Diffusion-limiting membrane holding means for sensor

• US 4,929,330 A
• Filed: 10/16/1989
• Issued: 05/29/1990
• Est. Priority Date: 03/31/1987
• Status: Expired due to Term

• Current Assignee: Horiba Limited
• Original Assignee: Daikin Industries Ltd
• Inventors: Okamoto, Mitsunari, Terawaki, Hiroshi, Osaka, Tatsuhiko
• Primary Examiner(s): Kaplan, G. L.
• Application Number:
  US07/423,533
• Time in Patent Office: 225 Days
• Field of Search: 204/403, 204/1 E, 204/402, 204/415, 204/407, 435/817, 435/291
• US Class Current: 204/403.05
• CPC Class Codes: C12Q 1/001 Enzyme electrodes
• CPC Class Codes: Y10S 435/817 Enzyme or microbe electrode

Abstract

A diffusion-limiting membrane holding means for a sensor comprising: a slender resilient thin plate, of which one shorter side serves as an engagement side, and of which one longer side is provided at its predetermined position with an engagement portion, an opening being formed in the thin plate between the engagement side and the engagement portion; and a diffusion-limiting membrane integrally attached to the thin plate as covering the opening; whereby the resliency of the thin plate causes the diffusion-limiting membrane to be stuck to the surface of an enzyme electrode unit of a sensor, thus enhancing the accuracy of concentration measurement of a target substance to be measured.

Claims

1. A diffusion-limiting membrane holding means for a sensor, comprising:

a thin resilient plate provided in a predetermined position with an opening through which a target solution to be measured is adapted to penetrate, said thin resilient plate adapted to be bent into operative position; and

a diffusion-limiting membrane for limiting diffusion of the target solution attached to said thin resilient plate so as to cover said opening, and said diffusion-limiting membrane being dimensioned and attached to said resilient plate such that, upon a bending of said resilient plate into operative position, said plate causes a similar bending in said attached membrane.

2. A diffusion-limiting membrane holding means for a sensor as set forth in claim 1, wherein said surface of the thin resilient plate is hydrophobic and a wall defining said opening is hydrophilic.

3. A diffusion-limiting membrane holding means for a sensor as set forth in claim 1, wherein said thin resilient plate is provided at its predetermined area including the opening with an arcuate concaved portion.

4. A diffusion-limiting membrane holding means for a sensor as set forth in claim 1, wherein the opening is provided at the periphery thereof with a plurality of acute convexo-concave portions.

5. A diffusion-limiting membrane holding means for a sensor as set forth in claim 1, wherein said thin resilient plate is provided with a plurality of grooves at the periphery of the opening, said grooves extending outward around said opening.

6. A diffusion-limiting membrane holding means for a sensor as set forth in claim 5, wherein each of the grooves is spiral.

7. A diffusion-limiting membrane holding means for a sensor as set forth in claim 1, wherein said thin resilient plate is provided at a predetermined position thereof with a projection for holding said thin resilient plate in a raised portion.

8. A diffusion-limiting membrane holding means for a sensor as set forth in claim 7, wherein said thin resilient plate is provided with the projection at only a position thereof remote from the opening.

9. A diffusion-limiting membrane holding means for a sensor as set forth in claim 7, wherein the surface of said thin resilient plate is hydrophobic and the wall of the opening is hydrophilic.

10. A diffusion-limiting membrane holding means for a sensor as set forth in claim 1, wherein said thin resilient plate is provided at a predetermined position thereof with a housing portion for housing a standard solution for calibration, said housing portion being adapted to supply the standard solution for calibration to the opening.

11. A diffusion-limiting membrane holding means for a sensor as set forth in claim 10, wherein said thin resilient plate has a guide portion adapted to guide the standard solution for calibration to the opening only when the housing portion is crushed.

12. A diffusion-limiting membrane holding means for a sensor as set forth in claim 11, wherein a long-size plate and a sheet are laminated to each other, and a housing portion for housing standard solution for calibration and a guide portion are formed between said long-size plate and said sheet.

13. A diffusion-limiting membrane holding means for a sensor as set forth in claim 10, wherein said thin resilient plate has a surrounding portion which covers the top side of said opening and which connects with the guide portion.

14. A diffusion-limiting membrane holding means for a sensor comprising:

a thin resilient plate lengthened in one direction and provided in a predetermined position with an opening through which a target solution to be measured is adapted to penetrate; and

a diffusion-limiting membrane for limiting diffusion of the target solution attached to said thin resilient plate so as to cover said opening;

one longitudinal end side of said thin resilient plate serving as an engagement side adapted to be engaged with one of a pair of positioning portions disposed on a sensor, the positioning portions being opposite to each other with respect to an enzyme electrode unit of the sensor;

the other longitudinal end side of said thin resilient plate serving as a holding portion;

one longer side of said thin resilient plate having engagement means for engagement with the other of the positioning portions and the distance between said engagement side and engagement means being greater than the distance between the pair of positioning portions so as to cause said thin resilient plate to bow outwardly so as to essentially conform to a curved surface of the electrode.

15. A diffusion-limiting membrane holding means for a sensor as set forth in claim 14, wherein said one longitudinal end side of the thin resilient plate is arcuate around the center of the opening.

16. A diffusion-limiting membrane holding means for a sensor as set forth in claim 14, wherein said one longitudinal end side of the thin resilient plate is provided at a predetermined position thereof with a positioning notched concave.

17. A diffusion-limiting membrane holding means for a sensor as set forth in claim 14, wherein said one longitudinal end side of the thin resilient plate is provided at a predetermined position thereof with a positioning projection.

18. A diffusion-limiting membrane holding means for a sensor as set forth in claim 14, wherein the thin resilient plate is provided with a positioning hole at a predetermined position thereof in the vicinity of said one longitudinal end side.

19. A diffusion-limiting membrane holding means for a sensor as set forth in claim 14, wherein said engagement means is a notched groove.

20. A diffusion-limiting membrane holding means for a sensor as set forth in claim 14, wherein said engagement means is a stepped portion.

21. A diffusion-limiting membrane holding means for a sensor comprising:

a thin resilient plate lengthened in one direction provided in a predetermined position thereof with an opening through which a target solution to be measured is adapted to penetrate; and

a diffusion-limiting membrane for limiting diffusion of said target solution attached to said thin resilient plate as covering said opening;

one longitudinal end side of said thin resilient plate serving as an engagement side adapted to be engaged with one of a pair of positioning portions disposed on a sensor, said positioning portions being opposite to each other with respect to an enzyme electrode unit of said sensor;

the other longitudinal end side of said thin resilient plate serving as a holding portion;

one longer side of said thin resilient plate serving as an engagement portion adapted to be engaged with the other of said positioning portions, wherein said one longitudinal end side of the thin resilient plate is arcuate around the center of the opening.

22. A diffusion-limiting membrane holding means for a sensor, comprising:

a thin resilient plate having formed therein an opening through which a target solution to be measured is adapted to penetrate, said thin resilient plate having an elongated length and said thin resilient plate having a cross-sectional thickness which is essentially equal over the entire elongated length of said thin resilient plate; and

a diffusion-limiting membrane for limiting diffusion of the target solution attached to said thin resilient plate so as to cover said opening.