Electrolysis cell and method of use

• US 4,921,586 A
• Filed: 03/31/1989
• Issued: 05/01/1990
• Est. Priority Date: 03/31/1989
• Status: Expired due to Term

• Current Assignee: United Technologies Corporation (Raytheon Technologies Corporation d/b/a RTX)
• Original Assignee: United Technologies Corporation (Raytheon Technologies Corporation d/b/a RTX)
• Inventors: Molter, Trent M.
• Primary Examiner(s): THOMPSON, JEFFREY
• Application Number:
  US07/331,454
• Time in Patent Office: 396 Days
• Field of Search: 204/72, 204/77, 204/263, 204/265, 204/266
• US Class Current: 205/338
• CPC Class Codes: C25B 3/25 Reduction
• CPC Class Codes: C25B 9/23 comprising ion-exchange membranes in or on which electrode material is embedded

Abstract

The present invention discloses an improved solid polymer electrolysis cell for the reduction of carbon dioxide. The improvement being the use of a cathode having a metal phthalocyanine catalyst which results in the suppression of the formation of hydrogen during the reduction process and the subsequent improved conversion efficiency for carbon dioxide.

Claims

1. An improved electrolysis cell for the reduction of carbon dioxide having an anode, a cathode and a solid polymer electrolyte, the improvement comprising a primary carbon dioxide reducing cathode containing a catalytic material having a hydrogen overvoltage greater than platinum and a secondary carbon dioxide reducing cathode having a hydrogen overvoltage greater than platinum thereby resulting in the suppression of the formation of hydrogen gas and improved efficiency for the reduction of carbon dioxide.

2. The cell of claim 1 wherein the secondary catalyst is in the form of one or more screens.

3. The cell of claim 2 wherein the screens comprise stainless steel, copper, brass, niobium, zirconium, or titanium.

4. The cell of claim 3 wherein the secondary catalyst comprises a screen comprising a carbon dioxide reducing material having a hydrogen overvoltage greater than platinum wherein said screen is substantially coated with a carbon dioxide reducing catalyst having a hydrogen overvoltage greater than platinum.

5. The cell of claim 4 wherein the coating catalyst is a metal.

6. The cell of claim 4 wherein the coating is indium.

7. The cell of claim 4 wherein the coating catalyst is a metal porphyrin.

8. The cell of claim 4 wherein the coating is a metal phthalocyanine.

9. The cell of claim 8 wherein the metal phthalocyanine is selected from the group consisting of iron, copper, nickel and cobalt phthalocyanine.

10. The cell of claim 8 wherein the metal phthalocyanine is nickel phthalocyanine.

11. The cell of claim 1 wherein the primary cathode comprises a metal phthalocyanine.

12. The cell of claim 11 wherein the metal phthalocyanine is nickel phthalocyanine.

13. The cell of claim 6 wherein the primary cathode comprises a metal phthalocyanine.

14. The cell of claim 13 wherein the metal phthalocyanine is nickel phthalocyanine.

16. The method of claim 11 wherein the metal phthalocyanine is selected from the group consisting of iron, nickel, copper and cobalt phthalocyanine.

17. The method of claim 12 wherein the secondary catalyst is in the form of one or more screens.

18. The method of claim 14 wherein the secondary catalyst is formed from a material selected from the group consisting of tin, lead, copper, zinc, cadmium, gallium, silver, gold, indium, iron, tungsten, molybdenum and carbon.

19. The method of claim 14 wherein the screen is substantially coated with a metal porphyrin.

20. The method of claim 12 wherein the screen is coated with a metal phthalocyanine.

21. The method of claim 17 wherein the metal phthalocyanine is selected from the group consisting of iron, nickel, copper and cobalt.

22. The method of claim 17 wherein the metal phthalocyanine is nickel phthalocyanine.

23. The method of claim 14 wherein the coating comprises indium, tin, lead, copper, zinc, cadmium, gallium, silver, gold, iron, tungsten, molybdenum, or carbon.

24. The method of claim 11 wherein the carbon dioxide material is at a pressure greater than 100 pounds per square inch.

25. The method of claim 11 wherein the carbon dioxide material is at a pressure greater than 500 psi.

26. The method of claim 11 wherein the carbon dioxide material is at a pressure of between 200 and 1000 psi.

27. The method of claim 11 wherein the pressure of the carbon dioxide material in contact with the cathode is about 600 psi to about 900 psi.

15. A method for reducing carbon dioxide in an electrolysis cell having an anode a cathode and a solid polymer electrolyte comprising;

contacting the anode with a hydrogen containing material,

converting said hydrogen containing material to hydrogen ions,

transporting said hydrogen ions through the solid polymer electrolyte to the cathode;

contacting the cathode with carbon dioxide;

thereby causing the carbon dioxide to react with the hydrogen ions to form organic compounds wherein the improvement comprises a cathode having a primary and secondary cathode wherein said primary cathode comprises a metal phthalocyanine and said secondary cathode comprises materials capable of reducing carbon dioxide and also having a hydrogen overvoltage greater than platinum.