Thermoplastic/foam core/fiber-reinforced resin structural composite material, a process for making said material and a boat structure made from said material

• US 4,910,067 A
• Filed: 07/21/1989
• Issued: 03/20/1990
• Est. Priority Date: 07/21/1989
• Status: Expired due to Term

• Current Assignee: Sabic Innovative Plastics IP BV (Government of Saudi Arabia)
• Original Assignee: Advance Group Incorporated (CURO Group Holdings Corp.)
• Inventors: O'Neill, Michael A.
• Primary Examiner(s): Van Balen, William J.
• Application Number:
  US07/383,809
• Time in Patent Office: 242 Days
• Field of Search: 156/79, 264/45.3, 264/46.4, 428/139, 428/309.9, 428/317.9
• US Class Current: 428/139
• CPC Class Codes: B32B 2260/021 Fibrous or filamentary layer layers of natural mineral fibres or particles being impregnated in a plastic substance B32B19/02
• CPC Class Codes: B32B 2262/101 Glass fibres
• CPC Class Codes: B32B 2266/0278 Polyurethane
• CPC Class Codes: B32B 2266/08 Closed cell foam
• CPC Class Codes: B32B 2305/022 Foam
• CPC Class Codes: B32B 2307/558 Impact strength, toughness
• CPC Class Codes: B32B 2307/712 Weather resistant
• CPC Class Codes: B32B 2323/16 EPDM, i.e. ethylene propylene diene monomer
• CPC Class Codes: B32B 2325/00 Polymers of vinyl-aromatic compounds, e.g. polystyrene
• CPC Class Codes: B32B 2333/04 Polymers of esters
• CPC Class Codes: B32B 2355/02 ABS polymers, i.e. acrylonitrile-butadiene-styrene polymers
• CPC Class Codes: B32B 2605/12 Ships
• CPC Class Codes: B32B 27/065 of foam
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/302 comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
• CPC Class Codes: B32B 27/308 comprising acrylic (co)polymers
• CPC Class Codes: B32B 5/18 characterised by features of a layer of foamed material
• CPC Class Codes: B32B 5/24 one layer being a fibrous or filamentary layer
• CPC Class Codes: B32B 5/245 another layer next to it being a foam layer
• CPC Class Codes: B63B 5/24 made predominantly of plastics surf boards B63B32/57
• CPC Class Codes: Y02T 70/10 : Measures concerning design or construction of watercraft hulls
• CPC Class Codes: Y10T 428/24339 : Keyed
• CPC Class Codes: Y10T 428/24996 : With internal element bridging layers, nonplanar interface between layers, or intermediate layer of commingled adjacent foam layers
• CPC Class Codes: Y10T 428/249986 : Void-containing component contains also a solid fiber or solid particle

Abstract

A structural composite material is provided. The material comprises a thermoplastic layer, a layer of fibrous material spaced from the thermoplastic layer and a foam core disposed in the space between the layers. A resin impregnates and holds the layer of fibrous material together to form a fiber-reinforced resin structure. The foam core and the fiber-reinforced resin structure are integrally formed from a core material capable of having both a foamed character and a resinous character. A process for manufacturing the composite and a boat structure formed from the material are also provided.

Claims

1. A structural composite material comprising:

a thermoplastic layer having an outer surface and an inner surface;

a layer of fibrous material disposed in a first region spaced from the inner side of the thermoplastic layer, and

a core material capable of having a foamed character and a resinous character joining said thermoplastic layer and said layer of fibrous material, said core material having a foamed character defined by a multiplicity of foam cells in a second region between said inner surface of the thermoplastic layer and said first region of fibrous material and having a resinous character impregnating and holding together the layer of fibrous material to form a fiber-reinforced resin structure in said first region,

said composite material having controlled uniformity of thickness, density and resin content throughout.

2. The structural composite material of claim 1 wherein said thermoplastic layer comprises an impact-grade ABS.

3. The structural composite material of claim 1 wherein said thermoplastic layer comprises a first layer of a high impact, weather resistant and chemical resistant polymer and a second layer of an impact-grade ABS.

4. The structural composite material of claim 1 wherein said layer of thermoplastic material comprises an acrylic film, a first layer of a high impact, weather resistant and chemical resistant polymer, and a second layer of impact-grade ABS.

5. The structural composite material of claim 1 wherein said thermoplastic layer comprises an outer acrylic film, an intermediate layer of a high impact, weather resistant and chemical resistant polymer and an inner substrate of impact-grade ABS.

6. The structural composite material of claim 3 wherein said first layer comprises a polymer selected from the group consisting of polycarbonate, PVC, ASA and AES polymers.

7. The structural composite material of claim 6 wherein said first layer comprises an EPDM-rubber modified styrene-acrylonitrile copolymer.

8. The structural composite material of claim 5 wherein said intermediate layer comprises a polymer selected from the group consisting of polycarbonate, PVC, ASA and AES polymers.

9. The structural composite material of claim 8 wherein said intermediate layer comprises an EPDM-rubber modified styrene-acrylonitrile copolymer.

10. The structural composite material of claim 1 wherein said core material in said second region comprises a rigid urethane foam.

11. The structural composite material of claim 10 wherein said rigid urethane foam is of the closed cell type.

12. The structural composite of claim 1 wherein said fibrous material is selected from the group consisting of woven roving fiberglass, mat fiberglass, undirectional fiberglass, bidirectional fiberglass, polyamide fibers, graphite fibers and polyethylene fibers.

13. The structural composite material of claim 12 wherein said fibrous material is bidirectional fiberglass.

14. A structural composite material comprising:

an outer thermoplastic layer, said outer layer having an outer acrylic film, an intermediate layer of an EPDM-rubber modified styrene-acrylonitrile copolymer and an inner substrate of an impact-grade ABS;

an inner layer of bidirectional fiberglass disposed in a first region spaced from said inner substrate;

a urethane core material capable of having a foamed character and a resinous character joining said thermoplastic layer and said inner layer of bidirectional fiberglass, said urethane core material having a foamed character defined by a multiplicity of closed foam cells in a second region between said inner substrate and the inner layer of bidirectional fiberglass and a resinous character impregnating and holding the bidirectional fiberglass together to form a fiberglass reinforced resin structure in said first region,

said structural composite material having controlled uniformity of thickness, density and resin content throughout.

15. A process for manufacturing a structural composite material comprising the steps of:

(a) providing a thermoplastic layer in a desired shape, said layer having an exposed surface and an inner surface;

(b) providing a layer of fibrous material in spaced relationship to the inner surface of said thermoplastic layer;

(c) introducing a foam into the space between the inner surface of the thermoplastic layer and the layer of fibrous material and allowing the foam to expand and completely fill the space, wherein the foam cells adjacent the layer of fibrous material and in contact with said fibrous material convert to a liquid resin which wicks through and completely wets the layer of fibrous material to form a thermoplastic/foam/fiber reinforced resin structure composite.

16. The process set forth in claim 15 where step (a) is further characterized in that said thermoplastic layer is vacuum formed.

17. The process set forth in claim 15 wherein step (a) is further characterized in that said thermoplastic layer comprises an impact-grade ABS.

18. The process set forth in claim 15 wherein step (a) is further characterized in that said thermoplastic layer comprises a first layer of a high impact, weather resistant and chemical resistant polymer and a second layer of an impact grade ABS.

19. The process set forth in claim 15 wherein step (a) is further characterized in that said thermoplastic layer comprises an outer acrylic film, an intermediate layer of a high impact, weather resistant and chemical resistant polymer and a substrate of an impact-grade ABS.

20. The process set forth in claim 18 wherein said polymer is selected from the group consisting of polycarbonate, PVC, ASA and AES thermoplastics.

21. The process set forth in claim 20 wherein said polymer comprises an EPDM-rubber modified styrene-acrylonitrile copolymer.

22. The process set forth in claim 19 wherein said polymer is selected from the group consisting of polycarbonate, PVC, ASA and AES thermoplastics.

23. The process set forth in claim 22 wherein said polymer is an EPDM-rubber modified styrene-acrylonitrile copolymer.

24. The process set forth in claim 15 wherein step (a) comprises:

(A) extruding a laminated thermoplastic sheet, said sheet including a co-extrusion of a high impact, weather resistant and chemical resistant polymer and an impact-grade ABS, and an acrylic film laminated to the exposed surface of said polymer;

(B) heating said thermoplastic sheet;

(C) placing the sheet over the surface of a mold, and

(D) subjecting said sheet to a vacuum forming process to form said thermoplastic layer.

25. The process set forth in claim 24 wherein step (B) comprises heating said thermoplastic sheet at 300-400 degrees F. for a period of 4-5 minutes.

26. The process set forth in claim 15 wherein step (b) comprises:

(E)treating the inner surface of the thermoplastic layer to promote adhesion;

(F) providing a matched die mold having a bottom section and a lid section;

(G) placing said thermoplastic layer in the bottom section of the matched die mold, said mold construction so that when the lid section of the mold is put in place a mold cavity is disposed adjacent the inner surface of the thermoplastic layer;

(H) applying adhesive to the mold surface of the lid section, and

(I) adhering a uniform layer of dry fibrous material to the mold surface of the lid section.

27. The process set forth in claim 26 wherein step (I) is further characterized in that said fibrous material is selected from the group consisting of woven roving fiberglass, mat fiberglass, unidirectional fiberglass, bidirectional fibeglass, polyamide fibers, graphite fibers and polyethylene fibers.

28. The process set forth in claim 27 wherein said fibrous material is bidirectional fiberglass.

29. The process set forth in claim 15 wherein step (b) comprises the step of:

(J) spraying a defoaming agent onto the layer of fibrous material capable of converting the cells of a foam to a liquid resin.

30. The process set forth in claim 29 wherein step (J) is further characterized in that said defoaming agent is selected from the group consisting of Byk-A 500 and methyl ethyl ketone.

31. The process of claim 30 wherein said defoaming agent is Byk-A 500.

32. The process of claim 15 wherein step (d) comprises:

(K) joining said lid section and said bottom section of said matched die mold to form said cavity disposed adjacent the inner surface of said thermoplastic layer;

(L) injecting a urethane foam into said cavity;

(M) allowing the urethane foam to expand until a prescribed foam density is reached, wherein the foam completely fills the mold cavity and the foam cells adjacent to and in contact with the layer of fibrous material convert to a liquid urethane resin which wicks through and completely wets the fibrous layer to form a thermoset layer/foam core/fiber reinforced urethane resin composite, and

(N) curing said thermoplastic layer/foam core/fiber reinforced urethane resin composite in the mold.

33. The process set forth in claim 32 further characterized in that said urethane foam is a rigid urethane foam of the closed cell type.

34. The process set forth in claim 33 wherein said foam has a final density of 6-8 PCF.

37. A structural composite material made according to the process set forth in claim 15.

35. A process for manufacturing a structural composite material comprising the steps of:

extruding a laminated thermoplastic sheet, said sheet including a co-extrusion of an EPDM-rubber modified styrene-acrylonitrile copolymer and an impact-grade ABS, and an acrylic film laminated to the exposed surface of said copolymer;

heating said thermoplastic sheet at 300-4000 degrees F. for a period of 4-5 minutes;

placing the heated thermoplastic sheet over an aluminum-filled epoxy mold and subjecting the sheet to a vacuum forming process to form a thermoplastic outer layer, said thermoplastic outer layer having an exposed surface of acrylic film and an inner surface of an impact-grade ABS;

treating the inner surface of the thermoplastic outer layer to promote adhesion;

providing a mathched die mold made from aluminum-filled epoxy, said mold having a bottom section and a lid section;

placing the thermoplastic outer layer in the bottom section of the matched die mold, said mold constructed so that a mold cavity is disposed adjacent the inner surface of the outer thermoplastic layer;

applying adhesive to the molding surface of the lid section of the matched die mold;

adhering a uniform layer of bidirectional fiberglass to the molding surface of the lid section;

joining said lid section and said bottom section of said matched die mold to form said mold cavity disposed adjacent the inner surface of said outer thermoplastic layer;

injecting a rigid urethane foam of the closed cell type into said mold cavity;

allowing the foam to expand until a foam density of 6-8 PCF is reached, wherein the urethane foam completely fills the mold cavity and the foam cells adjacent to and in contact with the layer of bidirectional fiberglass convert to a liquid urethane resin which wicks through and completely wets the fiberglass to form a thermoplastic outer layer/urethane foam core/fiberglass-reinforced urethane resin inner structure composite, and

curing said thermoplastic outer layer/urethane foam core/ fiberglass-reinforced urethane resin inner structure composite in the mold for 20-30 minutes.

36. A process for manufacturing a structural composite material comprising the steps of:

extruding a laminated thermoplastic sheet, said sheet including a co-extrusion of an EPDM-rubber modified styrene-acrylonitrile copolymer and an impact-grade ABS, and an acrylic film laminated to the exposed surface of said copolymer;

heating said thermoplastic sheet at 300-4000 degrees F. for a period of 4-5 minutes;

placing the heated thermoplastic sheet over an aluminum-filled epoxy mold and subjecting the sheet to a vacuum forming process to form a thermoplastic outer layer, said thermoplastic outer layer having an exposed surface of acrylic film and an inner surface of an impact-grade ABS;

treating the inner surface of the thermoplastic outer layer to promote adhesion;

providing a matched die mold made from aluminum-filled epoxy, said mold having a bottom section and a lid section;

placing the thermoplastic outer layer in the bottom section of the matched die mold, said mold constructed so that a mold cavity is disposed adjacent the inner surface of the outer thermoplastic layer;

applying adhesive to the molding surface of the lid section of the matched die mold;

adhering a uniform layer of bidirectional fiberglass to the molding surface of the lid section;

spraying a defoaming agent onto the layer of fibrous material, said defoaming agent capable converting the cells of a foam to a liquid resin;

joining said lid section and said bottom section of said matched die mold to form said mold cavity disposed adjacent the inner surface of said outer thermoplastic layer;

injecting a rigid urethane foam of the closed cell type into said mold cavity;

allowing the foam to expand until a foam density of 6-8 PCF is reached, wherein the urethane foam completely fills the mold cavity and the foam cells adjacent the layer of bidirectional fiberglass and in contact with the defoaming agent are collapsed and converted to a liquid urethane resin which wicks through and completely wets the fiberglass to form a thermoplastic outer layer/urethane foam core/fiberglass-reinforced urethane resin inner structure composite, and

curing said thermoplastic outer layer/ urethane foam core/ fiberglass-reinforced urethane resin inner structure composite in the mold for 20-30 minutes.

38. A boat structure formed from a structural composite material comprising:

an outer thermoplastic layer, said outer layer having an outer acrylic film, an intermediate layer of an EPDM-rubber modified styrene-acrylonitrile copolymer and an inner substrate of an impact-grade ABS;

an inner layer of bidirectional fiberglass disposed in a first region spaced from said inner substrate, and

a urethane core material capable of having a foamed character and a resinous character joining said thermoplastic layer and said inner layer of bidirectional fiberglass, said urethane core material having a foamed character defined by a multiplicity of closed foam cells in a second region between said inner substrate and said inner layer of bidirectional fiberglass and a resinous character impregnating and holding the bidirectional fiberglass together to form a fiberglass reinforced resin structure in said first region,

said structural composite material having controlled uniformity of thickness, density and resin content throughout.