Process for the production of amines

• US 4,937,384 A
• Filed: 03/16/1988
• Issued: 06/26/1990
• Est. Priority Date: 03/26/1987
• Status: Expired due to Fees

• Current Assignee: BP Chemicals Ltd. (BP PLC)
• Original Assignee: BP Chemicals Ltd. (BP PLC)
• Inventors: Dobson, Ian D.
• Primary Examiner(s): Raymond, Richard L.
• Assistant Examiner(s): O'Sullivan, P.
• Application Number:
  US07/168,852
• Time in Patent Office: 832 Days
• Field of Search: 564/375, 564/448, 564/488
• US Class Current: 564/488
• CPC Class Codes: B01J 23/8986 with manganese, technetium or rhenium
• CPC Class Codes: C07C 209/50 by reduction of carboxylic acid amides
• CPC Class Codes: C07C 211/03 Monoamines

Abstract

An amine is produced by reacting an amide with hydrogen at elevated temperature in the presence as catalyst of a composition comprising as a first component (i) a noble metal of Group VIII of the Periodic Table of the Elements, particularly palladium or ruthenium, and (ii) rhenium, which component may be supported, and as a second component either an alumina or a zeolite, preferably a low silica aluminosilicate zeolite, for example type A or type Y zeolite.

Claims

1. A process for the production of an amine which process comprises reacting an amide with hydrogen at elevated temperature in the presence as catalyst of a composition comprising as a first component (i) a noble metal of Group VIII of the Periodic Table of the Elements, and (ii) rhenium, said first component being supported on a high surface area graphitised carbon, and as a second component either an alumina or a zeolite.

2. A process according to claim 1 wherein the amide is of the formula:

##STR3## wherein R¹ is either hydrogen or a substituted or unsubstituted benzyl, aryl, aliphatic or cycloaliphatic group, and R² and R³ are independently either hydrogen or substituted or unsubstituted aliphatic groups.

3. A process according to claim 2 wherein in the formula (I) R¹ is either hydrogen or an alkyl group.

4. A process according to claim 2 wherein in the formula (I) R² and R³ are either hydrogen or an alkyl group.

5. A process according to claim 1 wherein the amide is either acetamide, propionamide or a fatty amide.

6. A process according to claim 1 wherein in the first component of the catalyst the noble metal of Group VIII is palladium or ruthenium.

7. A process according to claim 1 wherein the first component is modified by incorporation of a metal or metals of Group IA, Group IIA or Group IVA of the Periodic Table of the Elements.

8. A process according to claim 1 wherein the first component of the catalyst is prepared by a method comprising the steps of:

(A) impregnating a high surface area graphitised carbon support with a solution of a soluble Group VIII noble metal compound thermally decomposable/reducible to Group VIII noble metal and subsequently removing the solvent therefrom, and

(B) impregnating the Group VIII metal impregnated support with a solution in a solvent in which the Group VIII metal is substantially insoluble of a soluble rhenium compound thermally decomposable/reducible to rhenium metal and/or an oxide and thereafter removing the solvent therefrom.

9. A process according to claim 8 wherein the first component of the catalyst is activated by contact at elevated temperature with either hydrogen or a hydrogen/inert gas mixture for a period of from 1 to 20 hours.

10. A process according to claim 1 wherein the first component of the catalyst is prepared by a method comprising the steps of:

(A'"'"') impregnating a high surface area graphitised carbon support with a solution of a soluble Group VIII noble metal compound thermally decomposable/reducible to the Group VIII noble metal and subsequently removing the solvent therefrom,

(B'"'"') heating the Group VIII noble metal on the support, and

(C'"'"') impregnating the Group VIII noble metal impregnated support with a solution of a soluble rhenium compound thermally decomposable/reducible to rhenium metal and/or oxide and thereafter removing the solvent therefrom.

11. A process according to claim 10 wherein the first component of the catalyst is activated by contact at elevated temperature with either hydrogen or a hydrogen/inert gas mixture for a period of from 1 to 20 hours.

12. A process according to claim 1 wherein the second component of the catalyst is a zeolite which is a low silica aluminosilicate zeolite.

13. A process according to claim 12 wherein the zeolite is either zeolite type A or zeolite type Y.

14. A process according to claim 12 wherein the zeolite is a zeolite type A which is zeolite type 4A.

15. A process according to claim 1 wherein the elevated temperature is in the range from 150°

to 300°

C.