Container for photographic film cartridge

• US 4,921,737 A
• Filed: 06/30/1988
• Issued: 05/01/1990
• Est. Priority Date: 07/02/1987
• Status: Expired due to Term

• Current Assignee: Fujifilm Corporation (Fujifilm Holdings Corporation)
• Original Assignee: Fuji Photo Film Co Limited (Fujifilm Holdings Corporation)
• Inventors: Akao, Mutsuo
• Primary Examiner(s): Seidleck, James J.
• Application Number:
  US07/213,600
• Time in Patent Office: 670 Days
• Field of Search: 523/200, 524/108, 524/232, 524/231, 524/229, 524/583, 428/36.92, 206/316.1, 206/407
• US Class Current: 428/36.92
• CPC Class Codes: C08K 5/20 Carboxylic acid amides
• CPC Class Codes: C08K 9/04 Ingredients treated with organic substances treated with macromolecular compounds C08K9/08
• CPC Class Codes: C08L 23/10 Homopolymers or copolymers of propene
• CPC Class Codes: G03C 3/00 Packages of films for inserting into cameras, e.g. roll-films, film-packs; Wrapping materials for light-sensitive plates, films or papers, e.g. materials characterised by the use of special dyes, printing inks, adhesives wrapping materials in general B65D
• CPC Class Codes: Y10T 428/1397 Single layer [continuous layer]

Abstract

A container body for photographic film cartridge composed of a resin comprising more than 70 wt. % of polypropylene resin, 0.01 to 2 wt. % of a fatty acid amide lubricant, 0 to 1 wt. % of an antioxidant and 0.01 to 1 wt. % of an organic nucleating agent of which the surface has previously been treated with a stabilizer selected from the group consisting of aliphatic metal salts, metal salts of alkyl lactic acids and metal salts of lactic acid.

The container body of the invention is excellent in dropping strength, transparency and odor. The injection moldability is also excellent, because of good resin fluidity and high crystallization temperature.

Claims

1. A container body for photographic film cartridge composed of a resin comprising more than 70 wt. % of polypropylene resin, 0.01 to 2 wt. % of a fatty acid amide lubricant, 0 to 1 wt. % of an antioxidant and 0.01 to 1 wt. % of an organic nucleating agent wherein more than 30% of the surface of the organic nucleating agent is coated with a stabilizer selected from the group consisting of metal salts of fatty acids metal salts of condensates of lactic acid and a fatty acid and metal salts of lactic acid.

2. The container body of claim 1 wherein said polypropylene resin is a propylene-α

-olefin copolymer resin of which propylene content is 90 to 99 wt. %.

3. The container body of claim 1 wherein the melt flow rate of said polypropylene resin is 12 to 80 g/10 minutes measured according to ASTM D-1238 at 230°

C. under 2160 g loading.

4. The container body of claim 1 wherein said organic nucleating agent is selected from the group consisting of carboxylic acids, dicarboxylic acids, their salts and anhydrides, salts and esters of aromatic sulfonic acids, aromatic phosphinic acids, aromatic phosphinic acids, aromatic carboxylic acids and their aluminum salts, metal salts of aromatic phosphoric acids, alkyl alcohols having a number of carbon atoms of 3 to 30, condensation products of a polyhydric alcohol and an aldehyde, and alkylamines.

5. The container body of claim 1 wherein said organic nucleating agent is selected from the group consisting of aluminum p-t-butylbenzoate, aluminum hydroxy-di-p-t-butylbenzoate, 1,3,2,4-dibenzylidenesorbitol, the di-substituted benzylidene-sorbitol represented by the following formula:

##STR3## wherein R₁ and R₂ indicate an alkyl group or an alkoxy group having a number of carbon atoms of 1 to 8 or a halogen, and m andn are 0 to 3 and m+n are greater or equal to 1,

metal salts, of stearyl lactic acid, the compounds, represented by the following formula;

##STR4## wherein R₃ indicates an alkyl group having a number of carbon atoms of 8 to 30, and k and l are 0 to 10 and k+l≧

1,

metal salts, of 1,2-dihydroxystearic acid, stearyl alcohol, lauryl alcohol, sodium benzoate, benzoic acid, and sebacic acid.

6. The container body of claim 1 wherein said organic nucleating agent is selected from the group consisting of dibenzylidenesorbitol, 1,3,2,4-di(methylbenzylidene) sorbitol, 1,3,2,4-di(ethylbenzylidene)sorbitol, 1,3,2,4-di(propylbenzylidene)sorbitol, 1,3,2,4-di(methoxybenzylidene)sorbitol, 1,3,2,4-di(ethoxybenzylidene) sorbitol, 1,3,2,4-di(p-methylbenzylidne)sorbitol, 1,3,2,4-di(p-chlorobenzylidene)sorbitol, 1,3,2,4-di(p-methoxybenzylidene)sorbitol, 1,3,2,4-di(alkylbenzylidene) sorbitol and 1,3,2,4-bis(methylbenzylidene)sorbitol and tribenzylidenesorbitol.

7. The container body of claim 1, 4 or 5 wherein said stabilizer is selected from the group consisting of calcium stearate, aluminum stearate, zinc stearate, sodium stearate, magnesium stearate, calcium behenate, calcium stearyl lactate, calcium lauryl lactate, calcium lactate and barium lactate.

8. The container body of claim 1 wherein said metal salts of fatty acids have 7 to 32 carbon atoms.

9. The container body of claim 8 wherein said metal salts of fatty acids have 11 to 26 carbon atoms.

10. The container body of claim 1 wherein said condensates of lactic acid and a fatty acid have 7 to 32 carbon atoms.

11. The container body of claim 10 wherein said condensates of lactic acid and a fatty acid have 11 to 26 carbon atoms.