Heat transfer fluids containing dicarboxylic acid mixtures as corrosion inhibitors

• US 4,946,616 A
• Filed: 11/14/1988
• Issued: 08/07/1990
• Est. Priority Date: 11/14/1988
• Status: Expired due to Term

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Falla, Daniel J., Berchtold, Peter H.
• Primary Examiner(s): Lieberman, Paul
• Assistant Examiner(s): Skane, Christine A.
• Application Number:
  US07/270,718
• Time in Patent Office: 631 Days
• Field of Search: 252/79, 252/76, 252/75, 252/73, 252/77, 252/396, 252/394
• US Class Current: 252/75
• CPC Class Codes: C09K 5/20 Antifreeze additives therefor, e.g. for radiator liquids for application to surfaces C09K3/18; inhibiting corrosion by liquids C23F11/00
• CPC Class Codes: C23F 11/10 using organic inhibitors

Abstract

A coolant composition for use in automotive engines is disclosed which comprises a liquid alcohol freezing depressant and a corrosion inhibitor consisting essentially of decanedioic acid, dodecanedioic acid and sodium tolyltriazole.

Claims

1. A coolant composition comprising a major portion of one or more water-soluble liquid alcohol freezing point depressants and a corrosion-inhibiting amount of an inhibitor consisting essentially of (1) from about 2.0 to about 5.5 weight parts of a mixture of decanedioic acid and dodecanedioic acid or salts thereof per 100 weight parts of the coolant composition and (2) from about 0.5 to about 0.5 weight parts of a hydrocarbyl triazole or salt thereof per 100 weight parts of the coolant composition.

2. The composition of claim 1 wherein the freezing point depressant consists essentially of a 90:

10 ratio mixture of ethylene glycol and diethylene glycol.

3. The composition of claim 2 wherein the mixture of decanedioic acid and dodecanedioic acid consists of about 0.7 weight parts of decanedioic acid and about 1.8 weight parts of dodecanedioic acid.

4. The composition of claim 1 wherein the pH of the composition is at least about 7.0 and no greater than about 9.0.

5. The composition of claim 4 wherein the pH is at least about 8.0 and no greater about 8.5.

6. The process of claim 3 wherein the triazole is sodium tolyltriazole.

7. The process of claim 3 wherein from about 0.1 to about 0.3 weight parts of the triazole are used.

8. The process of claim 7 wherein about 0.1 weight part of the triazole is used.