Hydrometallurgical process for producing finely divided iron based powders

• US 4,927,456 A
• Filed: 05/27/1987
• Issued: 05/22/1990
• Est. Priority Date: 05/27/1987
• Status: Expired due to Fees

• Current Assignee: GTE Products Corporation
• Original Assignee: GTE Products Corporation
• Inventors: Johnson, Walter A., Kopatz, Nelson E., Ritsko, Joseph E.
• Primary Examiner(s): Russel, Jeffrey E.
• Application Number:
  US07/054,479
• Time in Patent Office: 1,091 Days
• Field of Search: 75/0.5 BB, 75/0.5 AA, 75/0.5 AA, 75/0.5 BA, 264/14.0
• US Class Current: 75/346
• CPC Class Codes: B22F 1/065 Spherical particles

Abstract

A process for producing finely divided spherical iron group based metallic powders comprises forming an aqueous solution containing a source of the appropriate metal sources in a mineral acid, forming a reducible iron group based material from the solution, reducing the material to iron group based metal powder particles, subjecting the metal particles to a high temperature zone to melt a portion of the particles and to form droplets and cooling the droplets to form an essential spherical iron group based metallic powders.

Claims

1. A process consisting essentially of:

(a) forming an aqueous solution containing at least one iron group metal value,

(b) forming a reducible solid metallic material selected from the group consisting of iron group metal salts, oxides, hydroxides and mixtures thereof from said solution,

(c) reducing said material to form iron group based metallic powder particles,

(d) entraining at least a portion of said powder particle in a carrier gas to form entrained iron group metal powder particles,

(e) feeding said entrained particles and said carrier gas into a high temperature zone and maintaining said particles in said zone for a sufficient time to melt at least about 50% by weight of said particles, and to form droplets therefrom and

(f) cooling said droplets to form iron group metal based particles having essentially a spherical shape and a majority of said particles having a size less than 20 micrometers.

2. A process according to claim 1 wherein said solution contains a water soluble acid.

3. A process according to claim 2 wherein said reducible solid material is formed by evaporation of the water from the solution.

4. A process according to claim 2 wherein said reducible solid material is formed by adjusting the pH of the solution to form a solid which is separated from the resulting aqueous phase.

5. A process according to claim 1 wherein the material from step (b) is subjected to a particle size reduction step prior to the chemical reduction step (c).

6. A process according to claim 1 wherein the powder particles from step (c) are subjected to a particle size reduction step prior to the entraining step (d).

7. A process according to claim 1 wherein said iron group metal is iron.

8. A process according to claim 1 wherein said iron group metal is cobalt.

9. A process according to claim 1 wherein said iron group metal is nickel.

10. A process according to claim 1 wherein said high temperature zone is created by a plasma torch.

11. A process according to claim 1 wherein said carrier gas is an inert gas.

12. A process according to claim 1 wherein in step e essentially all of said iron group metal particles are melted.

13. A process according to claim 1 wherein at least 50% of said particles having essentially a spherical shape have a size less than about 10 micrometers.