Method of capturing sulfur in coal during combustion and gasification

• US 4,936,047 A
• Filed: 04/20/1988
• Issued: 06/26/1990
• Est. Priority Date: 11/12/1980
• Status: Expired due to Fees

• Current Assignee: Battelle Memorial Institute
• Original Assignee: Battelle Development Corporation
• Inventors: Feldmann, Herman F., Kim, Byung C.
• Primary Examiner(s): Kratz, Peter
• Application Number:
  US07/186,659
• Time in Patent Office: 797 Days
• Field of Search: 48/197 R, 48/203, 48/206, 48/210, 44/15 R, 24/77, 110/342, 110/345, 110/347, 122/4 D
• US Class Current: 48/197.00R
• CPC Class Codes: C10J 2300/0996 Calcium-containing inorganic materials, e.g. lime
• CPC Class Codes: C10J 3/54 Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
• CPC Class Codes: C10L 9/02 by chemical means
• CPC Class Codes: F23B 90/06 the primary combustion being a gasification or pyrolysis in a reductive atmosphere

Abstract

A method of reducing the amount of gaseous sulfur compounds released during combustion of sulfur-containing fuel, comprising the steps of: (a) preparing a mixture of sulfur containing particulate fuel and a sulfur absorbent, such as calcium oxide, calcium hydroxide, calcium carbonate, lime, limestone, dolomite, or mixtures thereof; (b) exposing the mixture to a reducing atmosphere at a temperature of at least about 1500° F., so as to convert at least a portion of the particulate fuel into a gaseous portion and a solid, char portion; and (c) combusting the char portion, thereby forming an ash containing sulfur fixed therein.

Claims

1. A method of combusting solid particulate carbonaceous fuel containing sulfur, comprising the steps of:

(a) treating said fuel by mixing it with an aqueous solution including a calcium-containing sulfur absorbent at at least ambient temperature to mix said sulfur absorbent with said fuel;

(b) providing a reactor and exposing said treated fuel to a reducing atmosphere in said reactor at a temperature of between about 1500°

F. and about 1800°

F. for converting at least about 20% of the solid carbonaceous material in said fuel to the gaseous state while forming a solid char material containing said sulfur and compounds of calcium; and

(c) providing a combustor and passing said char material from said reactor to said combustor and combusting said char material in said combustor at a temperature of at least about 2100°

F. in the presence of sufficient oxygen to promote the reaction of said sulfur and said compounds of calcium to form calcium sulfate, thereby forming gaseous combustion products substantially free of gaseous sulfur compounds and an ash containing sulfur fixed therein as calcium sulfate.

2. A method as claimed in claim 1, wherein the sulfur absorbent comprises calcium oxide, calcium hydroxide, calcium carbonate, lime, limestone, dolomite, or mixtures thereof.

3. A method as claimed in claim 1, wherein sufficient sulfur absorbent is utilized to provide a ratio of moles of absorbent to moles of sulfur in the particulate fuel of about three or more.

4. A method as claimed in claim 1, wherein said mixture is exposed to a reducing atmosphere in an enclosed reactor for a time of from about 25 to 60 minutes.

5. A method as claimed in claim 1, wherein the portion of particulate fuel converted to the gaseous state is in the range of from about 50% to 90%.

6. A method as claimed in claim 1, wherein the combustion temperature is maintained by providing excess air for combustion.

7. A method as claimed in claim 1, wherein the combustion temperature is maintained by supplying heat to heat exchanger tubes for steam generation.

8. A method as claimed in claim 1, wherein the reactor comprises a gasification reactor.

9. A method as claimed in claim 1, wherein said reactor and said combustor comprise an integrated, substantially enclosed system with said reactor situated above said combustor.

10. A method as claimed in claim 9, wherein said system, including said reactor and said combustor, comprises a fluidized bed system.