Nitramine-containing homopolymers and co-polymers and a process for the preparation thereof

• US 4,916,206 A
• Filed: 11/14/1988
• Issued: 04/10/1990
• Est. Priority Date: 11/14/1988
• Status: Expired due to Fees

• Current Assignee: Arch Chemicals Incorporated (Lonza Group AG)
• Original Assignee: OLIN Corporation
• Inventors: Day, Roger W., Hani, Rahim
• Primary Examiner(s): Foelak, Morton
• Assistant Examiner(s): Acquah, S. A.
• Application Number:
  US07/270,977
• Time in Patent Office: 512 Days
• Field of Search: 528/272, 528/274, 528/289, 528/292, 528/310, 149/19.4
• US Class Current: 528/272
• CPC Class Codes: C08G 63/6856 Dicarboxylic acids and dihydroxy compounds

Abstract

Energetic binders, and, more specifically, a class of nitramine-containing homopolymers and co-polymers characterized by favorable viscosity and glass transition temperature are prepared.

Claims

1. A nitramine-containing polymer characterized by an advantageous combination of a low viscosity and a low glass transition temperature and represented by the following empirical structural formula:

space="preserve" listing-type="equation">[(OOCCH.sub.2 CH.sub.2 --R--CH.sub.2 CH.sub.2 CO).sub.x (OOCCH.sub.2 CH.sub.2 --R'"'"'--CH.sub.2 CH.sub.2 CO).sub.y (OR")].sub.n

wherein R and R'"'"' are the same or different moieties selected from the group consisting of --N(NO₂)--, --N(NO₂)CH₂ CH₂ N(NO₂)--, and --N(NO₂)ZN(NO₂)--, wherein Z is a linear or branched-chain hydrocarbon having between 3 and 10 carbon atoms, with the proviso that at least one R or R'"'"' moiety on average per molecule of said polymer must be other than --N(NO₂)CH₂ CH₂ N(NO₂)--, and wherein x represents a mole fraction having a value between 0 and 1, y represents a mole fraction equal to 1 minus x and having a value between 0 and 1, R" is a linear or branched chain alkylene or alkylene ether radical having between 2 and 12 carbon atoms and having primary or secondary carbon atoms at said radical'"'"'s points of attachment in said polymer, and n has a value between 2 and 50, said polymer being prepared by reacting a nitramine-containing dicarboxylic acid with a diol, said nitramine-containing dicarboxylic acid being selected from the group consisting of 4,7-dinitraza-1,10-decanedioic acid (DNDA);

5-methyl-4,7-dinitraza-1,10-decanedioic acid (MDNDA);

4-nitraza-1,7-heptanedioic acid (NHDA);

4,8-dinitraza-1,11-undecanedioic acid, and combinations thereof; and

said diol being selected from the group consisting of ethylene glycol, propylene glycol, 1,4-butane diol, 1,6-hexane diol, diethylene glycol and combinations thereof.

2. The polymer of claim 1 which is terminated by primary hydroxyl groups.

3. The polymer of claim 1 wherein x is 1, y is 0, and R is N(NO₂).

4. The polymer of claim 1 wherein x is 1, y is 0, and R is N(NO₂)CH₂ CH₂ CH₂ N(NO₂).

5. The polymer of claim 1 wherein x is 0.3, y is 0.7, R is N(NO₂)CH₂ CH₂ N(NO₂), and R'"'"' is N(NO₂).

6. The polymer of claim 1 wherein x is 0.3, y is 0.7, R is N(NO₂) and R'"'"' is N(NO₂)CH₂ CH₂ CH₂ N(NO₂).

7. The polymer of claim 1 wherein x is 0.7, y is 0.3, R is N(NO₂), and R'"'"' is N(NO₂)CH₂ CH₂ CH₂ N(NO₂).

8. The polymer of claim 1 wherein x is 0.3, y is 0.7, R is N(NO₂)CH₂ CH₂ N(NO₂), and R'"'"' is N(NO₂)CH₂ CH₂ CH₂ N(NO₂).

9. The polymer of claim 1 which is terminated by carboxyl groups.

10. The polymer of claim 1 wherein the polymer is end-capped by reacting said polymer with a functional moiety to impart a desired terminal functionality to said polymer.

11. A process for producing a nitramine-containing polymer which comprises the steps of reacting a nitramine-containing dicarboxylic acid monomer with a diol monomer in the presence of an acid catalyst by a melt polymerization reaction to form said nitramine-containing polymer while removing by-product water during the course of said reaction.

12. The process of claim 11 wherein said by-product water is removed by distillation thereof.

13. The process of claim 11 wherein by-product water is removed during the course of said reaction by vacuum distillation with the proviso that a vacuum is applied only after any volatile monomer reactants have reacted.

14. The process of claim 11 wherein said nitramine-containing polymer is purified by precipitation using a paired solvent/non-solvent mixture.

15. The process of claim 14 wherein the solvent is selected from the group consisting of methylene chloride, chloroform, tetrahydrofuran, and mixtures thereof.

16. The process of claim 14 wherein the non-solvent is selected from the group consisting of water, methanol, ethanol, hexane, cyclohexane, benzene, and mixtures thereof.

17. The process of claim 11 which is conducted at a reaction temperature of between about 60°

C. and about 150°

C.

18. The process of claim 11 which is conducted at a reaction pressure of atmospheric or subatmospheric pressure.