High temperature oxygen recovery with reversible chemical reaction

• US 4,944,934 A
• Filed: 01/03/1990
• Issued: 07/31/1990
• Est. Priority Date: 01/03/1990
• Status: Expired due to Fees

• Current Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Original Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Inventors: Carlin, Richard T., Cassano, Anthony A., Dunbobbin, Brian R.
• Primary Examiner(s): Stoll, Robert L.
• Assistant Examiner(s): Langel, Wayne A.
• Application Number:
  US07/460,467
• Time in Patent Office: 209 Days
• Field of Search: 423/210.5, 423/219, 423/579
• US Class Current: 423/579
• CPC Class Codes: C01B 13/0285 by absorption in liquids
• CPC Class Codes: C01B 2210/0046 Nitrogen
• CPC Class Codes: C01G 31/00 Compounds of vanadium

Abstract

Separation of oxygen from air is performed in a continuous, cyclic manner using vanadium bronze liquid slurries as reversible chemical absorbents, absorbing at elevated temperature and desorbing at lowered temperature.

Claims

1. A continuous process for separating oxygen from air by a reversible chemical absorption at relatively high temperature and desorption at a relatively low temperature comprising the steps of:

(a) contacting air with a liquid slurry of a chemical absorbent for oxygen having a composition of

space="preserve" listing-type="equation">M.sub.x V.sub.2 O.sub.5

wherein M=Li, Na, K, Ag, or mixture thereof and 0<

x<

1, and heating the liquid slurry to a temperature in the range of approximately 630°

C. to 870°

C. to absorb at least a portion of the oxygen from the air and oxidize the liquid slurry to a predominantly liquid M₂ O/V₂ O₅ mixture;

(b) separating the oxygen depleted air from the oxidized liquid mixture;

(c) cooling the oxidized liquid mixture to a temperature in the range of approximately 370°

C. to 500°

C. to desorb oxygen from the liquid mixture and regenerate the liquid slurry; and

(d) separating the oxygen from the liquid slurry.

2. The process of claim 1 wherein the heat of step (a) is derived by indirect heat exchange with flue gas of a steam boiler, flue gas at a partial oxidation gasifier, flue gas from a Claus sulfur plant, flue gas from a stream-methane reformer, flue gas from an ethylene plant, a fluidized catalytic cracker regenerator or a fluidized bed combustor.

3. The process of claim 1 wherein the cooling of step (c) is derived from indirect heat exchange with water to produce steam.

4. The process of claim 1 wherein at least a portion of the heat of step (a) and at least a portion of the cooling of step (c) is derived by indirect heat exchange of the liquid slurry undergoing step (a) with the liquid mixture undergoing step (c).

5. The process of claim 1 wherein the heat of step (a) is derived from indirect heat exchange with an elevated temperature, oxygen-lean molten salt of alkali metal nitrates and nitrites and the cooling of step (c) is derived from indirect heat exchange with a lower temperature, oxygen-rich molten salt of alkali metal nitrates and nitrites.

6. The process of claim 1 wherein the air is pressurized before contacting the liquid slurry.

7. The process of claim 6 wherein the pressure is approximately 207 kPa.