Pressure sensor utilizing a polyurethane optical fiber

• US 4,915,473 A
• Filed: 02/23/1989
• Issued: 04/10/1990
• Est. Priority Date: 02/23/1989
• Status: Expired due to Fees

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Pedersen, David R., Haese, Nathan N.
• Primary Examiner(s): Sikes, William L.
• Assistant Examiner(s): HEALY, BRIAN
• Application Number:
  US07/314,685
• Time in Patent Office: 411 Days
• Field of Search: 350/96.10, 350/96.29, 350/96.32, 350/96.30, 350/96.34, 250/227, 250/231 P, 73/655, 73/800, 428/160, 428/158, 428/423.1, 264/1.5, 264/1.6
• US Class Current: 385/13
• CPC Class Codes: C08G 18/4825 Polyethers containing two hydroxy groups C08G18/4833 - C08G18/5096 take precedence
• CPC Class Codes: C08G 18/4837 and other oxyalkylene units
• CPC Class Codes: G01L 1/243 using means for applying force perpendicular to the fibre axis
• CPC Class Codes: G02B 1/046 characterised by the core material
• CPC Class Codes: Y10T 428/24512 Polyurethane
• CPC Class Codes: Y10T 428/31551 Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]

Abstract

The invention is a pressure sensing device utilizing a polymer optical fiber with a core comprised of a flexible thermoplastic aliphatic segmented polyurethane. The use of an optical fiber based pressure sensor eliminates the electromagnetic interference problems associated with conventional electronic pressure sensors. Use of polyurethane as the core material for the optical fiber results in an optical fiber with high flexibility, thus making the inventive pressure sensing device more rugged and durable than other optical fiber based pressure sensors.

Claims

1. An optical fiber pressure sensing device comprising:

(A) a light source capable of transmitting light through the optical fiber(s);

(B) a means of transmitting light from the light source to the pressure sensing component;

(C) a pressure sensing component comprising;

(i) at least one unclad optical fiber in which the core is comprised of a flexible thermoplastic aliphatic segmented polyurethane through which light from the light souce is transmitted, and

(ii) a means of compressing the optical fiber(s) such that when the optical fiber(s) is compressed under pressure, the intensity of light passing through the optical fiber(s) varies inversely with the pressure applied without deleteriously affecting the physical integrity of the optical fiber(s);

(D) a means of transmitting light from the pressure sensing component to the light detector; and

(E) a light detector capable of measuring the intensity of light transmitted through the optical fiber(s).

2. The pressure sensing device of claim 1 wherein the optical fiber is further comprised of a clad surrounding the core comprising a flexible material which adheres to the core and which possesses a lower refractive index than the flexible thermoplastic aliphatic segmented polyurethane core.

3. The pressure sensing device of claim 2 wherein the means of transmitting light from the light source to the pressure sensing component and the means of transmitting light from the pressure sensing component to the light detector comprise the flexible thermoplastic aliphatic segmented polyurethane core fiber utilized in the pressure sensing component.

4. The optical fiber pressure sensing device of claim 3 wherein the polyurethane comprises alternating soft and hard segments,

(1) said soft segments being derivable from the reaction of

(a) generally linear molecules terminated at each end by an isocyanate group and consisting of

(i) n residues of one or more methylolterminated polyetherglycols having molecular weights of from about 1000 to about 6000 and consisting essentially of chains of --O--CRR¹ --CH₂ -- units in which each of R and R¹ is hydrogen, methyl, or ethyl independently, except that in at least a preponderance of said units one or the other of R and R¹ is not hydrogen, and

(ii) (n+1) residues of one or more non-aromatic diisocyanates, joined to said polyetherglycol residues by intervening carbamate groups,

n ranging from 1 to about 4 and having an average value of from abut 1.5 to about 1, and

(2) said hard segments being derivable from the reaction of a chain extender with the isocyanate end groups in said molecules and with one or more non-aromatic non-polymeric diisocyanates of a nature such that the resulting carbamate groups will be unable to associate with each other in such a manner as to result in domain crystallinity in the resulting polymer.

5. The optical fiber pressure sensing device of claim 4 wherein the ratio of glycol:

diisocyanate;

chain extender ranges from about 1;

3;

2 to about 1;

15;

14.

6. The optical fiber pressure sensing device of claim 5 wherein he polyurethane possesses a weight-average molecular weight of between about 100,000 and about 200,000.

7. The optical fiber pressure sensing device of claim 6 wherein the polyurethane possesses a Shore hardness as measured by ASTM D2240-86 of between about A45 and about D80.

8. The optical fiber pressure sensing device of claim 7 wherein the clad possesses a refractive index which is at least 0.01 units less than the refractive index of the core.

9. The optical fiber pressure sensing device of claim 8 wherein the clad comprises polysiloxane.

10. The optical fiber pressure sensing evice of claim 9 wherein the optical fiber possesses an attenuation over the range of wavelengths of about 400 to 900 nanometers of less than about 30 decibels/meter.

11. The optical fiber pressure sensing device of claim 10 wherein the optical fiber possesses a maximum use temperature of about 60°

C. or greater.

12. The optical fiber pressure sensing device of claim 11 wherein the optical fiber has a diameter between about 0.1 and about 2.0 millimeters.

13. The optical fiber pressure sensing device of claim 3 which additionally comprises

(F) an informational handling system capable of recording the light intensity signal received from the light detector.

14. The optical fiber pressure sensing device of claim 13 wherein the informational handling system is comprised of a voltmeter, oscilloscope, strip chart recorder, or computer.

15. The optical fiber pressure sensing device of claim 13 which additionally comprises a means for focussing the light from the light source through the optical fiber.

16. The optical fiber pressure sensing device of claim 15 wherein the light source comprises a visible region tungston bulb, a light emitting diode, or a gaseous laser.

17. The optical fiber pressure sensing device of claim 16 wherein he light detector comprises a silicone PIN or other semiconducting diode or a photomultiplier tube.

18. The optical fiber pressure sensing device of claim 17 wherein the compression means comprises two hard parallel plates.

19. The optical fiber pressure sensing device of claim 18 capable of measuring pressures up to about 0.5 pounds/inch of fiber.