Process for the production of particulate ammonium nitrate for solid fuels or explosives

• US 4,925,600 A
• Filed: 12/14/1987
• Issued: 05/15/1990
• Est. Priority Date: 12/16/1986
• Status: Expired due to Term

• Current Assignee: Fraunhofer Gesellschaft Zur Foerderung Der Angewandten Forsching E.V.
• Original Assignee: Fraunhofer Gesellschaft Zur Foerderung Der Angewandten Forsching E.V.
• Inventors: Hommel, Horst, Schubert, Hiltmar
• Primary Examiner(s): Nelson, Peter A.
• Application Number:
  US07/132,255
• Time in Patent Office: 883 Days
• Field of Search: 264/3.1, 264/3.4, 264/3.5, 264/3.6, 149/109.6, 149/46, 149/60
• US Class Current: 264/3.4
• CPC Class Codes: C06B 21/0066 by granulation, e.g. flaking
• CPC Class Codes: C06B 31/28 the salt being ammonium nitrate

Abstract

Particulate ammonium nitrate for use as an oxidizer in solid propellants orxplosives is, according to a first alternative, produced in that a solid mixture of ammonium nitrate with phase stabilizers, e.g. metal oxides is melted in several small batches housed in spatially separate manner and reactively reacted, the melts of the individual batches are successively atomized by drawing off and the mixture is supplied cyclically to all the batches, the melt particles being solidified in a cooling gas sinking stream. According to another alternative, initially a phase-stabilizing additive in the form of a metalamine complex is reacted in the aqueous phase from metal nitrate and ammonia, dried and mixed with solid ammonium nitrate, the mixture is melted and then atomized by drawing off. In addition, both processes can be combined.

Claims

1. A process for producing particulate ammonium nitrate for use as an oxidizer in solid propellants or explosives, wherein a solid mixture of ammonium nitrate and at least one additive for effecting phase stabilization is melted and reacted, said additive being selected from the group consisting of copper oxide, nickel oxide and mixtures thereof;

the melt is atomized to form melt particles; and

the melt particles are solidified in a cooling gas stream;

said process being further characterized by successively producing the melt in several small batches, said batches being housed in a spatially separated arrangement;

supplying the melt of each batch to a common spraying vessel;

atomizing the melt; and

cyclically supplying the mixture to each of the several batches.

2. A process for producing particulate ammonium nitrate for use as the oxidizer in solid propellants or explosives, which comprises forming a mixture of solid ammonium nitrate, at least one additive for phase stabilization a metal (Cu, Ni) -amine complex, melting the mixture to form a melt;

atomizing the melt to produce melt particles; and

solidifying the melt particles in a cooling gas stream;

in a preliminary stage prior to melting the mixture, producing the metal (Ni, Cu)-ammine complex separately in an aqueous phase, drying the complex and mixing the dried complex with a solid ammonium nitrate and with an additive selected from the group consisting of nickel nitrate, copper nitrate or a mixture thereof.

3. A process according to claim 2, wherein the content of at least one of nickel and copper or the metal/ammine complex content of the end product is so adjusted by the mixing ratio of ammonium nitrate, metal nitrate and metal/ammine complex that the final content is between 1 and 5%.

4. A process according to claim 2, wherein the mixture of metal complex, nickel nitrate and pure ammonium nitrate is continuously dosed into the metal in proportion to the quantity drawn off for atomization.

5. A process according to one of claims 2 to 4, further comprising producing the mixture of metal complex, nickel nitrate and ammonium nitrate in several small batches, said batches being housed in a spatially separate arrangement and atomizing the melt of each batch individually or in continuous sequence.