Recording medium

• US 4,933,243 A
• Filed: 08/15/1988
• Issued: 06/12/1990
• Est. Priority Date: 09/20/1985
• Status: Expired due to Fees

• Current Assignee: Nippon Oil Corporation (ENEOS Holdings, Inc.)
• Original Assignee: Nippon Oil Corporation (ENEOS Holdings, Inc.)
• Inventors: Iida, Shigeki, Satoh, Tetsuo, Toya, Tomohiro, Orii, Shingo, Hara, Hajime
• Primary Examiner(s): Martin, Roland E.
• Assistant Examiner(s): Hamilton, Cynthia
• Application Number:
  US07/233,852
• Time in Patent Office: 666 Days
• Field of Search: 430/19, 430/20, 428/1, 350/350 R, 350/346
• US Class Current: 430/20
• CPC Class Codes: C09K 19/3809 Polyesters; Polyester derivatives, e.g. polyamides
• CPC Class Codes: C09K 2219/00 Aspects relating to the form of the liquid crystal [LC] material, or by the technical area in which LC material are used
• CPC Class Codes: G03F 1/68 Preparation processes not covered by groups G03F1/20 - G03F1/50
• CPC Class Codes: G11B 7/25 containing liquid crystals
• CPC Class Codes: Y10S 430/146 Laser beam

Abstract

A rewritable or repeatedly employable recording medium having a base and a recording layer film provided on said base, characterized in that said recording layer film is formed by a thermotropic cholesteric liquid crystal polyester.

Claims

1. A rewritable or repeatably employable recording medium comprising a base and a recording layer film deposited on said base;

said recording layer film being a film of a thermotropic cholesteric liquid crystal polyester;

said recording layer film being reversibly transparent or opaque, said film being transparent at room temperature by heat-melting said film at the liquid crystal forming temperature followed by rapid cooling from said liquid crystal forming temperature to room temperature and being opaque at room temperature by heat-melting said film at the liquid crystal forming temperature followed by either (a) slow cooling to room temperature or (b) the application of an electrical or a magnetic field followed by rapid cooling to room temperature;

said cholesteric liquid crystal polyester of said recording layer film formed by copolymerizing an optically active compound with a mesogen, said mesogen have a structural unit selected from the group consisting of ##STR10## the combination of ##STR11## and the combination of ##STR12## where X and Y are each independently hydrogen, halogen or an alkyl group having no more than four carbon atoms.

2. The recording medium of claim 1, wherein said thermotropic cholesteric liquid crystal polyester has a liquid crystal forming temperature in the range of 150°

to 350°

C.

3. The recording medium of claim 1 wherein said recording layer film has a thickness in the range of 1 to 100 μ

m.

4. The recording medium of claim 1, wherein (R)- or (S)-3- methyladipic acid is copolymerized with the mesogen.

5. The recording medium of claim 1, wherein (R)- or (S)-2-methyl-1,4-butanediol is copolymerized with the mesogen.

6. The recording medium of claim 4, wherein said optically active component is present in a proportion of 1 to 10 mol% of all monomer units.