High purity polyether polyols

• US 4,946,939 A
• Filed: 05/30/1989
• Issued: 08/07/1990
• Est. Priority Date: 05/30/1989
• Status: Expired due to Term

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Murphy, Frank H., Jernigan, Robert T., Wessels, Wayne G., Grierson, Jeff G.
• Primary Examiner(s): Nielsen, Earl
• Application Number:
  US07/359,014
• Time in Patent Office: 434 Days
• Field of Search: 528/421, 528/499, 568/621, 210/644, 210/651
• US Class Current: 528/421
• CPC Class Codes: C08G 65/30 Post-polymerisation treatment, e.g. recovery, purification, drying

Abstract

High purity polyether polyol compositions such as polyethylene glycol are made having small amounts of impurities such as oligomers of active hydrogen compounds with alkylene oxides. The high purity is achieved by subjecting the polyether polyol compositions to membrane filtration to get less than about 10 parts per million of the low molecular weight oligomers.

Claims

1. A high purity polyalkylene polyol composition having a weight average molecular weight range from about 400 to about 15,000 and having as the major impurity a mixture comprising low molecular weight and high molecular weight polyalkylene polyol oligomers wherein said low molecular weight oligomer portion from dimer to pentamer is less than about 10 parts per million for each oligomer.

2. A high purity composition as set forth in claim 1 wherein the weight average molecular weight range is from about 600 to about 8,000.

3. A high purity composition as set forth in claim 1 wherein the weight average molecular weight range is from about 800 to about 4,000.

4. A high purity composition as set forth in claim 1 wherein said low molecular weight oligomer portion from dimer to decamer is less than about 10 part per million.

5. A high purity composition as set forth in claim 1 wherein said low molecular weight oligomer portion from dimer to pentamer is less than about 1 part per million.

6. A high purity composition as set forth in claim 1 wherein said low molecular weight oligomer portion from dimer to decamer is less than about 1 part per million.

10. A high purity composition as set forth in claim 5 wherein said low molecular weight oligomer portion from dimer to decamer is less than 10 parts per million.

18. A high purity composition as set forth in claim 1 wherein said low molecular weight oligomer portion from dimer to decamer is less than about 1 part per million.

7. A high purity polyether polyol composition made from alkylene oxides of two to four carbons and active hydrogen compound initiators, said polyol composition having a weight average molecular weight range from about 400 to about 100,000 and having as the major impurity a mixture comprising low molecular weight and high molecular weight oligomers of said initiators with said alkylene oxides wherein said low molecular weight oligomer portion from dimer to pentamer is less than about 10 parts per million for each oligomer.

8. A high purity polyalkylene glycol composition as set forth in claim 7 having a weight average molecular weight range from about 600 to about 8,000.

9. A high purity polyalkylene glycol composition as set forth in claim 7 having a weight average molecular weight range from about 800 to about 4,000.

11. A high purity composition as set forth in claim 7 wherein said low molecular weight oligomer portion from dimer to pentamer is less than about 1 part per million.

12. A high purity composition as set forth in claim 7 wherein said low molecular weight oligomer portion from dimer to decamer is less than about 1 part per million.

13. A high purity polyethylene glycol composition having a weight average molecular weight range from about 400 to about 15,000 and having as the major impurity a mixture comprising low molecular weight and high molecular weight polyethylene glycol oligomers wherein said low molecular weight oligomer portion from dimer to pentamer is less than about 10 parts per million for each oligomer.

14. A high purity polyethylene glycol composition as set forth in claim 13 wherein the weight average molecular weight range is from about 600 to about 8,000.

15. A high purity polyethylene glycol composition as set forth in claim 13 wherein the weight average molecular weight range is from about 800 to about 4,000.

16. A high purity composition as set forth in claim 13 wherein said low molecular weight oligomer portion from dimer to decamer is less than about 1 part per million.

17. A high purity composition as set forth in claim 13 wherein said low molecular weight oligomer portion from dimer to pentamer is less than about 1 part per million.

19. A high purity polyether polyol composition made from alkylene oxides of two to four carbons and active hydrogen compound initiators, having a weight average molecular weight range from about 400 to about 100,000 and having as the major impurity a mixture comprising low molecular weight and high molecular weight oligomers of said initiators with said alkylene oxides wherein said high purity composition is produced by the process comprising the steps of

(i) adding at least 2 grams of water per gram of an impure polyol containing residual amounts of said initiators, alkylene oxide monomers and low and high oligomers, and

(ii) subjecting the dilute impure polyol to membrane filtration to remove said low molecular weight oligomer portion, initiators, and alkylene oxide monomers with the permeate.

20. A high purity polyether polyol composition as set forth in claim 19 wherein the membrane used has a molecular weight cut off of at least 150 daltons.

21. A high purity polyethylene glycol composition made from ethylene oxide and active hydrogen compound initiators, having a weight average molecular weight range from about 400 to about 15,000 and having as the major impurity a mixture comprising low molecular weight and high molecular weight oligomers of said initiators with said ethylene oxide wherein said high purity composition is produced by the process comprising the steps of

(i) adding at least 2 grams of water per gram of an impure glycol containing residual amounts of said initiators, ethylene oxide and low and high oligomers, and

(ii) subjecting the dilute impure polyol to membrane filtration to remove said low molecular weight oligomer portion, initiators, and ethylene oxide with the permeate.

22. A high purity polyethylene glycol composition as set forth in claim 21 wherein the membrane used has a molecular weight cut off of at least 150 daltons.

23. A process for making high purity polyether polyol compositions wherein said high purity composition is produced by the process comprising the steps of

(i) adding at least 2 grams of water per gram of an impure polyol made from alkylene oxides of two to four carbons and active hydrogen compound initiators and having a weight average molecular weight range from about 400 to about 100,000 containing residual amounts of said initiators, alkylene oxide monomers and low and high oligomers, and

(ii) subjecting the dilute impure polyol to membrane filtration to remove said low molecular weight oligomer portion, initiators, and alkylene oxide monomers with the permeate.

24. A process as set forth in claim 23 wherein the membrane used has a molecular weight cut off of at least 150 daltons.

25. A process for making high purity polyethylene glycol compositions wherein said high purity composition is produced by the process comprising the steps of

(i) adding at least 2 grams of water per gram of an impure polyethylene glycol made from alkylene oxides of two to four carbons and active hydrogen compound initiators and having a weight average molecular weight range from about 400 to about 100,000 containing residual amounts of said initiators, alkylene oxide monomers and low and high oligomers, and

(ii) subjecting the dilute impure polyethylene glycol to membrane filtration to remove said low molecular weight oligomer portion, initiators, and alkylene oxide monomers with the permeate.

26. A process as set forth in claim 25 wherein the membrane used has a molecular weight cut off of at least 150 daltons.