Gas separation membrane

• US 4,950,314 A
• Filed: 03/07/1989
• Issued: 08/21/1990
• Est. Priority Date: 08/14/1986
• Status: Expired due to Fees

• Current Assignee: Toray Industries Incorporated
• Original Assignee: Toray Industries Incorporated
• Inventors: Shiro, Kuniyasu, Yamada, Shinichi
• Primary Examiner(s): SPITZER, ROBERT H
• Application Number:
  US07/319,801
• Time in Patent Office: 532 Days
• Field of Search: 55/16, 55/68, 55/158
• US Class Current: 96/4
• CPC Class Codes: B01D 2323/12 Specific ratios of components used
• CPC Class Codes: B01D 2323/30 Cross-linking
• CPC Class Codes: B01D 67/0002 Organic membrane manufacture
• CPC Class Codes: B01D 69/02 characterised by their properties
• CPC Class Codes: B01D 71/26 Polyalkenes
• CPC Class Codes: B01D 71/52 Polyethers
• CPC Class Codes: B01D 71/5223 Polyphenylene oxide, phenyl ether polymers or polyphenylethers
• CPC Class Codes: B01D 71/82 characterised by the presence of specified groups, e.g. introduced by chemical after-treatment
• CPC Class Codes: C08G 65/485 Polyphenylene oxides

Abstract

A gas separation membrane with excellent gas separation properties is disclosed. The gas separation membrane is substantially free from pinholes and consists essentially of a crosslinked polyolefin or a crosslinked polyarylene oxide. This gas separation membrane is produced by evaporating a solution containing a polyolefin or a polyarylene oxide having an active functional group which can form crosslinking site therebetween or which can react with a crosslinking agent to form a crosslinking site.

Claims

1. A gas separation membrane consisting essentially of a crosslinked polyolefin or a crosslinked polyarylene oxide, which gas separation membrane is produced by evaporating a solution containing polyolefin or a polyarylene oxide having an active functional group which can autogenically form crosslinking sites therebetween.

2. The gas separation membrane of claim 1, wherein the crosslinking sites are formed of oligosiloxane bonds.

3. The gas separation membrane of claim 2, wherein the oligosiloxane bond is expressed by the formula:

##STR6## wherein X₁, X₂, X₃ and X₄ independently represents --OSi--, alkyl, aryl, alkoxy, acetoxy, oxime or hydroxyl and n represents an integer of 1 to 3.

4. The gas separation membrane of claim 1, wherein the polyolefin is composed of olefin units containing 2 to 18 carbon atoms.

5. The gas separation membrane of claim 1, wherein the polyolefin is mainly composed of α

-olefin units.

6. The gas separation membrane of claim 1, wherein the polyolefin comprises at least one of polypropylene and poly(4-methylpentene).

7. The gas separation membrane of claim 1, wherein the polyarylene oxide is expressed by the formula:

##STR7## wherein m represents an integer of 1-3, n represents an integer of not less than 75, R represents, the same or different, alkyl, substituted alkyl, phenyl, substituted phenyl, halogen, alkoxy, alkenyl, alkynyl or amino).

8. The gas separation membrane of claim 7, wherein the polyarylene oxide consists essentially of poly(2,6-dimethyl-1,4-phenylene oxide).

9. The gas separation membrane of claim 1, wherein the polyarylene oxide has a non-crosslinking silicon-containing group selected from the group consisting of organosilyl, organosiloxane and organosilalkylene.

10. The gas separation membrane of claim 1, wherein the active functional group is an active silyl group.

11. The gas separation membrane of claim 10, wherein the active silyl group is selected from the group consisting of alkoxysilyl, acetoxysilyl and oximesilyl.

12. The gas separation membrane of claim 1, further comprising a porous support on which the gas separation membrane is laminated.

13. The gas separation membrane of claim 1, wherein the solution contains a crosslinking catalyst selected from the group consisting of organotin, a salt of carboxylic acid, amine and titannic ester.

14. The gas separation membrane of claim 1, which is an asymmetric membrane.

15. A composite gas separation membrane comprising:

a porous support;

a first gas permeable layer formed on the porous support; and

a gas separation layer consisting essentially of the gas separation membrane of claim 1.

16. The gas separation membrane of claim 1, which has a thickness of 1 to 300 μ

m.