Method of controlling air entrainment in concrete compositions

• US 4,948,429 A
• Filed: 06/14/1989
• Issued: 08/14/1990
• Est. Priority Date: 06/14/1989
• Status: Expired due to Fees

• Current Assignee: W R Grace & Company - CONN (Standard Industries Holdings, Inc.)
• Original Assignee: W R Grace & Company - CONN (Standard Industries Holdings, Inc.)
• Inventors: Arfaei, Ahmad
• Primary Examiner(s): Dixon, Jr., William R.
• Assistant Examiner(s): Wright, Alan
• Application Number:
  US07/366,908
• Time in Patent Office: 426 Days
• Field of Search: 106/90, 106/102, 106/104, 106/93, 106/85
• US Class Current: 106/659
• CPC Class Codes: C04B 2103/30 Water reducers, plasticisers, air-entrainers, flow improvers
• CPC Class Codes: C04B 2103/304 Air-entrainers
• CPC Class Codes: C04B 2103/50 Defoamers, air detrainers
• CPC Class Codes: C04B 24/02 Alcohols; Phenols; Ethers
• CPC Class Codes: C04B 24/24 Macromolecular compounds C04B24/14 takes precedence; macromolecular compounds comprising sulfonate or sulfate groups C04B24/16
• CPC Class Codes: C04B 24/32 Polyethers, e.g. alkylphenol polyglycolether
• CPC Class Codes: C04B 24/34 Natural resins, e.g. rosin C04B24/243 takes precedence
• CPC Class Codes: C04B 28/02 containing hydraulic cements other than calcium sulfates
• CPC Class Codes: C04B 40/0028 Aspects relating to the mixing step of the mortar preparation

Abstract

A method of controlling the level of entrained air in hydraulic cement compositions is disclosed comprising the sequential steps of preparing a hydraulic cement composition in the form of an aqueous slurry containing an air entraining plasticizer and a defoamer, and increasing the air content of the composition by adding to said composition an air entraining agent. This method prevents undesired air entrainment, while allowing controlled amounts of air to be entrained if desired for freeze/thaw durability.

Claims

1. A method of preparing an air entrained cementitious composition comprising the sequential steps of:

a. preparing an aqueous hydraulic cement-based slurry by admixing water, a hydraulic cement, an air entraining plasticizer, and a defoamer selected from the group consisting of acetylenic diols and reaction products thereof with alkylene oxides; and

b. increasing the air content of the said composition by adding to said composition an effective air-entraining amount of an second air entraining agent.

2. The method of claim 1 wherein the defoamer is a compound having the generic formula:

##STR2## wherein R₁, R₂, R₃, and R₄ may independently be short chain branched or linear alkyl groups having from 1 to 10 carbon atoms.

3. The method of claim 1 wherein the defoamer is 2,4,7,9-tetramethyl-5-decyn-4,7-diol.

4. The method of claim 1 wherein the defoamer is present in an amount of from 0.10% to 10% by weight based on the weight of the plasticizer.

5. The method of claim 1 wherein the air entraining agent is tall oil.

6. The method of claim 1 wherein the air entraining agent is present in an amount of from 0.01% to 0.10% solids on solids based on the weight of hydraulic cement.

7. The method of claim 1 wherein the air content subsequent to addition of the air entraining agent is greater than 6%.

8. The method of claim 1 wherein the slurry is prepared by mixing the water and hydraulic cement and adding thereto an aqueous solution of the defoamer and the plasticizer.

9. A hydraulic cement composition in the form of an aqueous slurry comprising:

a. a hydraulic cement binder;

b. an air entraining plasticizer;

c. a defoamer selected from the group consisting of acetylenic diols and reaction products thereof with alkylene oxides; and

d. a second air entraining agent air.

10. The composition of claim 9 wherein the defoamer is a compound having the generic formula:

##STR3## wherein R₁, R₂, R₃, and R₄ may independently be short chain branched or linear alkyl groups having from 1 to 10 carbon atoms.

11. The composition of claim 9 wherein the defoamer is 2,4,7,9-tetramethyl-5-decyn-4,7-diol.

12. The composition of claim 9 wherein the defoamer is present in an amount of from 0.003% to 0.035% solids on solids based on the weight of cement binder.

13. The composition of claim 9 wherein the air entraining agent is tall oil.

14. The composition of claim 9 wherein the air entraining agent is present in an amount of from 0.01% to 0.10% solids on solids based on the weight of cement binder.