Transparent polymeric laminate

• US 4,937,147 A
• Filed: 04/10/1989
• Issued: 06/26/1990
• Est. Priority Date: 04/10/1989
• Status: Expired due to Fees

• Current Assignee: Monsanto Company (Bayer AG)
• Original Assignee: Monsanto Company (Bayer AG)
• Inventors: Cartier, George E., Piretti, Carl P.
• Primary Examiner(s): Buffalow, Edith
• Application Number:
  US07/335,248
• Time in Patent Office: 442 Days
• Field of Search: 428/423.1, 428/424.4, 428/425.3, 428/425.5, 428/437
• US Class Current: 428/425.3
• CPC Class Codes: B32B 17/10761 containing vinyl acetal
• CPC Class Codes: B32B 2038/0076 Curing, vulcanising, cross-linking
• CPC Class Codes: B32B 2307/412 Transparent
• CPC Class Codes: B32B 2375/00 Polyureas; Polyurethanes
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/18 characterised by the use of special additives
• CPC Class Codes: B32B 27/306 comprising vinyl acetate or vinyl alcohol (co)polymers
• CPC Class Codes: B32B 27/40 comprising polyurethanes
• CPC Class Codes: Y10T 428/31551 Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
• CPC Class Codes: Y10T 428/31576 Ester monomer type [polyvinylacetate, etc.]
• CPC Class Codes: Y10T 428/31594 Next to aldehyde or ketone condensation product [phenol-aldehyde, etc.]
• CPC Class Codes: Y10T 428/31598 Next to silicon-containing [silicone, cement, etc.] layer
• CPC Class Codes: Y10T 428/3163 Next to acetal of polymerized unsaturated alcohol [e.g., formal butyral, etc.]

Abstract

A transparent polymeric laminate of plasticized polyvinyl butyral sheet chemically linked by urethane groups to a thermoset polyurethane layer formed as the reaction product of a cross-linkable mixture containing diisocyanate and polyether polyol containing primary or secondary hydroxyl groups and having a molecular weight between about 250 to about 8000.

Claims

1. A transparent polymeric laminate comprising a sheet of plasticized partial polyvinyl butyral containing about 17 to 25 weight percent hydroxyl groups chemically linked by urethane groups to a thermoset polyurethane layer formed as the reaction product of a cross-linkable mixture containing photoinitiator, cycloaliphatic diisocyanate having NCO groups chemically attached to secondary cycloaliphatic carbons and a polyether polyol containing primary or secondary hydroxyl groups having a molecular weight between about 250 to about 8000.

2. The laminate of claim 1 where the polyether polyol is selected from adducts of glycerine and propylene oxide, adducts of glycerine and propylene oxide capped with ethylene oxide and mixtures thereof.

3. The laminate of claim 2 wherein the refractive index of the polyurethane layer is within ±

0.04 refractive index units of the refractive index of the plasticized polyvinyl butyral.

4. The laminate of claim 2 wherein the cross-link density of the polyurethane layer is such that the molecular weight of the polyurethane between cross-links is about 50 to 2000.

5. The laminate of claim 4 wherein the mixture includes one or more hydroxylated acrylate monomers capable of reacting with free isocyanate groups to form pendant terminal reactive double bonds serving as cross-link sites.

6. The laminate of any of claims 1, 2, 3, 4 or 5 wherein the polyurethane layer is dual cured by heat and radiation.

7. The laminate of claim 6 wherein curing occurs first by exposure to ultraviolet light and then by exposure to elevated temperature.

8. The laminate of claim 6 wherein the viscosity of the mixture is about 200 to 1000 centipoises.

9. The laminate of claim 6 wherein the diisocyanate is methylene bis(4-cyclohexylisocyanate).