Method and apparatus for dispersing a gas into a liquid

• US 4,931,225 A
• Filed: 03/01/1989
• Issued: 06/05/1990
• Est. Priority Date: 12/30/1987
• Status: Expired due to Term

• Current Assignee: Praxair Technology Incorporated (Linde Plc)
• Original Assignee: Union Carbide Industrial Gases Technology Corporation (Linde Plc)
• Inventors: Cheng, Alan T.
• Primary Examiner(s): Miles, Tim
• Application Number:
  US07/317,577
• Time in Patent Office: 461 Days
• Field of Search: 417/151, 261/DIG. 78, 261/DIG. 76, 261/DIG. 75
• US Class Current: 261/76
• CPC Class Codes: B01D 19/0005 with one or more auxiliary substances
• CPC Class Codes: B01F 23/23 by introducing gases into liquid media, e.g. for producing aerated liquids
• CPC Class Codes: B01F 25/313 wherein additional components are introduced in the centre of the conduit
• CPC Class Codes: B01J 10/002 carried out in foam, aerosol or bubbles
• CPC Class Codes: B01J 19/26 Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
• CPC Class Codes: B01J 2219/00162 controlling the pressure
• CPC Class Codes: B01J 2219/00164 controlling the flow
• CPC Class Codes: C02F 1/20 by degassing, i.e. liberation of dissolved gases degasification of liquids in general B01D19/00; arrangement of degassing apparatus in boiler feed supply F22D
• CPC Class Codes: Y10S 261/75 Flowing liquid aspirates gas
• CPC Class Codes: Y10S 261/78 Sonic flow

Abstract

The present invention relates to an improved method and apparatus for dispersing a gas into a liquid. Gas is injected into a liquid and the flowing gas-liquid mixture is accelerated by a flow area contraction to at least sonic flow velocity, and subsequently decelerated by a flow area expansion to subsonic velocity. The attendant shock waves disperse the gas in the liquid. Preferred embodiments include off-centering the gas injection direction from the centerline of the contracting flow area and controlling the pressure at the exit of the expanding flow area.

Claims

1. An apparatus connected to a source of gas and liquid for dispersing said gas in said liquid, said apparatus comprising:

(a) at least one means for injecting said gas into said liquid, wherein said means injects said gas at a linear velocity which is at least sonic for at least a portion of said gas flow at the time said gas contacts said liquid, said injection means being located in communication with the entrance to a flow accelerating configuration; and

(b) at least one flow accelerating configuration for accelerating at least a portion a mixture of said gas and liquid flowing therethrough to sonic velocity, said flow accelerating configuration positioned so that gas injected by said gas injection means enters said flow accelerating configuration.

3. The apparatus of claim 1 or claim 2 wherein said injection means and said flow accelerating configuration are positioned inside a pipeline.

4. The apparatus of claim 1 or claim 2 wherein said injection means is positioned vertically beneath the entrance to said flow accelerating configuration, whereby the buoyancy force of said injected gas moves said gas into said flow accelerating configuration.

6. The apparatus of claim 1 or claim 2 wherein said flow accelerating configuration comprises a venturi.

7. The apparatus of claim 1 wherein said injection means is located off-center from the center line of said flow accelerating configuration.

8. The apparatus of claim 6 wherein the throat length of said venturi is the minimal length which can be reasonably fabricated.

9. The apparatus of claim 6 wherein said gas injection means is positioned inside the compression or entrance cone of said venturi.

10. The apparatus of claim 7 wherein said gas injection means is positioned inside the compression or entrance cone of said venturi.

11. The apparatus of claim 1 or claim 2 wherein said injection means is at least 0.1 pipeline diameters upstream of said flow accelerating configuration minimum diameter opening.

12. The apparatus of claim 11 wherein said flow accelerating configuration is a venturi.

13. The apparatus of claim 12 wherein said venturi configuration throat length is the minimal length which can be reasonably fabricated.

14. The apparatus of claim 13 wherein said injector is positioned within the compression cone of said venturi compression cone.

15. The apparatus of claim 14 wherein said injector is positioned off the centerline from said venturi throat opening.

16. The apparatus of claim 1 or claim 2 wherein said flow accelerating configuration minimum opening is as large as possible and still provides sufficient supersonic velocity in said at least a portion of said gas-liquid mixture to accomplish the desired gas dispersion.

17. The apparatus of claim 6 including a means for controlling the back pressure at the exit from the expansion cone of said venturi.

2. An apparatus for dispersing a gas in a liquid, said apparatus comprising:

(a) at least one means for injecting a gas into a liquid, wherein said means is located in communication with the entrance to a flow accelerating configuration and off-center from the center line of said flow accelerating configuration; and

(b) at least one flow accelerating configuration for accelerating a mixture of said gas and liquid to a linear velocity which is at least sonic for at least a portion of the flow of said mixture, said flow accelerating configuration positioned so that gas injected by said gas injection means enters said flow accelerating configuration.

5. The apparatus of claim 2 wherein said means for injecting a gas is capable of injecting said gas at a linear velocity which is at least sonic for at least a portion of said gas flow at the time said gas contacts said liquid.

18. A method of dissolving a gas in a liquid, said method comprising:

(a) contacting said liquid with said gas to be dissolved therein by injecting said gas into said liquid through a nozzle at a linear velocity which is at least sonic for at least a portion of said gas at the time it contacts said liquid;

(b) causing cocurrent flow of a composition comprising said injected gas in said liquid; and

(c) causing at least a portion of said cocurrently flowing composition to flow at a linear velocity which is at least sonic.

19. The method of claim 18 wherein said method is carried out inside a pipeline.

20. The method of claim 18 wherein causing at least a portion of said cocurrently flowing composition to flow at a lineat velocity which is at least sonic includes conducting said cocurrently flowing composition through at least one flow accelerating configuration.

21. The method of claim 20 and including directing said cocurrently flowing composition into and off centerline of said at least one flow accelerating configuration.

22. The method of claim 20 further including the step of controlling the back pressure of said at least one flow accelerating configuration.

23. A method of dispersing a gaseous or vaporous reactant into a reactant liquid or into a liquid containing a reactant, said method comprising:

(a) contacting said gaseous reactant with said liquid by injecting said gas into said liquid through a nozzle at a linear velocity which is at least sonic for at least a portion of said gas at the time it contacts said liquid;

(b) causing cocurrent flow of a composition comprising said injected gaseous reactant in said liquid; and

(c) causing at least a portion of said cocurrently flowing composition to flow at a linear velocity which is at least sonic.

24. The method of claim 23 wherein said method is carried out inside a pipeline.

25. The method of claim 23 wherein causing at least a portion of said cocurrently flowing composition to flow at a linear velocity which is at least sonic includes conducting said cocurrently flowing composition through at least one flow accelerating configuration.

26. The method of claim 25 and including directing said cocurrently flowing composition into and off centerline of said at least one flow accelerating configuration.

27. The method of claim 25 further including the step of controlling the back pressure of said at least one flow accelerating configuration.

28. A method for dispersing a gas in a liquid, said method comprising:

(a) injecting said gate into said liquid;

(b) causing cocurrent flow of a composition comprising said injected gas and at least a portion of said liquid;

(c) directing said flow into and off centerline of at least one flow accelerating configuration; and

(d) causing at least a portion of said composition to flow at a velocity which is at least sonic.

29. The method of claim 28 wherein said gas is injected at a linear velocity which is at least sonic for at least a portion of said gas at the time it contacts said liquid.

30. The method of claim 28 further including the step of controlling the back pressure of said at least one flow accelerating configuration.