Cable sealing apparatus comprising heat resistant gel compositions

• US 4,942,270 A
• Filed: 07/12/1988
• Issued: 07/17/1990
• Est. Priority Date: 07/13/1987
• Status: Expired due to Term

• Current Assignee: Tyco Electronics Corporation (TE Connectivity Limited)
• Original Assignee: Raychem Corporation (TE Connectivity Limited)
• Inventors: Gamarra, Jose P.
• Primary Examiner(s): NIMMO, MORRIS
• Application Number:
  US07/217,798
• Time in Patent Office: 735 Days
• Field of Search: 174/91, 174/92, 174/93, 174/77 R, 174/41, 524/505, 524/173
• US Class Current: 174/93
• CPC Class Codes: C08K 5/01 Hydrocarbons C08K5/0091 takes precedence
• CPC Class Codes: C08L 53/00 Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers

Abstract

This invention provides cable sealing apparatus comprising styrene-ethylene-butylene-styrene triblock copolymer-oil compositions which are temperature resistant and nonmeltable. They have a viscosity at 200° C. of at least 200 poise. The compositions can be molded under pressure at elevated temperatures.

Claims

1. A cable sealing apparatus, comprising:

a first end seal, the first end seal comprising a layer of gel which comprises;

(1) about 2 to about 30 parts by weight of a poly(styrene-ethylene-butylene-styrene) triblock copolymer having a styrene to ethylene butylene block ratio of about 27 to 35 styrene blocks to about 65 to 73 ethylene butylene blocks, and having a molecular weight of at least 100,000; and

(2) about 70 to about 98 parts by weight of a plasticizer;

wherein the triblock copolymer and the plasticizer have been

(a) melt-blended and

(b) have been treated

(i) at sufficiently high temperature or

(ii) under sufficiently high shear

to cause the composition to have a cone penetration of at least about 50 (10^-1 mm), an ultimate elongation of at least about 200% and a viscosity at 200°

C. of at least 10 poise;

the layer of gel including

(A) means formed therein for passage of the cable to be sealed therethrough between inner and outer opposite faces of the gel, the cable to be sealed being held in contact with the gel formed means;

(B) a convoluted member forming an outer circumferential surface of the gel, the convoluted member having a series of ridges and valleys extending circumferentially therearound;

(C) a first member disposed adjacent to and in contact with an outer face of the gel and having means formed therein to facilitate passage of the cable to be sealed therethrough;

(D) a second member disposed adjacent to and in contact with an inner face of the gel and having means formed therein to facilitate passage of the cable to be sealed therethrough; and

(E) gel formed means comprising a plurality of longitudinal slits extending through the gel, a width of at least one of the slits being greater than a diameter of the cable to be sealed.

2. The apparatus according to claim 1, wherein the viscosity of said layer of precured gel at 200°

C. is at least 100 poise.

3. The apparatus according to claim 1, wherein the molecular weight of the triblock copolymer is about 150,000 to about 300,000.

4. The apparatus according to claim 1, wherein the plasticizer comprises a hydrocarbon oil having a molecular weight of about 400 to about 2500.

5. The apparatus according to claim 1, wherein the plasticizer comprises a hydrocarbon oil having a solubility parameter of about 6.0 to about 8.5.

6. The apparatus according to claim 1, wherein the gel is disposed in a flexible matrix comprising a material having a plurality of open interstices having an average volume of less than 0.01 inches, the gel including a plurality of interconnected segments which lie within the interstices of the matrix.

7. The apparatus according to claim 6, wherein the first end seal further comprises means for securing the convoluted member and precured gel around a cable.

8. The apparatus according to claim 6, wherein the first end seal is a slit elongated disc.

9. The apparatus according to claim 8, wherein the first end seal includes means for connecting portions of the disc in a hinged manner to allow opening and closing thereof, and further includes means for closing the disc portions.

10. The apparatus according to claim 9, further comprising a first bridging member having a convoluted inner surface at opposite ends thereof engageable with the first convoluted member and second convoluted member of the first end seal and second end seal, respectively.

11. The apparatus according to claim 10, wherein the bridging member has an entire outer and inner surface thereof convoluted and has an inside diameter at the opposite ends thereof which is substantially equal to an outside diameter of the first and second end seals, respectively.

12. The apparatus according to claim 10, wherein the first and second end seals and the bridging member form a closure for a junction in a cable, the first and second end seals being adapted to be disposed around the cable adjacent opposite sides of the junction to be formed with the bridging member being adapted to be disposed around the junction to be formed and around at least part of each of the first and second end seals.

13. The apparatus according to claim 12, further comprising a second bridging member disposed around the first bridging member, the second bridging member being convoluted at opposite ends thereof.

14. The apparatus according to claim 10, further comprising means for forming a cone-like shaped member adjacent at least one of the end seals.

15. A splice cable closure, comprising:

first and second ends seals, each of which seals comprises a convoluted disc

(A) having convolutions on an outer cylindrical surface thereof and

(B) having a layer of gel on an inside surface thereof shaped so as to form an axial bore therethrough, said layer of gel comprising;

(1) about 2 to about 30 parts by weight of a poly(styrene-ethylene-butylene-styrene) triblock copolymer having a styrene to ethylene butylene block ratio of about 27 to 35 styrene blocks to about 65 to 73 ethylene butylene blocks, and having a molecular weight of at least 100,000; and

(2) about 70 to about 98 parts by weight of a plasticizer;

wherein the triblock copolymer and the plasticizer

(a) have been melt blended and

(b) have been treated at sufficiently high temperature or under sufficiently high shear to cause the composition to have a cone penetration of at least about 50 (10^-1 mm), an ultimate elongation of at least about 200% and a viscosity of 200°

C. of at least 10 poise; and

a bridging member having a continuous convoluted inner surface at opposite ends thereof adapted for engagement with an outer surface of the first and second end seals, the end seals being adapted to be disposed on a cable opposite a cable splice, the bridging member being adapted to be disposed around the splice.

16. The closure of claim 15, wherein the bridging member is split longitudinally.

17. The closure of claim 16, wherein one of the end seals is a split, elongated disc.

18. The closure of claim 16, wherein one of the ends seals comprises first and second half cylinders.

19. The closure of claim 15, wherein the bridging member has an entire outer and inner surface thereof convoluted and has an inside diameter at the opposite ends thereof which is substantially equal to an outside diameter of the first and second end seals, respectively.

20. The closure of claim 19, wherein the bridging member has a tube like shape.

21. The closure of claim 15, wherein the first and second end seals and bridging member form a closure for a junction to be formed in an electric cable, the first and second end seals being adapted to be disposed around the cable adjacent opposite sides of the junction to be formed and the bridging member being adapted to be disposed around the junction to be formed and around at least part of each of the first and second end seals.

22. The closure of claim 21, further comprising a second bridging member disposed around the first bridging member, the second bridging member being convoluted at opposite ends thereof.

23. The closure of claim 21, further comprising means for urging the gel of the first and second end seals into contact with the cable at the opposite sides of the junction.

24. A kit of parts capable of being assembled into a splice enclosure comprising:

a convoluted disc

(A) having convolutions on an outer cylindrical surface thereof and

(B) having a layer of gel on an inside surface thereof shaped so as to form an axial bore therethrough, said layer of gel comprising;

(1) about 2 to about 30 parts by weight of a poly(styrene-ethylene-butylene-styrene) triblock copolymer having a styrene to ethylene butylene block ratio of about 27 to 35 styrene blocks to about 65 to 73 ethylene butylene blocks, and having a molecular weight of at least 100,000; and

(2) about 70 to about 98 parts by weight of a plasticizer;

wherein the triblock copolymer and the plasticizer

(a) have been melt blended and

(b) have been treated at sufficiently high temperature or under sufficiently high shear to cause the composition to have a cone penetration of at least about 50 (10^-1 mm), an ultimate elongation of at least about 200% and a viscosity at 200°

C. of at least 10 poise; and

a bridging member having a continuous convoluted inner surface at opposite ends thereof adapted for engagement with an outer surface of the first and second end seals, the end seals being adapted to be disposed on a cable opposite a cable splice, the bridging member being adapted to be disposed around the splice.

25. The kit-of-parts of claim 24, wherein the bridging member has an entire outer and inner surface thereof convoluted and has an inside diameter at the opposite ends thereof which is substantially equal to an outside diameter of the first and second end seals, respectively.

26. The kit-of-parts of claim 25, wherein the viscosity of said layer of precured gel at 200°

C. is at least 100 poise.

27. The kit-of-parts of claim 25, wherein the molecular weight of the triblock copolymer is about 150,000 to about 300,000.

28. The kit-of-parts of claim 25, wherein the plasticizer comprises a hydrocarbon oil having a solubility parameter of about 6.0 to about 8.5.

29. The kit-of-parts of claim 28, wherein the first and second end seals and bridging member form a closure for a junction in an electric cable, the first and second end seals being adapted to be disposed around the cable adjacent opposite sides of the junction to be formed with the bridging member being adapted to be disposed around the junction to be formed and around at least part of each of the first and second end seals.

30. The kit-of-parts of claim 29, further comprising a second bridging member disposed around the first bridging member, the second bridging member being convoluted at opposite ends thereof.

31. The kit-of-parts of claim 29, further comprising means for urging the gel of the first and second end seals into contact with the cable at the opposite sides of the junction.

32. The kit-of-parts of claim 31, further comprising means for mounting a termination adjacent a junction surrounded by the closure.

33. The kit-of-parts of claim 32, wherein the termination mounting means includes means for mounting the termination outside of the bridging member after installation thereof.