Fragrance-containing polymeric particles suspended in antiperspirant and/or deodorant vehicle

• US 4,934,609 A
• Filed: 10/19/1984
• Issued: 06/19/1990
• Est. Priority Date: 10/19/1984
• Status: Expired due to Fees

• Current Assignee: International Flavors & Fragrances Incorporated
• Original Assignee: International Flavors & Fragrances Incorporated
• Inventors: Reich, Sharon L., Trizzino, Rose L., Suran, Valerie M., Cincotta, David E., Lindauer, Jerome I.
• Primary Examiner(s): Gorski, Joseph M.
• Application Number:
  US06/662,681
• Time in Patent Office: 2,069 Days
• Field of Search: 241/3, 241/23, 241/DIG. 37, 252/522 A, 264/178 R
• US Class Current: 241/3
• CPC Class Codes: A61K 2800/56 Compounds, absorbed onto or entrapped into a solid carrier, e.g. encapsulated perfumes, inclusion compounds, sustained release forms
• CPC Class Codes: A61K 8/0229 Sticks
• CPC Class Codes: A61K 8/0241 Containing particulates characterized by their shape and/or structure see also A61K8/04, A61K8/11, and A61K8/14, further aspects are classified in A61K2800/40 and subcodes
• CPC Class Codes: A61Q 15/00 Anti-perspirants or body deodorants deodorisation of air A61L9/00
• CPC Class Codes: B29B 13/10 by grinding, e.g. by triturating; by sieving; by filtering
• CPC Class Codes: B29B 9/06 in the form of filamentary material, e.g. combined with extrusion
• CPC Class Codes: B29K 2023/00 Use of polyalkenes or derivatives thereof as moulding material
• CPC Class Codes: B29K 2105/04 cellular or porous
• CPC Class Codes: B29L 2031/718 Cosmetic equipment, e.g. hair dressing, shaving equipment brushes B29L2031/42, combs B29L2021/005
• CPC Class Codes: C08J 3/005 Processes for mixing polymers
• CPC Class Codes: Y10S 241/37 Cryogenic cooling

Abstract

Described are deodorant and/or antiperspirant vehicles which contain fragrance-containing polymer pellets containing 1 to 80% fragrance, the polymeric pellets produced by means of cryogenically grinding an extruded mixture of perfume composition and polymer.

Claims

1. A process for producing a solid anti-perspirant stick or a deodorant stick having a long-lasting fragrance, which solid stick consists essentially of a solid suspension, which solid suspension consists essentially of cryogenically ground fragrance-containing polymeric particles suspended in a suspension composition comprising a suspension agent admixed with a deodorant material or an anti-perspirant material, said polymeric particles comprising a thermoplastic polymer selected from the group consisting of:

(1) low density polyethylene;

(2) high density polyethylene;

(3) polypropylene;

(4) a co-polymer of ethylene and vinyl acetate;

(5) polyvinyl chloride;

(6) a copolymer of ethylene and ethyl acrylate;

(7) a copolymer of ethylene and methyl acrylate;

(8) a copolymer of ethylene and butyl acrylate;

(9) a copolymer of ethylene and acrylic acid; and

(10) the hydrolyzed co-polymer of ethylene and vinyl acetate

said polymeric particles containing from 1 up to about 80% by weight of a perfume, said process comprising the steps of;

(i) co-extruding the thermoplastic polymer with from about 1% up to about 80% of said perfume thereby forming an extrudate with the polymer feed rate range being from 80 up to 300 pounds per hour and the feed rate range of perfume being between 1.01% and 400% of the feed rate range of thermoplastic polymer;

(ii) quick-chilling said extrudate by contacting said extrudate with an inert cooling liquid at a temperature of from about 5°

C. up to about 60°

C. whereby extrudate pellets are formed;

(iii) cryogenically grinding the resulting extrudate pellets to a particle size of from about 10 up to about 500 microns thereby forming cyrogenically ground extrudate pellets;

(iv) intimately admixing the resulting cryogenically ground extrudate pellets with said deodorant-containing suspension composition or said anti-perspirant-containing suspension composition whereby a liquid suspension is formed; and

(v) forming the thus created liquid suspension into deodorant or anti-perspirant sticks

the weight percent of cryogenically ground polymer in the resulting suspension being from about 2% up to about 8%, the resulting polymeric particles in said suspension being capable of controlled release of said perfume therefrom into and through the resulting deodorant sticks or anti-perspirant sticks.

2. The process of claim 1 wherein the cryogenic grinding step (iii) takes place using as a cryogenic agent liquid nitrogen whereby the extrudate pellets are first intimately contacted with said liquid nitrogen and are then milled in a mill cooled with liquid nitrogen.

3. The process of claim 2 wherein the thermoplastic polymer is high density polyethylene.

4. The process of claim 1 which includes adding a gaseous or liquid blowing agent during the step (i) of co-extruding.

5. The process of claim 4 wherein the thermoplastic polymer is high density polyethylene.

6. The process of claim 1 wherein the thermoplastic polymer is high density polyethylene.