Process for the production of building units from afterharding materials

• US 4,927,573 A
• Filed: 09/14/1989
• Issued: 05/22/1990
• Est. Priority Date: 05/05/1987
• Status: Expired due to Fees

• Current Assignee: Fakombinat
• Original Assignee: Fakombinat
• Inventors: Gyorvari, Janos, Schmidt, Erno, Alpar, Tibor
• Primary Examiner(s): Silbaugh, Jan H.
• Assistant Examiner(s): Kutach, Karen D.
• Application Number:
  US07/407,430
• Time in Patent Office: 250 Days
• Field of Search: 264/40.1, 264/40.3, 264/82, 264/83, 264/101, 264/211.11, 264/148, 264/157, 264/DIG. 43, 249/20, 249/22, 249/108, 249/109, 425/63, 425/64, 425/74, 425/178, 425/578, 425/580, 425/583, 425/585, 425/97, 425/380
• US Class Current: 264/40.1
• CPC Class Codes: B28B 11/245 Curing concrete articles B28B11/242 takes precedence
• CPC Class Codes: B28B 3/24 by reciprocating plunger
• CPC Class Codes: B28B 5/026 the shaped articles being of indefinite length
• CPC Class Codes: B28B 7/44 for treating with gases or degassing, e.g. for de-aerating treating with hot gases or vapour B28B7/42
• CPC Class Codes: C04B 28/02 containing hydraulic cements other than calcium sulfates
• CPC Class Codes: C04B 40/0231 Carbon dioxide hardening
• CPC Class Codes: C04B 40/0259 Hardening promoted by a rise in pressure C04B40/024 takes precedence
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/14 Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
• CPC Class Codes: C08L 2666/20 Macromolecular compounds having nitrogen in the main chain according to C08L75/00 - C08L79/00; Derivatives thereof
• CPC Class Codes: C08L 63/00 Compositions of epoxy resins; Compositions of derivatives of epoxy resins
• CPC Class Codes: C09K 2200/0647 Polyepoxides
• CPC Class Codes: C09K 2200/0672 Phenol-aldehyde condensation polymers
• CPC Class Codes: C09K 3/10 Materials in mouldable or extrudable form for sealing or packing joints or covers filling pastes C09D5/34
• CPC Class Codes: Y02P 40/18 Carbon capture and storage [CCS]
• CPC Class Codes: Y10S 264/43 Processes of curing clay and concrete materials

Abstract

A process for the production of building units from an afterhardening mixture containing cement and/or lime as binding material includes the following steps. The raw mixture is continuously fed and pressed by stamping into a die with CO₂ gas at a pressure higher than atmospheric being passed through the raw mixture in the die space. Through an instantaneous reaction of carbonation, the material is hardened to a formed body. The CO₂ gas is prevented from escaping by a gastight seal in the vicinity of the inlet port of the die. Further towards the outlet port, the pressure of the CO₂ gas is decreased. In the vicinity of the outlet port only as much CO₂ gas is fed as is necessary for the completing of the chemical reaction. Thus, any loss of gas will be minimized. The continuously discharged body is cut to size by using a saw.

Claims

1. Process for the production of building units from an afterhardening mixture containing cement, additives and water as binding material, the process including the steps of admitting the afterhardening mixture into a die which has an inlet port for insertion of the afterhardening mixture and an outlet port for removal of the afterhardening mixture in compacted form, injecting CO₂ gas into the afterhardening mixture and bringing about a carbonation reaction with the afterhardening mixture, pressing the afterhardening mixture continuously in the die while injecting the CO₂ gas into the afterhardening mixture under pressure, controlling the injecting of the CO₂ gas so as to provide a greater amount of the gas flowing through the afterhardening mixture near the inlet port of the die as compared to the amount of the gas flowing through the afterhardening mixture near the outlet port, mechanically compacting the afterhardening mixture at the inlet port and faces of the die, and thereby forming a generally gastight seal between the afterhardening material and the die, controlling the injecting of the CO₂ gas into the die so that full completion or essentially full completion of the carbonation reaction occurs, and removing the afterhardening mixture in compacted form from the die and separating the afterhardening mixture in compacted form into the building units.

2. Process according to claim 1, including pressing the afterhardening material into the die with a reciprocating device.

3. Process according to claim 1 including injecting the CO₂ gas into the die at least through one confining face under pressure exceeding atmospheric pressure, passing the CO₂ gas through the afterhardening mixture from one face of the die to another, and applying vacuum to at least one face of the die to assist the flow of the CO₂ gas through the afterhardening mixture.

4. Process according to claim 1 including injecting the CO₂ gas at a pressure of about 3-6 bar into pores of the afterhardening mixture in a first zone in the vicinity of the inlet port, injecting the CO₂ gas in the die at a pressure of about 2-3 bar in a second zone in an amount which is essentially equivalent to the gas consumed by carbonation of the afterhardening mixture, thereby providing for continuation of the carbonation reaction, injecting the CO₂ gas into said die in a third zone at a pressure of about 1-2 bar whereby essentially full completion of the carbonation reaction is realized.

5. Process according to claim 4 including creating a balancing zone in the die situated directly upstream of the outlet port, checking flow of the gas in the balancing zone, and injecting the gas into the first, second or third zones as a function of the amount of gas flowing out of the balancing zone.

6. Process according to claim 1, wherein the separating step includes the cutting into building units of carbonation-hardened mixture leaving the die.

7. Process according to claim 1, including injecting the CO₂ gas into the die with a gas mixture, containing at least about 30% CO₂.

8. Process according to claim 1, including injecting the CO₂ gas into the afterhardening mixture prior to feeding the afterhardening mixture into the die.