Process for improving the adhesive strength of electrolessly deposited metal layers on polyimide surfaces

• US 4,910,045 A
• Filed: 12/02/1988
• Issued: 03/20/1990
• Est. Priority Date: 12/23/1987
• Status: Expired due to Term

• Current Assignee: I & T Innovation Technology Entwicklungs-Und Holding AG
• Original Assignee: Bayer AG
• Inventors: Giesecke, Henning, Wolf, Gerhard D., Zecher, Wilfried
• Primary Examiner(s): Beck, Shrive
• Assistant Examiner(s): Dang, Vi Duong
• Application Number:
  US07/278,874
• Time in Patent Office: 473 Days
• Field of Search: 427/96, 427/385.5, 427/304, 427/305, 427/306
• US Class Current: 427/99.1
• CPC Class Codes: C23C 18/30 Activating or accelerating or sensitising with palladium or other noble metal
• CPC Class Codes: H05K 1/0346 containing N
• CPC Class Codes: H05K 3/181 by electroless plating adhesives therefor H05K3/387
• CPC Class Codes: H05K 3/387 for electroless plating H05K3/4661 takes precedence

Abstract

To improve the adhesive strength of electrolessly deposited metal deposits on surfaces of polyimide moulded bodies, the latter are treated with an activator formulation which, in addition to solvents, fillers and organometallic activators, preferably contains 5-25% of a polyimide as binder.

Claims

1. A process for improving the adhesive strength of electrolessly deposited metal layers on polyimide surfaces comprising treating the same with an activator formulation containing a binder, without pickling, wherein the formulation comprises

(a) 0.03-4.00% by weight of an organometallic noble-metal compound as an activator,

(b) 3-40% by weight of a polyimide binder,

(c) 1-30% by weight of a filler and

(d) 45-90% by weight of a solvent.

2. A process according to claim 1, wherein said activator is an organometallic compound of the 1st or 8th subgroup.

3. A process according to claim 1, wherein said binder is an polyimide obtained by condensation of cyclic polycarboxylic acid anhydrides, polycarboxylic acid carboxylic acid anhydrides, polycarboxylic acids or polycarboxylic acid esters with polyamines, polyamides, polyisocyanates or polycarbamic acid esters.

4. A process according to claim 1, wherein said binder is an aliphatic-aromatic polyamideimide obtained by condensation of trimellitic anhydride with polyisocyanates and lactams or polyamides.

5. A printing paste formulation according to claim 1 useful for the production of printed circuits, foiled keyboards, switching mats and sensors.

6. A process according to claim 1, wherein the formulation comprises

0.05 to 3 weight % of the organometallic noble metal compound,

5 to 25 weight % of the polyimide

5 to 25 weight % of the filler and

to 80 weight % of the solvent.

7. A process according to claim 1, wherein the polyimide is a polyamideimide, a polyetherimide, a polyesterimide or a cocondensate or a mixture thereof.

8. A process according to claim 1, wherein the polyimide is a polyamideimide obtained from trimellitic anhydride, caprolactam and 4,4'"'"'-diisocyanatodiphenylmethane or from blends of 4,4'"'"'-diisocyanatodiphenylmethane and mixtures of 2,4- and 2,6-toluylene diisocyanate.