Molecular sieving carbon

• US 4,933,314 A
• Filed: 03/08/1988
• Issued: 06/12/1990
• Est. Priority Date: 03/10/1987
• Status: Expired due to Term

• Current Assignee: Air Water Incorporated
• Original Assignee: Kanebo, Ltd. (HOYU Company Limited)
• Inventors: Marumo, Chisato, Shiomi, Niro, Hayata, Eiji
• Primary Examiner(s): Konopka, Paul E.
• Application Number:
  US07/165,525
• Time in Patent Office: 826 Days
• Field of Search: 502/180, 502/416, 502/417, 502/418, 502/420, 502/430, 502/432, 502/437, 423/445, 423/449
• US Class Current: 502/416
• CPC Class Codes: B01J 20/20 comprising free carbon; comprising carbon obtained by carbonising processes
• CPC Class Codes: C01B 13/0266 Carbon based materials
• CPC Class Codes: C01B 21/0461 Carbon based materials
• CPC Class Codes: C01B 2210/0046 Nitrogen
• CPC Class Codes: C07C 7/13 by molecular-sieve technique
• CPC Class Codes: C07C 9/04 Methane production by treatment of sewage C02F11/04; natural gas, synthetic natural gas C10L3/06
• CPC Class Codes: Y10S 95/903 Carbon

Abstract

A molecular sieving carbon characterized by (A) having a structure in which a number of spherical carbonaceous particles having a particle diameter of 0.8 to 120 micrometers overlap and coalesce three-dimensionally at random, (B) in which continuous pathways running three-dimensionally at random exist between a number of the carbonaceous particles, (C) in which a number of the carbonaceous particles have each a number of micropores communicating with the pathways existing between the particles, and (D) having a carbon content of at least 85% by weight. The molecular sieving carbon is useful for obtaining, for example, a nitrogen gas, oxygen gas or gaseous mixture enriched with either the nitrogen gas or the oxygen gas from a gaseous mixture containing the nitrogen gas and oxygen gas.

Claims

1. A molecular sieving carbon comprising a shaped object

(A) which is an assembly of a number of contiguous, carbonaceous spheres having a diameter of 0.8 to 120 micrometers which spheres are bonded together three-dimensionally at random,

(B) in which continuous interstitual pathways running three-dimensionally at random exist between a number of the carbonaceous spheres, said continuous pathways having an average diameter of 0.1 to 20 micrometers,

(C) in which a number of the carbonaceous spheres each have a number of micropores communicating with the pathways existing between the spheres, said micropores having an average diameter of about 10Å

or less and a volume of 0.1 to 0.7 cc/g,

(D) having a carbon content of at least 85% by weight, and

(E) having a bulk density of 0.7 to 1.2 gg/cc.

2. The molecular sieving carbon of claim 1 in which a number of the carbonaceous spheres have a diameter of 2 to 80 micrometers.

3. The molecular sieving carbon of claim 1 having a porosity of 25 to 50% by volume.

4. The molecular sieving carbon of claim 1 having a carbon content of at least 90% by weight.

5. The molecular sieving carbon of claim 1 in which a number of the carbonaceous spheres are derived from spheres of a phenol resin having a diameter of 1 to 150 micrometers.

6. The molecular sieving carbon of claim 1 in which the shaped object is a column having a width of 0.5 to 5 mm and a height of 1 to 10 mm long or a sphere having a diameter of 0.5 to 10 mm.

7. The molecular sieving of carbon of claim 1 in which said micropores have a volume of from 0.15 to 0.5 cc/g.

8. The molecular sieving carbon of claim 1 in which said micropores have a volume of from 0.2 to 0.4 cc/g.

9. The molecular sieving carbon of claim 1 having a porosity of from 30 to 45%.

10. The molecular sieving carbon of claim 9 in which said micropores have a volume of from 0.15 to 0.5 cc/g.

11. Porous carbon granules each consisting of a multitude of contiguous, carbonaceous spheres bonded in molded relationship, said spheres having a diameter of from 0.8 to 120 micrometers, said spheres having internal micropores having an average size of not more than 10 Angstrom units and most of said micropores having an average size of from 3 to 5 Angstrom units, the volume of said micropores being from 0.1 to 0.7 cc/g, said spheres having a volume of larger pores having an average size of from 15 to 200 Angstrom units of up to 0.2 cc/g, each of said granules having continuous, randomly disposed pathways between said spheres, said pathways having an average diameter of from 0.1 to 20 micrometers, said micropores communicating with said pathways,

said granules being either columnar granules having a diameter of from 0.5 to 5 mm and a length of from 1 to 10 mm, or substantially spherical granules having a diameter of from 0.5 to 10 mm, said granules consisting of at least 85% by weight of carbon, and having a porosity of 25 to 50% by volume, a bulk density of 0.7 to 1.2 g/cc and a specific surface area, measured by the B.E.T. method of N₂ adsorption, of from 5 to 600 m² /g.

12. Porous carbon granules each consisting of a multitude of contiguous, carbonaceous spheres bonded in molded relationship, said spheres having a diameter of from 2 to 80 micrometers, said spheres having internal micropores having an average size of not more than 10 Angstrom units and most of said micropores having an average size of from 3 to 5 Angstrom units, the volume of said micropores being from 0.2 to 0.4 cc/g, said spheres having a volume of larger pores having an average size of from 15 to 200 Angstrom units of up to 0.1 cc/g, each of said granules having continuous, randomly disposed pathways between said spheres, said pathways having an average diameter of from 0.1 to 20 micrometers, said micropores communicating with said pathways,

said granules being either columnar granules having a diameter of from 0.5 to 5 mm and a length of from 1 to 10 mm, or substantially spherical granules having a diameter of from 0.5 to 10 mm, said granules consisting of at least 85% by weight of carbon, and having a porosity of 30 to 45% by volume, a bulk density of 0.8 to 1.1 g/cc and a specific surface area, measured by the B.E.T. method of N₂ adsorption, of from 20 to 350 m² /g.