Method and apparatus for the detection of hydrocarbons dissolved in bodies of water

• US 4,943,161 A
• Filed: 11/29/1988
• Issued: 07/24/1990
• Est. Priority Date: 01/27/1983
• Status: Expired due to Fees

• Current Assignee: Gkss-Forschungszentrum Geesthacht GmbH
• Original Assignee: Gkss-Forschungszentrum Geesthacht GmbH
• Inventors: Weitkamp, Claus, Michaelis, Walfried
• Primary Examiner(s): Evans, F. L.
• Application Number:
  US07/277,183
• Time in Patent Office: 602 Days
• Field of Search: 356/51, 356/402, 356/407, 356/432 T, 356/437, 356/72, 356/73, 250/301, 250/304, 250/343, 250/345, 436/28, 436/29, 436/30, 436/32
• US Class Current: 356/437
• CPC Class Codes: G01N 2021/1704 in gases
• CPC Class Codes: G01N 21/1702 with opto-acoustic detection, e.g. for gases or analysing solids
• CPC Class Codes: G01N 33/1833 Oil in water water in oil G01N33/2847

Abstract

A method and apparatus for the detection of hydrocarbons dissolved in bodies of water and for the determination of their concentration in the water wherein a water sample is introduced into a sealed system in which the hydrocarbons are driven out of solution into a gas phase by heating the sample or exposing it to low pressure, or both, a laser beam of a wavelength or a frequency which provides for at least partial overlapping with the absorption lines of the hydrocarbons is directed through the gaseous phase, a correction laser beam of a wavelength such that it is not subjected to absorption by hydrocarbons is also directed through the gaseous phase to determine the influence of gases other than hydrocarbons and the amount of hydrocarbons in the water iscalculated from the amount of light energy absorbed in the gas phase by any hydrocarbons therein and a correction as determined by the correction laser beam.

Claims

1. A method for the detection and the measurement of hydrocarbons dissolved in bodies of water, comprising the steps of:

introducing a water sample, without a loss of hydrocarbons therefrom, into a sealed measuring system, driving any hydrocarbons out of solution in the water sample into a gaseous phase, directing a first laser beam of a wavelength selected so as to provide for at least partial overlapping with the absorption lines of said hydrocarbons through said gaseous phase for absorption therein by hydrocarbons, directing a correction laser beam of a wavelength at which such correction beam is not subject to absorption by the hydrocarbons through said gaseous phase so as to determine the contribution of gases other than hydrocarbons to the absorption of said first laser beam, determining the absorption of said first laser beam by said hydrocarbons, calculating the partial pressure of said hydrocarbons in said gaseous phase from the absorption of said first laser beam in said gaseous phase by the hydrocarbons, and determining the concentration of the hydrocarbons in the water sample from the partial pressure of the hydrocarbons in the gaseous phase on the basis of the distribution equilibrium of the hydrocarbons utilizing the given temperature and pressure conditions.

2. A method according to claim 1, wherein said partial pressure is determined at a given beam path length in said gaseous phase and at a given total pressure by measuring the attenuation of the first laser beam in the gaseous phase.

3. A method according to claim 1, wherein, for determining said partial pressure, the first laser beam intensity is modulated so as to cause heat generation in said gaseous phase by absorption of the first laser beam at a rate which is in accordance with the modulation frequency, and which causes pressure variations that are detected by an acoustic detector.

4. A method according to claim 1, wherein for determining the partial pressure, local changes in the refraction index in the gas phase which are caused by partial absorption of the first laser beam and which are proportional to the partial pressure of hydrocarbons in the gas phase are measured by directing a second laser beam through said gas phase and determining its deflection in said gas phase.

5. A method according to claim 1, wherein the beam length of said first laser beam in said gas phase is increased by reflecting the beam at least once back through the gas phase so as to increase its absorption and the detection capabilities.

6. A method according to claim 1, wherein said hydrocarbons are driven out of solution by increasing the temperature of said sample.

7. A method according to claim 1, wherein said hydrocarbons are driven out of solution by reducing the pressure in said measuring system.

8. A method according to claim 1, wherein a magnetic field is generated within said gaseous phase so as to influence the first laser beam or the sample gas for optimizing overlapping of the first laser beam emission spectrum and the absorption spectrum of the hydrocarbons to be detected.

9. An apparatus for the detection and the measurement of hydrocarbons dissolved in bodies of water, said apparatus comprising:

a sealed measuring system, a container for the reception of water samples in said sealed measuring system, heating means for heating said sample and evacuation means for reducing the pressure in said container for driving any hydrocarbons out of said sample into a gas phase, a chamber for receiving said gas phase, means for sensing the temperature and means for sensing the pressure in said chamber, a laser beam source so associated with said system as to provide a laser beam which extends through said gas phase, said laser source being selected so as to provide light with a wavelength providing for at least partial overlapping with the absorption lines of the hydrocarbons to be detected to thereby cause substantial attenuation of said laser beam, means for measuring the attenuation of said laser beam, a correction laser beam source also associated with said system so as to provide a beam which extends through said gas phase, said correction beam having a wavelength at which such correction beam is not subject to absorption by the hydrocarbons through said gaseous phase so as to determine the contribution of gases other than hydrocarbons to the absorption of said first laser beam, determining the absorption of said first laser beam by said hydrocarbons and means for determining therefrom the hydrocarbon content in said sample.