate comprising about 20 to 80 wt. % lubricating oil and about 20 to 80 wt. % of an oil soluble reaction product of a caprolactone adduct and an acylating agent selected from the group consisting of long chain fatty acids, long chain fatty acid dimers and hydrocarbyl substituted C4 to C10 monounsaturated dicarboxylic acid producing material having from about twelve to about 18 carbon atoms in said hydrocarbyl substituent, said caprolactone adduct being prepared by reacting caprolactone with at least one member selected from the group consisting of (a) polyamines having from about 2 to 60 total carbon atoms and from about 2 to about 12 nitrogen atoms and (b) amino alcohols containing up to about 50 total carbon atoms, from 1 to about five nitrogen atoms and from 1 to about 15 hydroxyl groups.
Specification