NOx sensor having catalyst for decomposing NOx

• US 4,927,517 A
• Filed: 04/27/1989
• Issued: 05/22/1990
• Est. Priority Date: 04/30/1988
• Status: Expired due to Term

• Current Assignee: NGK Insulators Limited
• Original Assignee: NGK Insulators Limited
• Inventors: Mizutani, Yoshihiko, Nishizawa, Hitoshi
• Primary Examiner(s): Kaplan, G. L.
• Application Number:
  US07/343,682
• Time in Patent Office: 390 Days
• Field of Search: 204/1 N, 204/410, 204/412, 204/425, 204/406, 338/34, 422/98
• US Class Current: 204/406
• CPC Class Codes: G01N 27/4065 Circuit arrangements specially adapted therefor
• CPC Class Codes: G01N 27/4074 for detection of gases other than oxygen
• CPC Class Codes: G01N 27/417 using cells , i.e. more than one cell and probes with solid electrolytes
• CPC Class Codes: G01N 33/0037 for NOx
• CPC Class Codes: Y02A 50/20 Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Abstract

An NOx sensor having an electrochemical cell having a solid electrolyte body and a first and a second electrode, a portion that permits restricted communication of the first electrode with an external measurement gas space, a catalyst disposed adjacent the first electrode for decomposing NOx, a device for applying a current between the first and second electrodes, a current measuring device for detecting a current flowing between the first and second electrodes, an oxygen partial pressure measuring device for detecting an oxygen partial pressure of the atmosphere surrounding the first electrode, and a control device for calculating the concentration of NOx contained in the measurement gas in the external space, based on a first and a second current value. The current value is detected by the current measuring device when the oxygen partial pressure detected by the oxygen partial pressure measuring device is higher than a predetermined level above which the decomposition of NOx by the catalyst will not occur and below which the decomposition of NOx will occur. The second current value is detected when the oxygen partial pressure is lower than the predetermined level.

Claims

1. An NOx sensor for determining the concentration of NOx contained in a measurement gas, comprising:

an electrochemical cell having a solid electrolyte body, and at least two electrodes, formed on said solid electrolyte body, which includes a first electrode exposed to said measurement gas and a second electrode;

diffusion-resistance means for restricted communication of said first electrode with an external space in which said measurement gas exists, said diffusion-resistance means having a predetermined resistance to diffusion of said measurement gas therethrough from said external space toward said first electrode;

a catalyst disposed adjacent said first electrode, for decomposing NOx contained in an atmosphere adjacent said catalyst;

current applying means for applying an electric current between said first and second electrodes of said electrochemical cell;

current measuring means for detecting an electric current flowing between said first and second electrodes;

oxygen partial pressure measuring means for detecting an oxygen partial pressure of the atmosphere adjacent said catalyst; and

control means for calculating the concentration of NOx contained in said measurement gas, based on a first current value and a second current value, said first current value being detected by said current measuring means when said oxygen partial pressure detected by said oxygen partial pressure measuring means is higher than a predetermined level above which the decomposition of NOx by said catalyst will not occur and below which said decomposition of NOx will occur, and said second current value being detected by said curent measuring means when said oxygen partial pressure detected by said oxygen partial pressure measuring means is lower than said predetermined level.

2. The NOx sensor of claim 1, further comprising a second electrochemical cell in addition to a first electrochemical cell which consists of said electrochemical cell having said first and second electrodes, said second electrochemical cell having a third electrode, which consists of said first electrode of said first electrochemical cell, and a fourth electrode exposed to a reference gas of a predetermined reference oxygen partial pressure, said third and fourth electrodes being formed on said solid electrolyte body on which said first and second electrodes are formed, said oxygen partial pressure measuring means comprising said solid electrolyte body, said third electrode, said fourth electrode, and voltage measuring means for detecting an electromotive force induced between said first and fourth electrodes.

3. The NOx sensor of claim 1, further comprising a second electrochemical cell in addition to a first electrochemical cell which consists of said electrochemical cell having said first and second electrodes, said second electrochemical cell having another solid electrolyte body, a third electrode exposed to a substantially same atmosphere as the atmosphere adjacent said catalyst, and a fourth electrode exposed to a reference gas having a predetermined reference oxygen partial pressure, said oxygen partial pressure measuring means comprising said second electrochemical cell, and voltage measuring means for detecting an electromotive force induced between said third and fourth electrodes.

4. The NOx sensor of claim 1, wherein said oxygen partial pressure measuring means comprises said electrochemical cell and voltage measuring means for detecting an electromotive force induced between said first and second electrodes.

5. The NOx sensor of claim 4, wherein said current applying means applies said electric current intermittently, and said voltage measuring means detects said electromotive force while the electric current is not applied between said first and second electrodes by said current applying means, the detected electromotive force being held for a predetermined time duration.

6. The NOx sensor of claim 1, wherein said oxygen partial pressure measuring means comprises:

a semiconductor oxide whose electrical resistance varies with the oxygen partial pressure of an atmosphere to which the semiconductor oxide is exposed;

a pair of electrodes formed on said semiconductor oxide; and

resistance measuring means connected between said pair of electrodes, for detecting the electrical resistance of said semiconductor oxide.

7. The NOx sensor of claim 1, wherein said catalyst is combined with said first electrode and said first electrode functions as said catalyst.

8. An NOx sensor for determining the concentration of NOx contained in a measurement gas, comprising:

a first and a second sensing unit, each of which comprises;

(a) an electrochemical cell having a solid electrolyte body and at least two electrodes, formed on said solid electrolyte body, which include a first electrode exposed to said measurement gas and a second electrode;

(b) diffusion-resistance means for restricted communication of said first electrode with an external space in which said measurement gas exists, said diffusion-resistance means having a predetermined resistance to diffusion of said measurement gas therethrough from said external space toward said first electrode;

(c) a catalyst disposed adjacent said first electrode, for decomposing NOx contained in an atmosphere adjacent the catalyst;

(d) current applying means for applying an electric current between said first and second electrodes of said electrochemical cell;

(e) current measuring means for detecting an electric current flowing between said first and second electrodes; and

(f) oxygen partial pressure measuring means for detecting an oxygen partial pressure of the atmosphere adjacent the catalyst; and

control means for calculating the concentration of NOx contained in said measurement gas, based on a first current value and a second current value, said first current value being detected by said current measuring means of said first sensing unit when said oxygen partial pressure detected by said oxygen partial pressure measuring means of said first sensing unit is higher than a first predetermined level above which the decomposition of NOx by said catalyst of said first sensing unit will not occur and below which said decomposition of NOx will occur, and said second current value being detected by said current measuring means of said second sensing unit when said oxygen partial pressure detected by said oxygen partial pressure measuring means of said second sensing unit is lower than a second predetermined level above which the decomposition of NOx by said catalyst of said second sensing unit will not occur and below which said decomposition of NOx will occur.

9. The NOx sensor of claim 8, wherein said control means controls said current applying means such that said oxygen partial pressure detected by said oxygen partial pressure measuring means of said first sensing unit is held at a level higher than said first predetermined level, while said oxygen partial pressure detected by said oxygen partial pressure measuring means of said second sensing unit is held at a level lower than said second predetermined level.

10. The NOx sensor of claim 8, wherein said catalyst is combined with said first electrode of said first sensing unit and said first electrode functions as said catalyst.

11. An NOx sensor for determining the concentration of NOx contained in a measurement gas, comprising:

a first and a second sensing unit, each of which comprises;

(a) an electrochemical cell having a solid electrolyte body, and at least two electrodes formed on said solid electrolyte body which include a first electrode exposed to said measurement gas and a second electrode;

(b) diffusion-resistance means for restricting communication of said first electrode with an external space in which said measurement gas exists, said diffusion-resistance means having a predetermined resistance to diffusion of said measurement gas therethrough from said external space toward said first electrode;

(c) a catalyst disposed adjacent said first electrode, for decomposing NOx contained in an atmosphere adjacent the catalyst;

(d) current applying means for applying an electric current between said first and second electrodes of said electrochemical cell;

(e) current measuring means for detecting an electric current flowing between said first and second electrodes; and

(f) oxygen partial pressure measuring means for detecting an oxygen partial pressure of the atmosphere adjacent the catalyst; and

control means for calculating the concentration of NOx contained in said measurement gas, based on one of a first and a second combination of current values, said first combination consists of a first current value, a second current value and a third current value, while said second combination consists of said first and second current values, and a fourth current value,

said first current value being detected by said current measuring means of said first sensing unit when said oxygen partial pressure detected by said oxygen partial pressure measuring means of said first sensing unit is higher than a first predetermined level above which the decomposition of NOx by said catalyst of said first sensing unit will not occur and below which said decomposition of NOx will occur,

said second current value being detected by said current measuring means of said first sensing unit when said oxygen partial pressure detected by said oxygen partial pressure measuring means of said first sensing unit is lower than said first predetermined level,

said third current value being detected by said current measuring means of said second sensing unit when said oxygen partial pressure measuring means of said second sensing unit is higher than a second predetermined level above which the decomposition of NOx by said catalyst of said sensing unit will not occur and below which said decomposition of NOx will occur, and

said fourth current value being detected by said current measuring means of said second sensing unit when said oxygen partial pressure detected by said oxygen partial pressure measuring means of said second sensing unit is lower than said second predetermined level.

12. The NOx sensor of claim 11, wherein said control means controls said current applying means of said second sensing unit such that said oxygen partial pressure detected by said oxygen partial pressure measuring means of said second sensing unit is held at a level higher than said second predetermined level, said control means calculating the concentration of NOx based on said first combination of the first, second and third current values.

13. The NOx sensor of claim 11, wherein said control means controls said current applying means of said second sensing unit such that the oxygen partial pressure detected by said oxygen partial pressure measuring means of said second sensing unit is held at a level lower than said second predetermined level, said control means calculating the concentration of NOx based on said second combination of the first, second and fourth current values.

14. The NOx sensor of claim 11, wherein said catalyst is combined with said first electrode of said first sensing unit and said first electrode functions as said catalyst.