Active chemical transducer with optical fibres and reagent supporting means

• US 4,907,037 A
• Filed: 03/18/1988
• Issued: 03/06/1990
• Est. Priority Date: 03/27/1987
• Status: Expired due to Fees

• Current Assignee: Commissariat a L'Energie Atomique (AES Corporation)
• Original Assignee: Commissariat A L'Energie Atomiqued
• Inventors: Boisde, Gilbert, Perez, Jean-Jacques
• Primary Examiner(s): McGraw, Vincent P.
• Application Number:
  US07/169,958
• Time in Patent Office: 718 Days
• Field of Search: 356/44, 356/412, 250/227, 422/56, 422/58
• US Class Current: 356/412
• CPC Class Codes: G01N 21/7703 using reagent-clad optical fibres or optical waveguides using measurement of total internal reflection or attenuated total reflection G01N21/552; optical fibres or waveguides per se G02B
• CPC Class Codes: G01N 21/80 Indicating pH value
• CPC Class Codes: G01N 2201/08 Optical fibres; light guides
• CPC Class Codes: G01N 2201/122 Kinetic analysis; determining reaction rate

Abstract

It is intended for measuring a given characteristic of a fluid medium and comprises at least one assembly having an appropriate reagent for said measurement and serving to interact with the fluid medium, reagent support means, an optical fibre (2) called the emitting fibre and used for transmitting light in the direction of the support means and at least one other optical fibre (4), called the receiving fibre and which recovers at least part of the light from the support means when the latter receive the light from the emitting fibre. The support means comprise a single porous or adsorbant element (10) to which is fixed the reagent and which is positioned facing the emitting fibre and each receiving fibre. This element is in direct contact with the fluid medium when the transducer is immersed in it and therefore has no confinement membrane.

Claims

1. Active chemical transducer with optical fibres, for measuring a given characteristic of a fluid medium, said transducer having at least one assembly with a reagent appropriate for said measurement and intended to interact with the fluid medium, support means for supporting the reagent, an optical fibre, calling the emitting fibre and used for transmitting light in the direction of the support means and at least one other optical fibre, called the receiving fibre, which recovers at least part of the light from the support means, when the latter receive the light from the emitting fibre, wherein the support means have a single, membraneless, completely porous and adsorbing element, to which is fixed the reagent and which is positioned facing but spaced from the emitting fibre and each receiving fibre, substantially all of the outer surface of said element being unconfined and in direct contact with the fluid medium when the transducer is immersed in the latter.

2. Transducer according to claim 1, wherein each assembly comprises several receiving optical fibres, which are arranged parallel to the corresponding emitting optical fibre and on the same side thereof with respect to the element of the assembly and which are distributed around the emitting optical fibre.

3. Transducer according to claim 2, wherein it comprises several assemblies, which are juxtaposed and rendered integral with one another.

4. Transducer according to claim 2, wherein each element is at least partly transparent and wherein the transducer also comprises optical reflecting means placed on the other side of each element and which reflect part of the light from the support means in the direction of the receiving optical fibres via said support means.

5. Transducer according to claim 1, wherein each element is at least partly transparent and wherein each assembly comprises an emitting optical fibre and a receiving optical fibre arranged on either side of said element.

6. Transducer according to claim 5, wherein it comprises at least two assemblies arranged in series and connected by an optical connecting fibre, which connects the receiving fibre of one assembly to the emitting fibre of the adjacent assembly.

7. Transducer according to claim 5, wherein it comprises at least two assemblies arranged in series in such a way that the transducer is continuous, two adjacent assemblies having a common optical fibre serving as the receiving fibre for one and the emitting fibre for the other.

8. Transducer according to claim 3, wherein the reagents respectively associated with the assemblies differ from one another.

9. Transducer according to claim 1, wherein each element has an approximately spherical or ovoid shape.

10. Transducer according to claim 9, wherein each assembly comprises a rigid sheath, in which are fixed the element, the emitting fibre and each receiving fibre and which is provided with at least one opening facing each element.

11. Transducer according to claim 9, wherein each element is a porous synthetic resin ball.

12. Transducer according to claim 9, wherein each element is a porous silica ball.

13. Transducer according to claim 1, wherein it is intended for measuring a pH-value and wherein each reagent is a colorimetric reagent.

14. Transducer according to claim 13, wherein said reagent is thymol blue.

15. Transducer according to claim 8, wherein it comprises three assemblies respectively having as reagents fluorescein, thymol blue and bromophenol blue or phenol red.

16. Transducer according to claim 6, wherein the reagents respectively associated with the assemblies differ from one another.

17. Transducer according to claim 7, wherein the reagents respectively associated with the assemblies differ from one another.

18. Transducer according to claim 1 wherein the support means for supporting the reagent comprise said element and means for engaging and supporting said element so as to maintain said element in spaced apart relationship from both the emitting fibre and each receiving fibre, said means for engaging and supporting said element functioning in such a way as to expose substantially all of the outer surface of said element to the fluid medium.

19. A transducer according to claim 18 wherein said means for engaging and supporting said element makes line or point contact with said outer surface of said element.

20. A transducer according to claim 19 wherein said means for engaging and supporting said element comprises tubular means having an end engaged with said outer surface of said element and making line or point contact therewith.

21. A transducer according to claim 20 wherein said element is spherical or ovoid in shape and said end of said tubular means is annular in shape.