Method of treating a sample of an alloy

• US 4,935,068 A
• Filed: 01/23/1989
• Issued: 06/19/1990
• Est. Priority Date: 01/23/1989
• Status: Expired due to Term

• Current Assignee: Memry Corporation
• Original Assignee: Raychem Corporation (TE Connectivity Limited)
• Inventors: Duerig, Thomas W.
• Primary Examiner(s): R. Dean
• Application Number:
  US07/300,409
• Time in Patent Office: 512 Days
• Field of Search: 148/11.5 C, 148/11.5 N, 148/402, 420/902
• US Class Current: 148/563
• CPC Class Codes: C22F 1/006 Resulting in heat recoverable alloys with a memory effect
• CPC Class Codes: Y10S 420/902 Superplastic

Abstract

A method of treating a sample of an alloy which is capable of transforming between martensitic and austenitic phases, to render the alloy pseudoelastic, the method comprising:

(a) annealing the alloy at a temperature which is greater than the stress relaxation temperature (T_SR) of the alloy and less than the temperature at which the alloy is fully recrystallized (T_x); and

(b) deforming the sample at a temperature which is greater than about the maximum temperature at which the alloy can be made to transform from its austenitic phase to its martensitic phase by the application of stress (M_d), and less than the stress relaxation temperature.

Claims

1. A method of treating a sample of an alloy which is capable of transforming between martensitic and austenitic phases, to render the alloy pseudoelastic, the method comprising:

(a) annealing the alloy at a temperature which is greater than the stress relaxation temperature (T_SR) of the alloy and less than the temperature at which the alloy is fully recrystallized (T_x); and

(b) deforming the sample at a temperature which is greater than about the maximum temperature at which the alloy can be made to transform from its austenitic phase to its martensitic phase by the application of stress (M_d), and less than the stress relaxation temperature.

2. A method as claimed in claim 1, in which the sample is deformed by stretching it uniaxially.

3. A method as claimed in claim 1, in which the sample is deformed in a bending mode.

4. A method as claimed in claim 1, in which the sample is deformed in a torsion mode.

5. A method as claimed in claim 1, in which the amount by which the sample is deformed is less than about 15%.

6. A method as claimed in claim 1, in which the sample is deformed while submerged in a quantity of liquid which is heated to a temperature between M_d and T_SR.

7. A method as claimed in claim 1., in which the sample is deformed in a forming fixture which is heated to a temperature between M_d and T_SR.

8. A method as claimed in claim 1,, in which the sample is deformed at a temperature which is greater than about 0.5 (T_SR +M_d).

9. A method as claimed in claim 1, in which the sample is in the form of a wire.

10. A method as claimed in claim 9, in which at least a portion of the wire appear to have an undulated configuration when viewed in side elevation.

11. A method as claimed in claim 10, in which the undulations can be fitted substantially in a single plane, so that the wire is formed with a generally sinusoidal configuration.

12. A method as claimed in claim 10, in which at least a portion of the wire has a helical configuration.

13. A method as claimed in claim 1, in which the alloy is a nickel-titanium based alloy.

14. An article comprising a sample of an alloy, which has been treated by a method as claimed in claim 1.