Process for hardcoating polycarbonate sheet

• US 4,946,531 A
• Filed: 12/01/1988
• Issued: 08/07/1990
• Est. Priority Date: 12/01/1988
• Status: Expired due to Term

• Current Assignee: Sabic Innovative Plastics IP BV (Government of Saudi Arabia)
• Original Assignee: General Electric Company
• Inventors: Sieloff, Ronald F., Crouch, Earl T.
• Primary Examiner(s): Weston, Caleb
• Application Number:
  US07/278,649
• Time in Patent Office: 614 Days
• Field of Search: 156/242, 156/244.17, 156/272.2, 156/273.3, 156/273.5, 156/273.7, 427/35, 427/44, 427/54.1, 427/161, 427/163, 427/164
• US Class Current: 156/242
• CPC Class Codes: B05D 1/40 Distributing applied liquids or other fluent materials by members moving relatively to surface
• CPC Class Codes: B05D 3/067 Curing or cross-linking the coating
• CPC Class Codes: B05D 7/04 to surfaces of films or sheets producing layered products by applying coatings of pasty or pulverulent plastics B29C41/00
• CPC Class Codes: B32B 2037/243 Coating
• CPC Class Codes: B32B 2038/0076 Curing, vulcanising, cross-linking
• CPC Class Codes: B32B 2307/536 Hardness
• CPC Class Codes: B32B 2307/554 Wear resistance
• CPC Class Codes: B32B 2309/12 Pressure
• CPC Class Codes: B32B 2310/0831 using UV radiation
• CPC Class Codes: B32B 2333/08 Polymers of acrylic acid esters, e.g. PMA, i.e. polymethylacrylate
• CPC Class Codes: B32B 2369/00 Polycarbonates
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/36 comprising polyesters
• CPC Class Codes: B32B 27/365 comprising polycarbonates
• CPC Class Codes: B32B 37/203 One or more of the layers being plastic
• CPC Class Codes: B32B 37/24 with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate B32B37/15 takes precedence
• CPC Class Codes: C08J 2369/00 Characterised by the use of polycarbonates; Derivatives of polycarbonates
• CPC Class Codes: C08J 2433/00 Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
• CPC Class Codes: C08J 7/0427 with only one layer of a composition containing a polymer binder with more layers C08J7/042
• CPC Class Codes: C08J 7/046 Forming abrasion-resistant coatings; Forming surface-hardening coatings

Abstract

A process for preparing a hardcoated polycarbonate sheet involves (i) ultraviolet radiation curing an acrylic coating onto one surface of a flexible polycarbonate film via a drum casting technique to yield a flexible, abrasion and chemical resistant hardcoated film; and (ii) laminating the hardcoated film onto a thick rigid polycarbonate substrate by an on-line ultraviolet radiation lamination method. The process is fast, requires minimal labor and provides high optical quality hardcoats for polycarbonate sheet.

Claims

1. A process for producing a hardcoated aromatic polycarbonate resin sheet, said process comprising the steps of:

(a) hardcoating a flexible aromatic polycarbonate film having a thickness selected from between about 0.5 mils and about 30 mils, the hardcoating of the film being a continuous procedure involving;

(i) applying an uncured coating material to the film, the coating material comprising an amount of polyfunctional acrylate ester monomers and an amount of a photoinitiator,

(ii) passing the film and applied uncured coating material through a constant pressure compression nip, the compression nip pressure being selected from between about 5 psi to about 50 psi to provide a substantially uniform layer of uncured coating material on the film,

(iii) anaerobically contacting the uniform coating layer with a peripheral surface of a longitudinally rotateable, cylindrical casting drum,

(iv) curing the coating layer by directing ultraviolet radiation through the film to the coating layer while the coating layer is in contact with the drum surface to provide a hardcoated film having a cured coating having surface characteristics determined by the casting surface, the cured coating having a thickness selected from between 0.1 mils and 1.0 mils; and

(b) laminating the hardcoated film onto a rigid aromatic polycarbonate substrate, the substrate having a thickness selected from between about 35 mils to about 1000 mils, the laminating involving;

(i) preparing an overlay by placing an amount of an acrylic adhesive between a surface of the substrate and an uncoated surface of the hardcoated film, and by bringing the uncoated surface of the film into a position adjacent to the surface of said substrate;

(ii) passing the overlay through a laminating nip to eliminate diatomic oxygen from between the film and the substrate, and from the adhesive, said laminating nip pressing the overlay with a substantially constant pressure to create a substantially uniform layer of adhesive between the film and the substrate; and

(iii) curing the adhesive layer by directing ultraviolet radiation through the film to the adhesive layer to cure the adhesive layer and bond the hardcoated film to the substrate, said cured adhesive layer having a thickness selected from between 0.2 mils and 2.0 mil.

2. The process of claim 1 wherein said hardcoated film is rolled into the form of cylindrical roll and stored following said hardcoating step and prior to said laminating step, said hardcoated film having a coating hardness such that the hardcoat thereon experiences no more than 10 percent haze after 500 cycles of a CS10F Tabor abrasion wheel at a 500 gram loading, said hardcoated film having a degree of flexibility sufficient to allow said hardcoated film to be wrapped around the circumference of a cylinder of radias 3 inches without cracking of said hardcoat.