Severable multilayer thermoplastic film

• US 4,908,278 A
• Filed: 10/31/1986
• Issued: 03/13/1990
• Est. Priority Date: 10/31/1986
• Status: Expired due to Term

• Current Assignee: 3M Company
• Original Assignee: 3M Company
• Inventors: Stambaugh, Bruce D., Peper, William A., Bland, Ralph H.
• Primary Examiner(s): Buffalow, Edith
• Application Number:
  US06/926,371
• Time in Patent Office: 1,229 Days
• Field of Search: 428/500, 428/516, 428/520, 428/76, 264/145
• US Class Current: 428/500
• CPC Class Codes: B32B 2323/10 Polypropylene
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/306 comprising vinyl acetate or vinyl alcohol (co)polymers
• CPC Class Codes: B32B 27/308 comprising acrylic (co)polymers
• CPC Class Codes: B32B 27/32 comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: B32B 27/36 comprising polyesters
• CPC Class Codes: B32B 7/022 Mechanical properties
• CPC Class Codes: C09J 2301/162 the carrier being a laminate constituted by plastic layers only
• CPC Class Codes: C09J 7/29 Laminated material metallised plastics C09J7/22
• CPC Class Codes: Y10T 428/239 Complete cover or casing
• CPC Class Codes: Y10T 428/31855 Of addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31913 Monoolefin polymer
• CPC Class Codes: Y10T 428/31928 Ester, halide or nitrile of addition polymer

Abstract

A dispensable multilayer film having alternating layers of a ductile material, a brittle material, and optionally an intermediate layer. The film has excellent strength in its longitudinal and transverse directions but can be transversely cut by forces of less than 9 Newtons on the cutters of commercially available table top tape dispensers. At least one surface of the sheet material can be coated with a functional material.

Claims

1. A thermoplastic, severable film having a plurality of randomly occurring parallel layers of a brittle thermoplastic polymeric material having a glass transition temperature of greater than 50°

C., and a ductile polymeric material having at least 100% elongation at break situated one on the other in an array, said array comprising the product of a steam of each of said materials which, independently, has been split into a predetermined number of substream and said substreams subsequently recombined to form said array,

wherein no two adjacent layers of said array are of the same material, and

wherein each of said layers has sufficient adhesion to said adjacent layers to enable said film to be severed precisely in a straight line.

2. A severable film according to claim 1 comprising at least five of said layers.

3. A severable film according to claim 1 having a stretch at dispensing of no more than 6.5%.

7. A severable film according to claim 1, 4, 5 or 6 having a yield stress of at least 27×

10³ kilopascals (kPa).

8. A severable film according to claim 1, 4, 5 or 6 requiring a normalized force of no more than 9 Newtons (N) to sever said film.

9. A severable film according to claim 1, 4, 5 or 6 wherein said ductile material comprises a semicrystalline polymer.

10. A severable film according to claim 9 wherein said ductile material is selected from polyester and polymers and copolymers of alpha olefin monomers.

11. A severable film according to claim 10 wherein said ductile material is selected from polymers and copolymers of alpha olefin monomers.

12. A severable film according to claim 11 wherein said alpha olefin monomers are selected from ethylene, propylene, butylene, 4-methylpentene, ethylene/vinyl acetate copolymer, and ethylene/propylene copolymer.

13. A severable film according to claim 12 wherein said alpha olefin monomer is propylene.

14. A severable film according to claim 1, 4, 5 or 6 wherein said ductile material comprises from 20 to 70 percent by weight of said film.

15. A severable film according to claim 1, 4, 5 or 6 wherein said brittle material has less than 10% elongation at break.

16. A severable film according to claim 15 wherein said brittle material is selected from polymers and copolymers of methyl methacrylate, styrene, α

-methyl styrene, ring substituted alkyl styrenes, acrylonitrile, and methacrylonitrile.

17. A severable film according to claim 16 wherein said brittle material is selected from polymers and copolymers of methyl methacrylate.

18. A severable film according to claim 17 wherein said brittle material is polymethyl methacrylate.

19. A severable film according to claim 15 wherein said brittle material comprises from 30 to 80% by weight of said film.

20. A severable film according to claim 1, 4, 5 or 6 having an interlayer adhesion of at least 60 g/cm width.

21. A severable film according to claim 1, 4 or 5 further comprising one or more layers of an intermediate material which enhances the adhesion between the brittle and ductile materials.

22. A severable film according to claim 21 wherein said intermediate material is selected from ethylene/vinyl acetate copolymer, copolymers of ethylene and methyl acrylate, copolymers of ethylene and acrylic acid, and maleic anhydride modified polyolefins and copolymers of polyolefins.

23. A severable film according to claim 22 wherein said intermediate material is a copolymer of ethylene and vinyl acetate.

24. A severable film according to claim 23 wherein said ethylene/vinyl acetate copolymer contains at least about 10% by weight vinyl acetate units.

25. A severable film according to claim 21 wherein said intermediate material comprises from 2 to 30% by weight of the film.

27. A severable film according to claims 1, 4, 5 or 6 having a structure selected from

28. A severable film according to claim 1, 4, 5 or 6 having at least 25 layers.

29. A severable film according to claim 28 having at least 45 layers.

30. A severable film according to claim 29 having at least 65 layers.

31. A severable film according to claim 1, 4, 5 or 6 wherein a layer of a first functional material is applied to at least one surface thereof.

32. A severable film according to claim 31 wherein said first functional material comprises an adhesive.

33. A severable film according to claim 32 wherein said adhesive comprises a pressure sensitive adhesive.

34. A severable film according to claim 31 wherein said first functional material comprises an abrasive material.

35. A severable film according to claim 34 wherein an adhesive is applied to the surface opposite the surface bearing said abrasive material.

36. An oriented film according to claim 1, 4, 5 or 6.

37. A biaxially oriented film according to claim 1, 4, 5 or 6.

40. A severable film according to claim 1, 4, 5 or 6 wherein one of said materials forms an envelope around said film.

41. A severable film according to claim 40 wherein said ductile material forms said envelope.

43. A severable film according to claim 1, 4, 5 or 6 wherein said layers comprise only said ductile material and said brittle material and wherein at least one of said materials has been combined with a component which contains a group reactive with said other material.

44. A severable film according to claim 43 wherein said brittle material contains a component reactive with said ductile material.

45. A severable film according to claim 44 wherein said component is selected from acrylic acid, methacrylic acid, maleic anhydride, vinyl pyridine and oxazoline-containing materials.

4. A severable thermoplastic film having a stretch at dispensing of no more than 6.5% said film comprising at least five layers situated one on the other in a parallel array, said layers occurring essentially randomly in said array and being individually selected from a brittle thermoplastic polymeric material having a glass transition temperature of greater than 50°

C., and a ductile polymeric material having at least 100% elongation at break, wherein no two adjacent layers are of the same material, and

wherein each of said layers has sufficient adhesion to said adjacent layers to enable said film to be severed precisely in a straight line.

5. A severable film having at least five alternating, parallel layers of dissimilar materials, wherein no two adjacent layers are of the same material, and wherein each layer comprises either a brittle thermoplastic polymeric material having a glass transition temperature of greater than 50°

C., or a ductile polymeric material having at least 100% elongation at break, and wherein said film has a stretch at dispensing of no more than 6.5%, and

wherein each of said layers has sufficient adhesion to said adjacent layers to enable said film to be severed precisely in a straight line.

6. A severable film having at least five layers comprising randomly occurring layers of a brittle thermoplastic polymeric material having a glass transition temperature of greater than 50°

C., a ductile polymeric material having at least 100% elongation at break and optionally an intermediate material which enhances the adhesion between the brittle and ductile materials, wherein no two adjacent layers are of the same material, said film stretching by no more than 6.5% when wherein each of said layers has sufficient adhesion to said adjacent layers to enable said film to be severed precisely in a straight line.

26. A severable film according to claim 6 wherein said intermediate material comprises from 2 to 30% by weight of said film.

38. A severable film having a plurality of randomly occurring parallel layers of a brittle thermoplastic polymeric material having a glass transition temperature of greater than 50°

C., and a ductile polymeric material having at least 100% elongation at break situated one on the other in an array, wherein one of said materials forms an envelope around said array.

39. A severable film according to claim 38 wherein said ductile material forms said envelope.

42. A method of making a severable, thermoplastic film containing alternating layers of a ductile polymeric material having at least 100% elongation at break, a brittle thermoplastic polymeric material having a glass transition temperature of greater than 50°

C., and, optionally, an intermediate material capable of enhancing the adhesion between the brittle and ductile materials comprising the steps of

providing an individual stream of each material in a flowable state,

separating each said individual stream into substreams of said materials in said flowable state, the number of substreams being individually predetermined for each stream,

combining said substreams to form an array of randomly occurring parallel layers of said materials in intimate contact with adjacent layers of said materials, wherein the outermost of said materials forms an envelope around said film, and

cooling said film to a non-flowable state.