Radiation-hardenable agent for the scratch-resistant coating of organic glasses

• US 4,921,881 A
• Filed: 06/07/1988
• Issued: 05/01/1990
• Est. Priority Date: 06/23/1987
• Status: Expired due to Fees

• Current Assignee: Degussa AG (Rag-Stiftung)
• Original Assignee: Degussa AG (Rag-Stiftung)
• Inventors: Weigelt, F. Werner, Morlock, Gerhard
• Primary Examiner(s): Bleutge, John C.
• Assistant Examiner(s): BERMAN, SUSAN W
• Application Number:
  US07/203,100
• Time in Patent Office: 693 Days
• Field of Search: 522/99, 528/33, 528/32
• US Class Current: 522/99
• CPC Class Codes: C08F 283/00 Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
• CPC Class Codes: C08F 283/124 on to polysiloxanes having carbon-to-carbon double bonds
• CPC Class Codes: C09D 183/10 Block or graft copolymers containing polysiloxane sequences obtained by polymerising a compound having a carbon-to-carbon double bond on to a polysiloxane C09D151/08, C09D153/00
• CPC Class Codes: C09D 4/06 Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
• CPC Class Codes: Y10S 528/901 Room temperature curable silicon-containing polymer

Abstract

A radiation-hardenable agent for the scratch-resistant coating of organic glasses consists of a cocondensate of vinyl trimethoxysilane or vinyl triethoxysilane and tetramethoxysilane or tetraethoxysilane, a reactive diluent which comprises at least 2 vinyl, acrylic or methacrylic groups per molecule and, if necessary, of a known photoinitiator. The agent can be prepared by forming the cocondensate in the presence of an amount of water which is at least equivalent to the methoxy or ethoxy groups present or in the presence of a small amount of a carboxylic acid, removing all volatile portions of the reaction mixture and mixing the oily siloxane remaining as residue with the other components.

Claims

1. A radiation-hardenable agent for the scratch-resistant coating of organic glasses, consisting essentially of

(A) 82 to 64% by weight of a cocondensate prepared by the cocondensation of

(A1) 90 to 65% by weight of a member of the group consisting of vinyl trimethoxysilane, vinyl triethoxysilane and mixtures of these two silanes and

(A2) 10 to 35% by weight of a member of the group consisting of tetramethoxysilane, tetraethoxysilane and mixtures of these two silanes

(B) 9 to 27% by weight of at least one reactive diluent comprising at least 2 vinyl, acrylic or methacrylic groups per molecule and

(C) 0 to 9% by weight of at least one known photoinitiator, the total amount of components (A), (B) and (C) being 100% by weight.

2. A radiation-hardenable agent as set forth in claim 1 in which the ratio of vinyl groups to silicon atoms in component (A) is between 0.5:

1 and 0.92;

1.

3. A radiation-hardenable agent according to claim 2 in which the ratio of vinyl groups to silicon atoms in component (A) is between 0.75:

1 and 0.85;

1.

4. A radiation-hardenable agent according to any one of claims 1 to 3 in which 1 to 10% by weight of component (B) comprises at least one free hydroxyl group per molecule.

5. A radiation-hardenable agent according to any one of claims 1 to 3 in which component (B) is a mixture of pentaerythritol triacrylate and hexane diol-1,6-diacrylate.

6. A radiation-hardenable agent according to any one of claims 1 to 3 in which the amount of component (C) is 7 to 9% by weight, said agent being hardenable by means of ultraviolet radiation.