Process for purifying crude gaseous hydrogen chloride

• US 4,935,220 A
• Filed: 05/11/1989
• Issued: 06/19/1990
• Est. Priority Date: 05/17/1988
• Status: Expired due to Term

• Current Assignee: Wacker-Chemie GmbH (Dr. Alexander Wacker Familiengesellschaft Mit Beschrã¤Nkter Haftung)
• Original Assignee: Wacker-Chemie GmbH (Dr. Alexander Wacker Familiengesellschaft Mit Beschrã¤Nkter Haftung)
• Inventors: Hilgert, Wilhelm, Schneider, Otto, Lindner, Tassilo
• Primary Examiner(s): Russel, Jeffrey E.
• Assistant Examiner(s): BOLAM, BRIAN
• Application Number:
  US07/351,506
• Time in Patent Office: 404 Days
• Field of Search: 423/488, 55/23, 55/89, 55/85, 55/71, 62/85, 62/115
• US Class Current: 423/488
• CPC Class Codes: C01B 7/0706 of hydrogen chloride
• CPC Class Codes: C01B 7/0712 by distillation

Abstract

The invention relates to a process for purifyng crude gaseous hydrogen chloride originating from plants producing silane or siloxane and containing as impurities silanes which contain chlorine and/or organic radicals, water, alkanols, hydrocarbons, chlorinated hydrocarbons, organic acids and derivatives thereof, by condensation, compression and fractional distillation. In this process, the crude gas is at least partially freed from condensable products by cooling to -35° C., then compressed in a screw compressor with oil injection to 1.5 MPa, the oil is separated off, freed from gel-containing residues through a filter web and again recycled into the compressor. The compressed hydrogen chloride gas is fractionated in a distillation column under pressure and hydrogen chloride having a purity of 99.999 percent is recovered.

Claims

1. A process for the purification of crude gaseous hydrogen chloride which contains as impurities silanes containing chlorine and/or organic radical, alkanols, water, chlorinated hydrocarbons, hydrocarbons, and organic acids, by condensation, compression and fractional distillation, which comprises (1) passing the crude gas through a heat exchanger, in which it is cooled to -15°

C. to -35°

C.;

(2) subsequently heating the crude gas which has been at least partially freed from condensable products to 0°

to -40°

C., compressing it in a screw compressor with oil injection to a pressure of 0.6 to 1.5 MPa, separating off the hydrogen chloride from the oil through a separator having a filter, cooling the oil which has been separated off in a heat exchanger, freeing it from residues through a filter web, and recycling it to the compressor; and

(3) subsequently fractionating the compressed hydrogen chloride which has been separated from the oil in a distillation column under pressure and discharging the purified hydrogen chloride at the top of the column. PG,12

2. The process of claim 1, wherein the crude gas in the first process stage is passed through a corrosion-resistant heat exchanger and cooled to -25°

C. to -35°

C.

3. The process of claim 1, wherein the crude gas which is at least partially freed from condensable products in the second process stage is heated to +10°

C. to -25°

C., compressed in a single-stage screw compressor with oil injection to a pressure of 0.8 to 1.2 MPa, the hydrogen chloride in separated from the oil through a separator having a ceramic filter and the oil which has been separated off is filtered through a filter web of polymeric organic material.

4. The process of claim 3, wherein additive-free polyolefin-based synthetic hydrocarbons are used for the oil lubrication of the screw compressor used in the second process stage.

5. The process of claim 1, wherein the compressed hydrogen chloride in the third process stage is fractionated under pressure in a distillation column equipped with a condenser and the purified hydrogen chloride is discharged at the top of the column as a liquid.